熱解反應性 的英文怎麼說
中文拼音 [rèjiěfǎnyīngxìng]
熱解反應性
英文
thermolytic reactivity-
In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術，有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應，提高了聚合物大分子鏈中有機硅鏈節的含量；利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵，並通過對共聚產物力學和吸水率的測試，證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能；從分子設計角度出發，利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體： ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷；利用核磁共振對新型硅烷單體結構進行了證實；研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液，且其聚合產物具有較高的力學及耐水性能。The results indicated that the dimension, shape and purity of base material could meet the functional demand of solid lubricant ; the thermal decomposition temperature of ptfe resin exceeds 400 c, but organic and inorganic packing filler added in ptfe made the water absorption rate of composite material increased, melting temperature and decomposition temperature decreased, in the meanwhile oxidative decomposition reaction was accompanied ; polar groups such as c = o, c - o - c and so on in the carbon fiber surface is advantageous to increase compatibility with other components and interlayer shearing strength ; uniform design experimental method could help to find the relationship between formula and frictional property by relatively small tests. the developing trend of each formula ' s friction coefficient could be showed by fitting curve ; the friction coefficient with no copper powder or graphite in formula was relatively big. this fact showed that copper powder and graphite should be used cooperatively ; it was found that when the ratio of copper powder to graphite by weight is 15 : 60, 30 : 30 - 40 and 60 : 15 - 30 respectively, the friction coefficient was relatively small. the degree of crystallinity of pure ptfe reached maximum by air cooling and the abrasion loss also reached maximum among three ones ; at the same time, the abrasion loss of solid lubricant sample was also the biggest among three ones ; when solid lubricant matched with 45 # steel axle or gcrl5 steel axle, lubricant transfer film could be formed on metal surface, thus direct contact between the surface of metal friction pair rings was reduced. their working life was elongated extremely ; there was mainly much graphite, a little ptff, moo3, feso4, cus and so on in lubricant transfer film
試驗結果表明：所選原料的尺寸、形狀及純度可滿足固體潤滑劑的性能要求；聚四氟乙烯樹脂熱分解溫度超過400 ，但在ptfe中加入無機填料會使復合材料吸水率提高，熔融溫度及分解溫度降低，且伴有氧化分解反應；碳纖維表面含有c = o及c - o - c等極性基團，有利於提高其與其它組分的相容性，提高層間剪切強度；均勻設計試驗方法能夠用較少的試驗次數找出配方與摩擦性能間的關系，擬合曲線基本能表示各配方的摩擦系數發展趨勢；配方中不加銅粉或不加石墨，其摩擦系數均較高，說明銅粉和石墨應該配合使用；當銅粉15份、石墨60份時，銅粉30份、石墨30 - 40份時，銅粉60 、石墨15 - 30份時，摩擦系數均具有較低值；純聚四氟乙烯樹脂在空氣冷卻時結晶度最大，磨損量也是三者中最大的；同時，固體潤滑劑試樣在空氣冷卻時的磨損量也是三者中最大的：不論是固體潤滑劑與45 #鋼軸配副或是固體潤滑劑鑲嵌入銅套后與gcr15鋼軸配副，在金屬表面均可形成潤滑轉移膜，從而減少金屬摩擦副表面間的直接接觸，大大延長其使用壽命;轉移膜中主要含有較多的石墨、少量聚四氟乙烯、 moo 。Solution vinyl are thermoplastic, but some cross - linking may be accomplished when reactive groups are present
可溶解乙烯基樹脂是熱塑性樹脂，當有反應基團存在時，可發生交聯反應。By virtue of the experiments carried out on the modified pilot - scale biomass gasification system, the temperature field in the gasifier is made explicit. and also some principles about how the temperature, feedstock and extraction mode exert influences on heat value and production rate of gas are attained. in addition, some tentative tests of tar cracking and thermodynamic characteristics of biomass gas burner have been performed, which are that indispensable to design and operation of biomass gasification demonstration project
接著，通過對生物質中熱值氣化中試試驗系統的多次改造和反復試驗，了解了氣化爐內溫度場分佈，得出了溫度、物料、抽氣方式等因素對生物質熱解氣的成分、熱值和產氣率影響的一些基本規律，並進行了初步的焦油催化裂解試驗和煤氣燃燒器的熱力特性、燃燒特性試驗，為面向工程應用的集中供氣示範項目提供了必要的設計和運行依據。Abstract : during the heating of scrap with carbon or hydrocarbon contented substances in some process, it will bring problems like explosion of carbon monoxide, fume and smell from oil volatilization, etc. ， if incomplete combustion occurs. through laboratory experiments, the time related variation of gas contents and post combustion ratio of fume during the heating of oil - bearing scrap are studied. the results show that the restrictive chain of reaction procedure is the thermolysis of oil ; that temperature and ( co ) / ( co2 ) ratio influence transformation ratio and post - combustion ratio under lower temperature ; that 900 is the temperature above which the complete reaction can be ensured at all ( co ) / ( co2 ) ratios
文摘:在某些廢鋼熔煉過程中，當爐料中含碳及碳氫物質且燃燒不充分時，會帶來煙氣中一氧化碳的燃爆、油污揮發時造成的煙霧、臭味等問題.通過實驗室裝置研究含油廢鋼在加熱過程中煙氣成分隨時間的改變以及二次燃燒率的變化，試驗結果表明，反應過程的限制性環節是油分的熱分解；在較低的溫度下（ co ） / （ co2 ）比例影響轉化率和二次燃燒率；而在任意比例下保證充分反應的溫度為900以上Tar content in the gas was influenced by the gasification conditions, such as the gasification temperature, residence time of feedstock in the gasifier and the type of feedstock, which can help us to investigate the mechanism of tar production in gasification process. catalytic cracking of tar was performed in a downstream secondary fixed - bed cracker with dolomite, limestone and alumina brick as catalysts. by comparison, thermal cracking of tar was also performed with silica carbide
在固定床二級催化裂化反應器上，實驗了白雲石、石灰石、高鋁磚等幾種催化劑作用下的焦油催化裂化過程以及炭化硅作用下的熱裂化過程，並對裂化溫度（ 650 950 ） 、氣相停留時間（ 0 . 5 1s ）和催化劑類型等過程參數對焦油轉化效果和熱解煤氣的影響進行了分析，對各種催化劑材料的性能進行了比較，力爭開發出可適用於工業化生物質氣化系統的焦油催化裂化技術。Because of its excellent properties, such as high strength, high module, wear resisting, and etc., sicp was added to ferroalloy as a reinforce phase. but the intrinsic difference between the bonds led to poor fabrication of the composites. in this paper, the effects of alloying, sintering, and heat - treatment on the properties and microstructures of sicp / ferroalloy - based composites were studied, : it was found that sic particles reacted with ferroalloy when sintered in 1100
碳化硅因其高強度、高模量、耐熱、耐磨等優良性能而被作為顆粒增強體來制備鐵基復合材料，但因其共價鍵與鐵基體的金屬鍵之間的本質區別導致兩者復合困難，本文擬從基體合金化、燒結及熱處理工藝等方面對鐵合金基復合材料組織與性能的影響進行考察，具體內容如下：加入fe - cu - c基體中的sicp顆粒， 1100燒結時就已經開始發生分解，但反應不強烈，在顆粒表面鍍鎳可以延緩基顆粒與基體之間的反應。By increasing the h2 dilution ratio, it is found that atomic hydrogen can selectively etch amorphous phase and stabilize crystalline phase. from the study on the distance from substrate to catalyzer, choosing a proper distance can ensure the gas fully decomposed, while a relatively low substrate temperature can cause the nanocrystalline particles to lose mobility and keep their sizes. the pre - carbonization process can enhance the nucleation density and make the growth of high quality nanocrystalline p - sic films much easier
實驗結果表明：隨著工作氣壓的減小，薄膜的晶粒尺寸有所減小；通過提高氫氣稀釋度，利用原子氫在成膜過程中起的刻蝕作用，可以穩定結晶相併去除雜相；選擇適當的熱絲距離能保證反應氣體充分分解，又使襯底具有較高的過冷度，是形成納米薄膜的重要條件；採用分步碳化法可以提高形核密度，有利於獲得高質量的納米- sic薄膜；襯底施加負偏壓可以明顯提高襯底表面的基團的活性，因負偏壓產生的離子轟擊還能造成高的表面缺陷密度，形成更多的形核位置。Thermodynamic properties for the dissolution of nickel orthoperiodate hydrate
水合正高碘酸鎳鹽溶解反應的熱力學性質A mathematic model of reactor, steam generator, pressurizer is developed based on characteristic of pwr coolant system. for reactor, the point reactor kinetics equation with six - group delayed neutrons is used and influence of coolant ' s and fuel ' s temperature is considered, conduction model of one dimension and single - channel model is used in thermal and hydraulic calculation, third - order hermite polynomial is used to solve the point reactor kinetics equation
對于反應堆，在物理計算中採用了帶有六組緩發中子的點堆方程，同時考慮了多普勒效應及冷卻劑溫度效應對反應性的影響；在熱工水力計算中採用了一維的熱傳導模型與單通道模型；在求解點堆方程中採用了hermite插值的方法，克服了點堆方程的剛性問題。Coal - char pyrolysis, firing, burnt and limestone calcination under o _ ( 2 ) / n _ ( 2 ) oro _ ( 2 ) / co _ ( 2 ) atmosphere were carried on a thermobalance. limestone calcination and sulfuration under o _ ( 2 ) / co _ ( 2 ) atmosphere were tested on a bench scale fluidized bed facility. the characteristics of coal combustion and pollutant emission under o _ ( 2 ) / n _ ( 2 ) or o _ ( 2 ) / co _ ( 2 ) atmosphere were experimented on a circulating fluidized bed multi - function test - facility
在熱天平上進行o _ 2 / n _ 2氣氛與o _ 2 / co _ 2氣氛下的煤焦熱解、著火與燃燼反應動力學及石灰石煅燒分解特性研究；在小型流化床試驗臺上進行石灰石在o _ 2 / co _ 2氣氛下的煅燒與硫化反應特性研究；在設計、搭建的循環流化床多功能綜合試驗臺上進行o _ 2 / n _ 2氣氛與o _ 2 / co _ 2氣氛下的煤燃燒特性與污染物排放規律研究。Carbonaceous materials used in the production of aluminium - baked anodes - determination of the reactivity to carbon dioxide - thermogravimetric method
鋁生產用含碳材料.焙燒陽極.對二氧化碳反應性的測定.熱解重量分析法Studying the heat - mass transfer and multi - spices electric - chemical reaction, a dynamic temperature model was deduced for molten - carbonate fuel cell stack. the thermal radiation, shift reaction, and the change of gas spices were considered in this model. establishing momentum equation, the paper has developed a 3d temperature and flow fields model for mcfc stack based on cfd technique
建立了熔融碳酸鹽燃料電池堆內部單體的暫態溫度模型，並考慮了電堆的輻射換熱、轉換反應、反應氣體組分變化對溫度場的影響；根據mcfc的微分控制方程組，考慮氣體組分的熱力學性質及動量變化的影響，利用數值分析方法求解熔融碳酸鹽燃料電池堆的三維流場與溫度場，分析了各作用因素對熔融碳酸鹽燃料電池堆溫度分佈的影響機制。B ) the concept of ratio of conversion ; c ) effect of temperature and residence time on tar conversion ratio ; increasing the temperature and residence time is beneficial to tar cracking, and the effect is not evidence when t > 900c and > 1. 0s d ) effect of cracking temperature on the tar conversion ratio with sic ; e ) effect of different catalyst on the tar conversion ratio ; some catalyst was test in the experimental system and dolomite is a most promising one
研究了生物質焦油含量隨熱解溫度和生物質原料的變化趨勢，提出了生物質焦油裂解率的概念、探討了不同條件（熱解溫度、停留時間）下熱裂解的效果和不同催化劑，不同反應條件下對焦油催化裂解效果的影響，催化劑在使用過程中由於積碳、中毒等原因會使得活性喪失，本文針對催化劑活性的喪失以及再生進行丁試驗研究和理論分析。The result of experiment showed that the reaction between ti and c is a thermodynamic course, when 2 wt % mg is added to melt, it can restrain the formation of fragility phase al3ti, and gained al matrix composite which contained tic reinforced particles only. because mg reacts with the forms a micro - high temperature field around the oxide around the graphite particles and the oxygen gas which is brought by the immersion bell, and the reaction gives out a lot of heat energy, thus forms many high micro - fields in melt, which prompt the reaction between the al and ti
加入適量的mg （ 2wt ）可以抑制tic al復合材料中的脆性相al _ 3ti的產生，生成僅含tic的鋁基復合材料；由於活化劑鎂在體系中與石墨顆粒周圍的氧化物、以及外來的氧反應放熱，在熔體中形成微高溫區，促進al - ti反應，同時， al - ti反應也是放熱反應，因此體系中的內能急劇增大，促使al _ 3ti分解以及ti朝c顆粒擴散，縮短反應的孕育時間。Numerical simulation by cfd was carried out to understand the hot current behavior in a tunnel with longitudinal ventilation. it becomes clear that fire source modeling is very important because the hot current behavior is strongly affected by the fire source position and is sensitive to methods in the modeling of the fire source. the flame area which has developed from the fire source is an area of chemical reaction caused by combustion. even if grids in the vicinity of the fire source are made fine, it was difficult to simulate the heat generation area with consideration to this chemical reaction through using a method for setting the heat release rate simply on the fire source surface. therefore, we proposed a method adopting the knowledge on flame shape under the longitudinal ventilation and incorporating it into numerical simulation and it showed a good agreement with the experimental results. it was shown through experiments in a tunnel with longitudinal ventilation that the hot current developed toward the tunnel center downwind from the fire source near a wall. the cause was investigated by numerical simulation and it became clear from the results that the spiral air by the fire plume created a vortex in the crevice between the wall and the plume
運用cfd進行數字模擬，以了解縱向通風隧道內熱煙氣流的特性.通過模擬發現對火源進行模擬非常重要，熱煙氣流特性受火源位置的影響很大，並且對火源模擬方法很敏感.火源生成的火焰區是燃燒引起的化學反應區域.即使火源附近的木垛排列完好，也很難在考慮這些化學反應條件下模擬熱生成區域.建議考慮縱向通風隧道內火焰形狀並對它進行數字模擬.模擬結果與試驗結果非常吻合.試驗證明，在縱向通風隧道內，熱煙氣流從靠近墻體火源處順風向隧道中心蔓延.數字模擬結果發現，火災羽流造成的螺旋上升空氣會在墻體和羽流之間形成一個渦流區Abstract : numerical simulation by cfd was carried out to understand the hot current behavior in a tunnel with longitudinal ventilation. it becomes clear that fire source modeling is very important because the hot current behavior is strongly affected by the fire source position and is sensitive to methods in the modeling of the fire source. the flame area which has developed from the fire source is an area of chemical reaction caused by combustion. even if grids in the vicinity of the fire source are made fine, it was difficult to simulate the heat generation area with consideration to this chemical reaction through using a method for setting the heat release rate simply on the fire source surface. therefore, we proposed a method adopting the knowledge on flame shape under the longitudinal ventilation and incorporating it into numerical simulation and it showed a good agreement with the experimental results. it was shown through experiments in a tunnel with longitudinal ventilation that the hot current developed toward the tunnel center downwind from the fire source near a wall. the cause was investigated by numerical simulation and it became clear from the results that the spiral air by the fire plume created a vortex in the crevice between the wall and the plume
文摘:運用cfd進行數字模擬，以了解縱向通風隧道內熱煙氣流的特性.通過模擬發現對火源進行模擬非常重要，熱煙氣流特性受火源位置的影響很大，並且對火源模擬方法很敏感.火源生成的火焰區是燃燒引起的化學反應區域.即使火源附近的木垛排列完好，也很難在考慮這些化學反應條件下模擬熱生成區域.建議考慮縱向通風隧道內火焰形狀並對它進行數字模擬.模擬結果與試驗結果非常吻合.試驗證明，在縱向通風隧道內，熱煙氣流從靠近墻體火源處順風向隧道中心蔓延.數字模擬結果發現，火災羽流造成的螺旋上升空氣會在墻體和羽流之間形成一個渦流區And the chemical reactions in the pyrolysis process were also discussed
並對輪胎熱解的化學反應過程進行了總結性的討論。The combustion conditions in a circulating fluidized bed ( cfb ) boiler are much different from a pulverized coal firing ( pf ) boiler. however, this dissertation has confirmed that coal char in cfb boiler will also experience reactivity loss and ordering of turbostratic carbon structure, which have been reported by many researchers whose work were mainly restricted to pf conditions
本文通過獲得在cfb燃燒條件下熱解和燃燒過程中的焦碳，對其反應性、亂層碳結構、礦物質催化作用和比表面積等進行了系統研究，指出cfb鍋爐和煤粉爐同樣存在焦碳亂層碳結構有序化和焦碳反應性下降（失活）現象，並全面分析了焦碳失活的機理。Meanwhile, the structural stability of delithiated cathode materials is also improved by ti doping. it results in the suppression of thermal decomposition reaction of delithiated cathode material, which will produce heat and oxygen gas as the fuse of electrolyte decomposition and combustion reaction. hence, thermal stability of delithiated cathode material is also enhanced by ti doping
同時，欽的摻雜增強了電極材料在脫鏗狀態下的結構穩定性，抑制了電極材料自身熱分解反應的發生，阻止了氧氣和熱量的釋放，減少或延遲了電解液的分解或燃燒反應，從而提高了電極材料的熱穩定性。分享友人