共軛聚體 的英文怎麼說
中文拼音 [gòngèjùtǐ]
共軛聚體
英文
conjugated polymers-
The fluorescence of the copolymer ( dmbn - vcz ) spectra show that the fluorescence spectra are in good agreement with that of dmbn monomer when the solution of copolymer ( dmbn - vcz ) is located in low concentration range ( < 10 - 3mg / ml )
對非共軛聚合物（ dmbn - vcz ）的熒光光譜來說，在濃度很低時，它的激發，發射光譜和單體（ dmbn ）非常類似。Polyparaphenylenevinylene ( ppv ) has been paid attention to because of good photoelectric property and peculiar molecule framework ; fullenene have three - dimensional conjugated structure and diminutive electron binding energy, and its peculiar structure and property has interested photoelectric scientist. as an electronic acceptor, c60 can enhance the efficiency of organic photoelectric cells compounded with ppv. but the little solubility of c60 in common organic solvent limited its application, and processing measure need more researchment
聚對苯乙撐（ ppv ）具有優良的光電性能和特有的分子構架而倍受關注， c _ （ 60 ）具有三維共軛結構完美的對稱性和小的電子結合能，以其獨特的結構和性能引起了光電科學工作者的極大興趣，將c _ （ 60 ）作為電子受體與共軛聚合物ppv復合可以使有機光伏電池的效率提高。The fluorescence spectra of the conjugationed polymer containing of n - ( a - naphthyl ) carbazole show that the emission sprctra in aromatic solvents are more red - shifted than that in aliphatic solvents although these solvents have the same polarity. the fluorescence chatacteristics were different from th e n - ( a - naphthyl ) carbazole ' s. the fluorescence of the conjugationed polymer can be quenched by electron donors and cm and cannot be quenched by electron acceptors
對含有n - （ -荼基）咔唑基團的共軛高聚物，它在芳香族溶劑中的熒光發射比非芳香族溶劑中明顯紅移，也不具有n - （ -萘基）咔唑單元所具有的分子內電荷轉移特性，它的熒光只能被電子給體和c _ （ 60 ）猝滅而不能被一般的電子受體猝滅。Abstract : polyphenylacetylenes were synthesized by rn ( nbd ) cl 2 and wcl6 / ph4sn catalyst systems in n2 at room temperature. polymers with high yield and high molecular weight were obtained. their structures were characterized by uv, ir, nmr and gpc, respectively. the fluorescence of the polymer solution with different concentration was investigated using variable excitation wavelength from uv to visible region. the relation between fluorescence and polymer structure was studied. the results showed that the molecular chain structure has great influence on fluorescence of the polymers. the emitting peak wavelength of fluorescence for the polymer of high stereoregularity is independent of solution concentration and excitation wavelength. the emitting peak wavelength of fluorescence for the polymer with disordered molecular chain arrangement varies with changing the solution concentration and excitation wavelength, and different emission sites in molecular chains and low emitting yield are shown. the measurement and analysis of fluorescence spectroscopy of polyphenylacetylenes may provide some useful information to judge the molecular chain arrangement in some conjugated polymers
文摘:使用有機金屬銠、金屬鎢/四苯基錫催化劑體系聚合苯乙炔，分別獲得了高產率和高分子量的聚苯乙炔.使用uv ， ir ， nmr ， gpc等分別對聚合物結構進行了表徵.採用不同波長的激發光對聚合物熒光性能進行研究，詳細分析了聚合物結構與熒光性能之間的關系.研究結果發現，不同聚合物結構對聚合物熒光性能產生很大影響，規整性高的聚合物，將有較高的發光量子效率；聚合物規整性差，將可能導致多個熒光發光結構點，其熒光強度降低.聚合物熒光光譜研究將對某些共軛聚合物結構的規整性分析提供一些有用的信息With the development of the research on organic photon material, many photon phenomena in conventional material had been detected such as photoelectric transform, electroluminescence. the photon material included conjugated polymers, fullerene material and organnic little molecule containing good it conjugated system
隨著有機光子材料研究的不斷發展，許多在傳統材料中發現的光子現象如光電轉換、電致發光等在有機材料中也同樣被觀測到，這些光子材料包括共軛聚合物、富勒烯族材料和具有良好的共軛體系的有機小分子。分享友人