烯丙基聚合物 的英文怎麼說
中文拼音 [xībǐngjījùgěwù]
烯丙基聚合物
英文
allyl polymer- 烯 : 名詞[化學] (有機化合物的一類) alkene; olefince
- 丙 : Ⅰ名詞1. (天乾的第三位) the third of the ten heavenly stems2. (姓氏) a surname Ⅱ數詞(第三) third
- 聚 : 動詞(聚集; 聚積) assemble; gather; get together
- 合 : 合量詞(容量單位) ge, a unit of dry measure for grain (=1 decilitre)
- 物 : 名詞1 (東西) thing; matter; object 2 (指自己以外的人或與己相對的環境) other people; the outsi...
- 聚合物 : [化學] polymer; polymerizate; polymeric compound; polymeric substance; polymeride; polymerized su...
- 聚合 : 1 (聚集到一起) get together2 [化學] (單體結合成高分子化合物) polymerization; polymerize 3 [生...
-
The obtained polysilane - polyacrylate gradient films showed no macro - interface with the silicone content reducing gradually from the top surface to the bottom one. dma thermograms indicated that polysilane - polyacrylate gradient films contained two glass temperatures with their bands drifting from and their range extending much from each component. the good properties of waterproof, calorifics, and ultraviolet - absorption were also determined by dsc, uv and water contact angle measurements
結果表明:有機硅聚合物-聚丙烯酸酯梯度膜有一個較寬的玻璃化轉變溫區,玻璃化轉變范圍相對組分材料的玻璃化轉變范圍發生了擴展:有機硅聚合物-聚甲基丙烯酸酯梯度膜具有較好的熱學性能;硅含量的提高有利於改善膜層的憎水性能和紫外吸收性能。First, a terminal double bond was introduced into 3 - amino - 9 - ethylcarbazole ( aec ) via methacryloyl chloride to obtain the compound, 3 - ( n - methacryloyl ) amino - 9 - ethylcarbazole ( mec ). second, mec was copolymerized with butyl methacrylate to prepare the mec - immobilized polymer particles. the resultant polymer particles were used as a fluorescence probe, which was almost free of dye leaching, and had higher photostability in comparison with free aec
首先利用甲基丙烯酰氯向3 -氨基- 9 -乙基咔唑( aec )分子中引入末端雙鍵,得到帶末端雙鍵的熒光指示劑3 - ( n -甲基丙烯酰基)氨基- 9 -乙基咔唑( mec ) ,然後通過乳液聚合技術將mec共價固定到聚甲基丙烯酸丁酯基體上,制得一種共價固定了mec的聚合物顆粒。In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術,有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應,提高了聚合物大分子鏈中有機硅鏈節的含量;利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵,並通過對共聚產物力學和吸水率的測試,證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能;從分子設計角度出發,利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體: ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷;利用核磁共振對新型硅烷單體結構進行了證實;研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液,且其聚合產物具有較高的力學及耐水性能。In this paper, pan based metal gradient composites films ( pmgcf ) were prepared by electrochemical reduction. the effect of polymer matrix on pmgcf and preparation and its forming mechanism of pmgcf were invested, they are as follows : lacrylonitrile - methyl - methacrylate copolymer, acryonitrile - itaconic acid copolymer, acrylonitrile - methyl methacry late - sodium allyl sulfonate terpolymer have been synthesized seperately in order to analyze the effects of the mma monomer unites and the hydrophilic unites of acryonitrile terpolymer on the process of copper deposition in polyacrylonitrile - based metal gradient composite film ( pmgcf ) as well as the flexibility of the film
其內容如下: 1通過合成的丙烯腈?甲基丙烯酸甲酯二元共聚物( p ( an - mma ) ) ,丙烯腈?亞甲基丁二酸二元共聚物( p ( an - ita ) ) ,丙烯腈-甲基丙烯酸甲酯?丙烯磺酸鈉三元共聚物( p ( an - mma - as ) )分別作為基體制備了聚合物基金屬梯度復合膜材料( pmgcf ) ,以分析加入的mma基團和親水性基團對pmgcf沉積層中金屬銅的梯度分佈形態和膜的柔韌性的影響。Studies on the synthesis of grafted copolymer polyol with dimethyl ally phosphite onto unsaturated flame retardant polyether polyol
不飽和阻燃聚醚多元醇接枝烯丙基膦酸二甲酯共聚物的合成研究Ir, sem - edx, and water contact angle measurements on polysilane and polyacrylate film obtained by double operations and single operation showed that the influence of weight ratio of polymers, the molecular of pmma on film structure was great. the film translucence dropping while the ratio of pmma / pmts grew and the compatible reducing while the molecular of pmma increased
通過測定所配製的系列濃度聚合物甲苯溶液、 thf溶液的表面張力發現:有機硅聚合物溶液的表面張力值在有機硅聚合物濃度低於30時變化不明顯;而甲基丙烯酸酯聚合物溶液表面張力值隨甲基丙烯酸酯聚合物濃度的變化比有機硅聚合物溶液明顯。In this article, the bellcore method was used to prepare polymer electrolyte membrane based on pvdf - hfp, and polymer electrolyte membranes under different conditions were prepared by changing sorts of solvents 、 ratio of dbp and solvent. effects of ratio of plasticizer and solvent on the liquid uptake 、 sem 、 mechanism capability 、 ionic conductivity 、 electrochemical stability window of polymer electrolyte membrane were also studied. through optimizing the preparation technics, the integrated effects of additives such as pc 、 ec 、 dbp and nanophase al2o3 on the ionic conductivity 、 liquid uptake were studied
本文以聚偏氟乙烯-六氟丙烯共聚物pvdf - hfp為基質,採用bellcore制膜法制備了pvdf - hfp聚合物電解質膜,通過改變增塑劑dbp的含量、溶劑的種類及溶劑的含量制備了不同條件下的聚合物電解質膜,分別研究了增塑劑含量、溶劑含量等對聚合物電解質膜的吸液率、表面形貌、機械性能、離子電導率、電化學穩定窗口等的影響;對制備工藝進行了優化,研究了各種添加劑如pc 、 ec 、 dbp及納米al2o3對聚合物電解質膜的離子電導率、吸液率等性能的綜合影響。In attempt to prepare and investigate the novel high - performance electrically conductive polymer composites, the binary and multicomponent electrically conductive nanocomposites as well as the combined nano and in - situ composites were prepared with polypropylene ( pp ) served as the matrix, expanded graphite ( eg ) as a conductive filler, nylon 66 ( pa66 ) as a modifier, and maleic anhydride grafted polypropylene as an eg intercalater and the compatibilizer of pp - pa66, based on the state - of - art development in the realm of polymer / inorganic nanocomposites and polymer / polymer in - situ composites domestically and overseas. the main outcomes are obtained as follows : 1
本論文以制備和研究新型高性能聚合物導電復合材料為目的,跟蹤和借鑒國內外在聚合物無機物納米復合、聚合物聚合物原位復合領域的最新研究成果,制備和研究了以聚丙烯( pp )為基體、膨脹石墨( eg )為導電填料、尼龍66 ( pa66 )為改性劑、馬來酸酐接枝聚丙烯( gpp )為eg插層劑和pp ? pa66增容劑的二元及多元導電納米復合材料和納米復合與原位復合組合復合材料,取得了以下主要研究成果: 1The prepn. of dimethyldiallylammonium chloride monomer and the related polymers was summarized, and the use of the derivatives in text, dyeing and printing as antistatic, color fixing and flocculating agents were presented
摘要簡述了二甲基二烯丙基氯化銨單體及其相關聚合物的制備方法,介紹了聚二甲基二烯丙基氯化銨及其衍生物產品在紡織印染行業中作為抗靜電劑、固色劑和絮凝劑的應用。Finally, through interpenetrating polymer networks, a complex rubber in which the blended rubber servers as the first network and polyacrylate as the second network was derived
以該共混橡膠作為第網路,再與甲基丙烯酸酯互貫聚合物網路,制得ipns復合橡膠阻尼材料。Polybutadiene is changed to an aziridinyl compound (polybutadieneimine) by a series of reactions.
聚丁二烯經一系列反應轉變成丙啶基化合物(聚丁二烯亞胺)。Polybutadiene is changed to an aziridinyl compound ( polybutadieneimine ) by a series of reactions
聚丁二烯經一系列反應轉變成丙啶基化合物(聚丁二烯亞胺) 。Besides, it was founded that the compatible of the system consisted of mts - mma copolymer and pmma was better than that of pmts / pmma
應用dma , dsc , uv及水滴接觸角等測試手段表徵了有機硅聚合物-聚甲基丙烯酸酯梯度膜的性能。Then properties of the polysilane - polyacrylate gradient films were characterized. the mechanism of film forming process of polysilane - polyacrylate fgm was probed into as well
並對所制得的有機硅聚合物-聚甲基丙烯酸酯梯度膜的性能進行了表徵,對其成膜機理進行了探討。To prepare the functionally gradient materials ( fgm ) of polysilane - polyacrylate, the method of solution preparation was performed. based on the results of the back - scattered electron images and linear scanning of the polysilane - polyacrylate film ' s cross section, the dependence of polysilane - polyacrylate film ' s structure on molecules of polysilane and polyacrylate, pmma / pmts feed ratio and component concentration were investigated
通過測試有機硅聚合物-聚甲基丙烯酸酯樹脂膜的結構,分析了聚有機硅( pmts ) 、聚甲基丙烯酸酯( pmma )的分子量、 pmma pmts體系配比、組分濃度等因素對有機硅聚合物-聚甲基丙烯酸酯樹脂膜結構的影響。In this paper, interpenetrating polymer networks ( ipn ) based on polysiloxane ( pdms ) and poly ( methyl acrylate ) ( pma ) were prepared by using ma monomer and two types of pdms, which viscosities were 3300pa s and 7000pa s respectively. pdms was crosslmked by tetraethyl orthosilicate
本論文制備了聚二甲基硅氧烷與聚丙烯酸甲酯的序列半互穿聚合物網路,其中聚硅氧烷為交聯結構,採用粘度分別為3300pa ? s和7000pa ? s兩個品種,聚丙烯酸甲酯為線性聚合物。The innovations of this novel vegetable - gum drilling fluid started with the investigations of vegetable - gums, synthetic high polymers, base modifiers, and coupling agents. through laboratory tests, we make sure that the constituents of this drilling fluid, named kl vegetable - gum drilling fluid by us, should consist of kl gum, hyper - php ( h - php ), and naoh, and by means of mathematical orthogonal tests, we got its optical compositions, and carried out laboratory tests regarding its behaviours
同時,為確定新型植物膠沖洗液的配方和組分,我們還對植物膠、合成高分子聚合物、改性處理劑進行了廣泛的調研,並通過室內試驗進行優選,最終確定新型植物膠沖洗液為苦藶豆膠沖洗液,基本三組分為:苦藶豆膠( kl ) 、超級水解聚丙烯酰胺( h - php )和燒堿( naoh ) ;進而,通過正交試驗確定該沖洗液優化配方,並進行相應的性能評價。Based on the liquid crystal polymer theory, two kinds of polyacrylates were synthesized by choosing biphenyl group as rigid nucleus of mesophase group and six methylene chain as flexible spacing group. an important chiral additive was synthesized by choosing l ( - ) ~ 2 - octanol as chiral group. mixture was made of the additive and liquid crystalline polymer, which structure was identified by ftit, " ii nmr, dsc and pom
本論文根據液晶分子結構理論,選擇聯苯基作為介晶基元的剛性核、柔性的六亞甲基脂肪鏈為柔性間隔基,與丙烯酸反應,合成了兩種丙烯酸酯型聚合物;以拆分的l ( - ) 2 -辛醇為手性基團合成了一種液晶手性添加劑,並將所合成的手性添加劑與液晶聚合物共混,採用ftit 、 ~ 1h - nmr 、 dsc 、 pom等手段對合成的化合物、共混物進行了表徵。Polymer networks have been produced in a variety of liquid crystal phases in cells without surface treatment. the liquid crystal / monomer mixtures are prepared using a ferroelectric liquid crystal and a diacrylate monomer. the polymerisation of the monomer is carried out by uv curing the mixture when it was kept in a specific phase which can be obtained by controlling the temperature of the ferroelectric liquid crystal. both the monomer and the polymer network will depress phase transition temperatures. the effects of the polymer network on the packing arrangement of the ferroelectric liquid crystal molecules are examined by means of optical microscopy. the molecular packing arrangement of the ferroelectric liquid crystal in a specific mesogenic phase is frozen on the formation of a polymer network in the ferroelectric liquid crystal in that phase. the existence of the diacrylate based polymer network can improve the electrooptical switching of the ferroelectric liquid crystal
在灌裝于未經表面處理的樣品盒內處于不同狀態的液晶中制備聚合體網路.液晶/單體混合物由鐵電液晶和雙丙烯酸單體製成.單體的聚合通過維持該混合物處在一定的液晶態的條件下經紫外線固化來完成.不同的液晶態可通過控制鐵電液晶的溫度來獲得.雙丙烯酸單體或聚合體網路的存在會導致鐵電液晶載體的相變溫度降低.通過光學顯微鏡可觀察聚合體網路對鐵電液晶分子組合排列的影響.結果發現:在某一液晶態中鐵電液晶分子的組合排列可被在該液晶態中聚合而成的聚合體網路所穩定,雙丙烯酸基聚合體網路的存在可改良鐵電液晶的電光開關特性Then, surface tension measurements on various solution of pmma, pmts, mts - mma copolymer indicated that the change of polysilane ' s surface tension was not significant when its concentration was lower than 30 %, while that of polyacrylate ' s varied much more significant yet
隨之,用溶液聚合法制備了具有不同分子量及分子量分佈的有機硅聚合物、有機硅-丙烯酸酯共聚物( mts - 35 、 mts - 65 )和甲基丙烯酸酯聚合物。分享友人