In order to improve the electro - catalytic activity of platinum based catalyst to methanol oxidation, in this thesis, firstly prepare heteropoly acid modified pt / gc electrode with different concentration by cyclic voltammetry method, and then test the cyclic voltammetry curves individually in vitriolic and methanol solution. the study shows the best concentration for both phosphomolybdic acid and phosphotungstic acid is 1 10 ~ ( - 3 ) mol / l. and find the more heteropoly acid modified on electrode, the lower peak - up potential towards methanol because of the existence of oxygenous species
為了改善鉑基催化劑氧化甲醇的催化活性,本論文首先通過循環伏安掃描法制備了不同濃度磷鉬
酸和磷
鎢酸修飾的pt / gc電極,通過研究pt / gc電極在修飾前後在硫
酸溶液中及含甲醇的硫
酸溶液中的循環伏安行為發現,磷鉬
酸和磷
鎢酸均能在ptru / c電極上發生氧化還原反應,而且雜多
酸修飾濃度對pt / gc電極氧化甲醇的催化活性有很大影響。
The main conclusions with innovative features acquired from the present work are as follows : ( 1 ) soft solution processing technique for preparing functional thin films was put forward and applied to preparing advanced inorganic functional thin films ; a series of molybdate and tungstate films with scheelite - type were prepared directly on metal substrates ( molybdenum and tungsten foils ) by using constant current electrochemical technique at room temperature ; a series of titanate thin films with perovskite - type were synthesized directly on titanium flakes by hydrothermal method in our country for the first time
通過上述研究工作,得到了如下具有創新性研究成果: ( 1 )首次在國內提出和運用軟溶液制備工藝技術進行無機功能薄膜材料的制備研究;首次在國內採用室溫恆電流電化學技術直接在金屬基底(鉬片和
鎢四川大學博士學位論文片)制備了白
鎢礦結構的鋁
酸鹽、
鎢酸鹽薄膜;首次在國內採用水熱合成技術在欽金屬片上直接沛叮備了鈣欽礦結構的欽
酸鹽薄膜。
Non - debye dielectric spectroscopy of lead tungstate crystals
鎢酸鉛的非德拜型介電譜
Calcium tungstate middle speed intensifying screens for medical use
鎢酸鈣中速醫用增感屏
A study on the mechanism of localized corrosionof stainless steel by tungstate
鎢酸根對不銹鋼局部腐蝕的作用
The ammonium tungstate igniting gravimetric method for the determination of tungsten trioxide content
鎢酸銨灼燒法測定三氧化
鎢量
Method for the determination of sodium tungstate content in sodium tungstate for import and export
進出口
鎢酸鈉中
鎢酸鈉含量的測定
Medical x - ray films used with intensifying screens ; sensitometric simulation of the fluorescent radiation of calcium tungstate intensifying screens
增光屏用x射線膠片
鎢酸鈣增光屏熒光射線感光模擬
Methods for chemical analysis of tungsten concentrates - the ammonium tungstate igniting gravimetric method for the determination of tungsten trioxide content
鎢精礦化學分析方法
鎢酸銨灼燒法測定三氧化
鎢量
Technological practice of producing tungstic acid using waste catalyst containing tungsten
利用含
鎢廢催化劑生產
鎢酸工藝實踐
Industrial experience of producing tungstic acid using waste catalyst containing tungsten
利用含鎢廢催化劑生產鎢酸的工業實踐