The absorption isotherms are equilibrium equations.
Allen and co-worker did ab initio calculation to test the adequacy of scf mo calculations for predicting molecular equilibrium geometries.
Hence we may have to search for a suitable catalyst, to speed up attainment of equilibrium.
Another limitation is the lack of availability of accurate equilibrium constants.
Regaining new stable equilibrium he rose uninjured though concussed by the impact, raised the latch of the area door by the exertion of force at its freely moving flange and by leverage of the first kind applied at its fulcrum gained retarded access to the kitchen through the subadjacent scullery, ignited a lucifer match by friction, set free inflammable coal gas by turning on the ventcock, lit a high flame which, by regulating, he reduced to quiescent candescence and lit finally a portable candle