熱電化學 的英文怎麼說
中文拼音 [rèdiànhuàxué]
熱電化學
英文
thermoelectrochemistry-
The structures and characteristics of several graphite samples are measured by means of powder x - ray diffraction ( xrd ), brunauer - emmer - teller ( bet ) surface area measurement, inductively coupled plasma ( icp ) spectroscopy, particle size analysis and electrochemical measurements. the effects of origin, structure, impurity, particle size, specific surface area of carbon materials on the electrochemical characteristics are studied. a synthetic graphite with abundant resources, low cost and favorable performance is determined as the raw material for modification of graphite
採用xrd 、 bet 、 icp 、激光粒徑分析及電化學性能測試等方法,對國內外多種典型石墨樣品的結構與性能進行比較,研究石墨材料的來源、晶體結構、雜質含量、顆粒大小、比表面積等因素對其充放電性能的影響,確定一種性能較好、價格低廉、來源廣泛的普通人造石墨粉作為熱處理與摻雜改性、以及復合結構炭材料研究的原材料。The difference of reactive mechanisminduced the difference of their structure. v _ 2o _ 5 product prepared by melting - cooling showed more notable undefined structure. after heat - treating under300, particle size becomes smaller, and aggregate to globate grain, showesbetter electrochemical performance at low charge - discharge rate
熔融淬冷法合成的樣品其無定型結構更明顯,前驅體經過300熱處理后,材料的粒徑變細,團聚成球狀的顆粒,球狀特徵更顯著,在低倍率下具有較好的電化學性能。Ionic liquids are extensively studied in areas of chemical synthesis, separation technology, electrochemistry and material processing due to their unique properties such as high electrical conductivity, high thermal stability, low measurable vapor pressure and incombustibility
摘要由於離子液體具有電導率高、熱穩定性好、蒸氣壓低、不燃燒等優良性質,越來越多地應用於有機合成、分離、電化學和材料加工等領域。The main conclusions with innovative features acquired from the present work are as follows : ( 1 ) soft solution processing technique for preparing functional thin films was put forward and applied to preparing advanced inorganic functional thin films ; a series of molybdate and tungstate films with scheelite - type were prepared directly on metal substrates ( molybdenum and tungsten foils ) by using constant current electrochemical technique at room temperature ; a series of titanate thin films with perovskite - type were synthesized directly on titanium flakes by hydrothermal method in our country for the first time
通過上述研究工作,得到了如下具有創新性研究成果: ( 1 )首次在國內提出和運用軟溶液制備工藝技術進行無機功能薄膜材料的制備研究;首次在國內採用室溫恆電流電化學技術直接在金屬基底(鉬片和鎢四川大學博士學位論文片)制備了白鎢礦結構的鋁酸鹽、鎢酸鹽薄膜;首次在國內採用水熱合成技術在欽金屬片上直接沛叮備了鈣欽礦結構的欽酸鹽薄膜。" in recognition of his work in thermochemistry
對電化學和熱力學的研究Electrode materials have effects on properties of electrochemical capacitor, many carbonaceous materials such as active carbon, pyrolytic carbon, active carbon fiber and carbon nanotube were mainly used in electric double - layer capacitor. because of synthetic conditions and cost, we studied their electrochemical properties of electronic double - layer capacitor that pyrolytic carbon was used as their electrode materials
電極材料是影響電化學電容器性能的主要因素之一,應用於雙電層電容器的電極活性物質主要是各種碳材料,如各種活性炭、熱裂解碳、碳纖維、碳納米管等,考慮到合成工藝和成本因素,我們採用熱裂解碳為雙電層電容器的電極材料,並研究了它們的電化學性能。The effects of the fabrication conditions on the crystal structure, grain size, micromorphology and electrochemical performance of these materials have been studied in depth. the reaction mechanism of the low - heating solid - state reaction method has also been investigated. in addition, a novel electrochemical method ( rpg method ) based on the concept of " ratio of potentio - galvano - charge capacity " has been for the first time developed to determine the diffusion coefficient of lithium - ion within insertion - host materials on the basis of the spherical diffusion model
本論文較系統地考察了低熱固相反應法合成鋰離子電池正極材料的可行性問題,研究了工藝條件對材料的晶體結構、晶粒尺寸、微觀形貌及電化學性能等的影響,探討了低熱固相反應的機理,並通過引進「恆壓-恆流充電容量比」的概念,給出了一種測定鋰離子嵌入脫出固相擴散系數的新方法。The process of flashing involves ionization on the dirty surface concerning the factors of electric, heat and chemicals, thermal dynamic equilibrium process of local electric arc occurrence and development
污閃是一種與電、熱和化學因素有關的污穢表面氣體電離及局部電弧發生、發展的熱動力學平衡過程。Secondly, the sorts and weights of the components of the gel electrolyte are optimized, and a gpe with excellent performance is prepared, whose ion conductivity reachs 9. 2ms / cm. we analyze all the factors influencing the performance of the gpe, and study many performances of the gpe, including the microstructure, conductivity performance, liquid electrolyte holding ability, electrochemical stability, thermodynamics stability, and interfacial stability between electrolyte and electrode, et al
其次,對gpe各組份進行了改進和優化,找到了最佳的配比,制備了性能良好的凝膠電解質,該gpe的室溫離子電導率最高可達9 . 2ms cm ;考察了影響凝膠電解質性能的各種因素;研究了凝膠電解質的微觀結構、導電性、保液性、電化學穩定性、熱力學穩定性以及電解質與電極間的界面穩定性等性質。The results show that mno which not be modified can not be use as electrode active materials because of its poor electrochemical activity. meanwhile, the rechargeabilify of mno modified by bi and pb is improved. bismuth could prolong the second electron equivalent discharge and lead could improve the first electron equivalent discharge performance
I44 )對熱分解產物進行了充放電,循環伏安,恆電流極化, tafe曲線分析,交流阻抗分析,得出未摻雜的mno直接作為電極活性材料,其電化學活性很差,但通過摻bi , ph進行改性,提高了其可充性, 1的影響主要在於第二電子放電, ph則可以延長第一電于放電Zhang x d, zhao y, zhu f, et al. fabrication of high growth rate solar - cell - quality c - si : h thin films by vhf - pecvd [ j ]. chinese physics, 2004, 13 ( 8 ) : 1370
汪六九,朱美芳,劉豐珍,等.熱絲化學氣相沉積技術低溫制備多晶硅薄膜的結構與光電特性[ j ] .物理學報, 2003 , 52 ( 11 ) : 2934 - 2937Dna electrochemical biosensors have received much attention due to the high sensitivity, specific, rapid response, easy handling, compatibility with miniaturization technology, and low cost
Dna電化學生物傳感器具有dna雜交反應高度的特異性,又具有電化學傳感器靈敏度高、響應快、操作簡便、微型化、價格低廉等顯著優點,成為近年國內外研究熱點。The charge and discharge performances of different composites were studied by the charge and discharge ; the structures of composites were characterized by sem ; the electrochemical properties of sulfur positive materials were characterized by cyclic voltammetry and eis. we studied the charge process, discharge process, charge - discharge efficiency, self heat, and self - discharge of lithium - sulfur system on system shuttle constant, conduct the mechanism of these processes and simply analyse them
以充放電技術研究了不同類別復合正極的充放電性能;以掃描電鏡技術觀測了復合正極的表面形貌;以循環伏安技術和交流阻抗技術研究了復合正極電極的電化學性能;並初步探討了鋰-硫電池體系中充電過程、放電過程、充放電效率、自熱和自放電等對體系飛梭常數的影響,推導了這些過程的機理並簡要的進行了分析。Then, a three - dimensional, comprehensive, steady - state mathematical model is described to investigate the fluid flow, heat transfer, species transport and electrochemical reaction in the pem fuel cells
然後,發展了一個用於研究質子交換膜燃料電池特性的三維綜合的數學模型,模型同時考慮了流體流動、熱量傳遞、電荷傳遞、多組分傳遞和電化學動力學。In this thesis, the physical properties of a series of na2fepo4f cathode materials synthesized by various routes are instigated and discussed in the light of structural ( xrd ), thermal ( dta ) analyses and particle size distribution. their microstructures were studied by transmission electron microscope ( tem ) and scan electron microscope ( sem ). the electrochemistry property were evaluated with cells containing the synthesized na2fepo4f as positive electrode
本文將藉助x -射線衍射、掃描電鏡、透射電鏡、差熱分析以及電化學測試等方法,系統研究多種制備法對所合成的鈉離子二次電池正極活性材料氟磷酸亞鐵鈉的微結構以及循環可逆容量、循環伏安性能、交流阻抗譜的影響。The tubular sensors were made with brass tubes used in thermal power plant and their electrochemical impedance spectroscopy ( eis ) were tested and compared in two kinds of cell ( classical tri - electrode cell and the same material tri - electrode cell )
採用熱電廠實際使用的黃銅管製作管狀傳感器,利用交流阻抗法在同種材料三電極體系電解池中測量傳感器的電化學阻抗譜,並與經典三電極體系電解池下的數值作比較。Abstract : in this paper the synthesis methods of silver nanostructure materials, such as nanocubes, triangular nanoprisms, nanorods, nanowires, nanotubes, dentrites, flake, nanodisks, nanobelts, and so on, were introduced, the methods include reducing precipitation, photoinduced conversion, irradiation reduction, electrodeposition, template, microwave - assisted, ultrasonic - assisted, hydrothermal assemble, microemulsion, and so on
摘要:介紹了納米立方體、三角形納米稜柱、納米棒、納米線、納米管、樹枝狀、片狀、納米盤、納米帶等納米結構銀的制備方法,包括溶液還原沉澱法、光誘導轉化法、輻射還原法、電化學沉積法、模板法、微波或超聲波輔助法、水熱法、微乳液法等。The conjoint affection of ruo _ 2 power on ta foil is also discussed here, including : selection and ratio of adhesive, selection and ratio of conductive agent, temperature and time of heat - press treatment of electrode. research indicated that temperature and time of heat - press treatment of electrode have the most effect on electrochemical properties of as - produced electrode
然後討論了粉體與鉭片基體結合的影響因素,包括:粘合劑的選擇和比例、導電劑的選擇和比例、熱壓溫度和時間對電極片的電化學性能的影響,研究表明:熱壓溫度和時間對電極片電化學性能影響較大。Ir - ta - ti metal oxide coated titanium anodes of variable composition were prepared by thermal decomposition. their micro morphorogies and electrochemical properties were characterized by scanning electron microscope, open circuit potential, cyclic voltammetry, consumption rate measurements and accelerated life test. the sem results indicated that all coatings were of a porous and cracked - mud microstructure influenced greatly by the composition of coatings. the electrochemical measurements showed that the ir - ta - ti ternary oxide - coated anodes exhibited excellent electrochemical activity and electrochemical stability in both acidic media and seawater which were affected by the composition and microstructure of the coatings. owing to good corrosion resistance and low consumption rate in seawater, metal oxde coated anodes belong to insoluble material, and can be potentially applid in impressed current cathodic protection systems as an anode
採用熱分解方法在鈦基體上制備銥鉭鈦金屬氧化物陽極,用掃描電鏡對陽極塗層顯微形貌進行分析,通過強化電解壽命試驗、開路電位測試、消耗率試驗及循環伏安曲線研究了金屬氧化物陽極的電化學性能. sem分析結果表明銥鉭鈦金屬氧化物陽極塗層呈現多孔多裂紋形貌結構.隨陽極塗層組成不同,塗層顯微形貌表現出很大差異,這種差異直接影響陽極電化學性能.電化學性能試驗結果表明銥鉭鈦金屬氧化物陽極在酸性介質和海水中具有良好的電化學穩定性和電化學活性.此外,銥鉭鈦金屬氧化物陽極在海水中的消耗率很低,屬于不溶性的陽極材料,作為外加電流陰極保護用輔助陽極具有廣泛的應用前景Catalysts were prepared by impregnation reduction, thermal reduction, advanced thermal reduction and sol - gel methods from these metals. electrochemistry measurements, xrd, tem were used to test these catalysts. the results showed that these metals have some electrocatalysis activities towards hydrogen oxidation reaction
本文選擇了w 、 mo 、 co等金屬,採用浸漬還原法、熱還原法、改進的熱還原法以及溶膠凝膠法分別制備了這幾種金屬的碳載催化劑,對制備出的非貴金屬催化劑進行了電化學測試、 x -射線衍射( x - raydiffraction , xrd ) 、透射電子顯微鏡( transmissionelectronmicroscopy , tem )等測試,研究結果表明:這些非貴金屬在硫酸體系中對氫氣的氧化反應均有一定的催化活性。分享友人