redox couple 中文意思是什麼
redox couple
解釋
氧化還原電對-
In the first part of this paper, mn ( iii ) / mn ( ii ) couple in h2so4 was firstly applied as the positive couple to this system, i. e. redox flow cell. its chemical, electrochemical properties, redox kinetics and related parameters were characterized and discussed by rotating disc electrode ( rde ), cyclic voltammetry ( cv ), a. c. impedance ( a. c. imp ), chronoamperometry, tafel curve, and galvanostatic charge / discharge techniques. conclusions have been drawn as follows : 1. the electrochemical kinetics of mn ( iii ) / mn ( ii ) redox couple in 6. 3m h2so4 solution were studied by means of rotating disc electrode ( rde ) technique on platinum electrode
本文第一部分首次成功地將酸性介質中的mn （ iii ） / mn （ ii ）電對應用於氧化還原液流電池這一新型儲能裝置的正極活性材料，通過旋轉圓盤（ rde ） 、循環伏安（ cv ） 、交流阻抗（ a . c . imp ） 、恆電位階躍、 tafel實驗以及mn （ iii ） / mn （ ii ）單電極的恆流充放電實驗，我們得出以下結論： 1 .在旋轉圓盤電極上，不同轉速范圍，不同的極化過電位， mn （ ） / mn （ ）體系氧化還原電極過程的控制步驟不同，電荷傳遞、擴散傳質可分別或聯合成為控制步驟。 -
The potential of mn ( iii ) / mn ( ii ) redox couple in h2so4 is 1. 51v vs. nhe, which may be suitable for the positive half - cell in a redox flow storage system. but studies on this couple as a positive electrode in this system have not been reported so far
錳的各種氧化物是化學電源里常選用的活性物質，而將溶液狀態的mn （ iii ） / mn （ ii ）電對作為化學儲能裝置的活性材料的工作尚未見報道。 -
And the kinetic parameters of mn ( iii ) / mn ( ii ) redox process were calculated to be ks = 1. 771 10 - 4cm ? s - 1, io = 4. 801ma ? cm - 2 and = 0. 234. the value of ks is sufficient to warrant further study to improve the reaction rate and to assess the feasibility of this couple as positive half - cell in a redox - cell system
Mn （ ） / mn （ ）體系在鉑盤電極上的標準速率常數ks的值說明可進一步研究來提高其反應速率，從而將mn （ ） / mn （ ）電對作氧化還原液流電池的正極材料。 -
The redox of v ( ) / v ( ), v ( ) / v ( ) couple on the graphite displayed one electron quasi - reversibility. it is proved that trace in3 +, sb3 + can inhibit cathodic hydrogen evolution during the charge process by increasing the hydro - gen overvoltage in addition that sb3 + is a stabilizing / kinetic enhancing ion. during the charge / discharge process, cross - mix and self - discharge rarely happened. the maximal energy density of the lab - level vanadium battery is 21 wh / kg. the capacity efficiency of the lab - level vanadium battery is as high as 94. 7 %
釩電池充電末期，會發生水的電解反應，痕量銦離子的加入提高了析氫過電位，抑制了充電過程中負極氫氣的析出；銻離子的加入不僅可以抑制氫氣的析出，還提高了正極反應速率，增強了正極表面的穩定性。實驗中得到的最高質量比能量為21wh / kg ，充放電過程中僅有極少的交叉混合和自放電發生，自製釩電池的容量效率可高達94 . 7 % -
This paper covers two parts. the first part reported mn ( iii ) / mn ( ii ) couple was used to be the cathode in a redox flow cell. the second one studied tin - based materials for anodes in lithium - ion batteries
本文共分兩部分，第一部分對mn （ iii ） / mn （ ii ）電對作為氧化還原液流電池正極材料的可行性進行研究；第二部分對鋰離子電池錫基負極材料進行制備、表徵及電化學性質研究。
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