free energy of solution 中文意思是什麼
free energy of solution
解釋
溶解自由能-
The thermodynamic free energy on mixing and the spinodal equation in ternary homopolymer blends were obtained by making plausible approximation based on flory ' s equation of state theory. because of the non - linear behavior of the spinodal equation, a numerical solution approach was used and succeeded in solving the problem. spinodal of polystyrene ( ps ) / poly ( vinyl methyl ether ) ( pvme ) / poly ( 2, 6 - dimethyl - 1, 4 - phenylene oxide ) ( ppe ) were simulated over a wide temperature range and the calculated result was coincidence with that of the literature
將上述方法用於已知狀態方程參數的二元均聚共混體系聚苯乙烯（ ps ） /聚甲基乙烯基醚（ pvme ） ，三元均聚共混體系聚苯乙烯（ ps ） /聚甲基乙烯基醚（ pvme ） /聚2 ， 6 -二甲基1 ， 4 -苯撐氧（ ppe ） ，得到一系列不同溫度下的spinodal相圖，預測結果與文獻報道吻合，在此基礎上進一步研究了聚合物的分子量對體系相行為的影響。 -
The research of gibbs free energy, critical nucleus radius, nucleation rate of homogeneous nucleation " and heterogeneous nucleation shows that the main reason decreasing solution stability is heterogeneous nucleation
通過分析非均相成核與均相成核的臨界成核半徑、臨界晶核形成功、成核速率等，說明降低溶液穩定性的主要因素是非均相成核。 -
The unstable solid solution would disintegrate and transform into carbide phases in these systems of sisocso, tisocso and zrsocso, based on the increase of free energy introduced by the effect mechanical alloying. for the system of wsocso, the solid solution had not transformed into tungsten carbides but an amorphous phase, which was different from those systems. the exist of fe in these experiments, which came from the abrasion of ball - milling tool because of the higher hardness of w and w - c solid solution, would induce the crystalline - to - amorphous phase transformation during milling
C50球磨體系中，繼續球磨時，不穩定的固溶體在機械合金化作用下，由於體系能量提高，會發生分解相變，從而可以形成碳化物；對于w扣c50球磨體系， w ? c固溶體具有較高的硬度，磨削不銹鋼質的球磨介質和球磨容器，而引入雜質，其中fe會促使固溶體向非晶相轉變。 -
The corrosion behavior of nanocrystalline ( nc ) copper bulks with various grain sizes prepared from igc ( inert gas condemsation ) and vacuum annealing in comparison with conventional microcrystalline ( mc ) copper ( as - rolled and electrolytic ) in acid copper sulphate solution and neutral solution containing chlorides under free corrosion conditions and anodic polarizations has been studied using potentiodynamic polarization, potentiometric analysis, cyclic voltammetry and electrochemical impedance spectroscopy. x - ray diffraction was used to estimate the grain size of the annealed nc copper. field emission gun scanning electron microscopy and x - ray energy - dispersive spectroscopy was used to characterize the surface morphology and analyze the surface composition after the polarization and potentiometric test of both nc and mc copper
本文研究了用igc （惰性氣體蒸發凝聚原位溫壓法）制備並真空退火到不同晶粒尺寸的納米晶銅和微米晶銅（冷軋紫銅、電解銅）在酸性硫酸銅溶液和中性含氯溶液中，在自腐蝕狀態和陽極極化狀態下的腐蝕性能。使用了動電勢極化、電位測定、循環伏安法（ cv ）和電化學阻抗譜（ eis ）等方法。 x -射線衍射（ xrd ）的方法用來估算納米晶銅晶粒尺寸。
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