Unsaturated alkynyl alcohols, such as dehydronerolidol, dehydrogeranyllinalool, and dehydroisophytol, were prepared by ethynylation of turpentine derivatives, namely terpenylacetones, e. g. geranylacetone, farnesylacetone, and phyton under normal pressure in presence of alkali metal hydroxide and organic solvents
摘要松節油衍生物格萜
烯基丙酮,如香葉基丙酮、金合歡基丙酮和植物酮在常壓條件,堿金屬氫氧化物和有機溶劑存在下可發生乙炔化反應,形成對應的, -不飽和炔醇化合物脫氫橙花叔醇、脫氫香葉基芳
樟醇和脫氫異植物醇。
The yields of dehydronerolidol, dehydrogeranyllinalool, and dehydroisophytol, under suitable conditions of ethynylation of the three terpenylacetones, were 85. 7 %, 86. 7 %, and 74. 4 %, respectively
在合適的反應條件下, 3種萜烯基丙酮乙炔產物,脫氫橙花叔醇、脫氫香葉基芳樟醇和脫氫異植物醇的得率分別為85 . 7 % 、 86 . 7 %和74 . 4 % 。