neodymium ion 中文意思是什麼
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We have prepared a series of neodymium binary / ternary complexes, such as nd ( acac ) 3 ' 2h2o, nd ( tfa ) 3 ' 2h2o, nd ( hfa ) 3 ' 2h2o, nd ( dbm ) 3 ' h2o, nd ( acac ) 3phen, nd ( tfa ) 3phen, nd ( hfa ) 3phen, nd ( dbm ) 3phen, nd ( tta ) 3 ( tppo ) 2, nd ( hfa ) 3 ( tppo ) 2, nd ( acac ) 4hpy, nd ( tta ) 4hpy and ndq3. the effects of organic ligands, synergistic coordination agents and different substitution groups for - diketones on effective line width and photoluminescence intensity of neodymium complexes were investigated. the photoluminescence spectra indicate that synergistic coordination agents can shield neodymium ion and impede water molecules penetrating into inner coordination shell to satisfy large coordination number of nd3 + during hydrous synthesis process, so the luminescence intensity of neodymium ternary complexes is stronger than that of neodymium binary complexes
發光光譜研究表明，由於協同試劑的參與，屏蔽了水分子參與配位，降低了羥基（ oh ）對釹離子激發態能級~ 4f _ （ 3 2 ）的猝滅，三元配合物的熒光強度均比二元配合物強，其中配合物nd （ tta ） _ 3 （ tppo ） _ 2在1340nm處的熒光強度最強，適合作為摻雜的光學活性物質，來制備有源光波導材料；在有水工藝條件下，單純地氟化配體未必能提高釹配合物的近紅外發光性能。 -
The first ytterbium - doped yttrium - aluminum garnet ( yb : yag ) laser action was reported back in 1965 using a lamp - pumped rod at 77 k. because of poor spectral overlap of the lamp with the the trivalent ytterbium ion ( yb3 + ) absorption band, the efficiency was very low. lamp - pumped nd : yag lasers fared better due to the multiple pump bands of neodymium
但yb3 +離子的泵浦吸收帶與閃光燈光譜匹配很差，導致其激光效率很低;而nd : yag的激活離子（ nd3 + ）有多個泵浦帶與閃光燈光譜匹配，較好適應了燈泵浦的需要，長期占據了固體激光器的主導地位。
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