羧化物 的英文怎麼說
中文拼音 [suōhuàwù]
羧化物
英文
carboxylates-
Carboxylase an enzyme that catalyzes the incorporation of carbon dioxide into a substrate molecule
羧化酶:一類催化二氧化碳合成底物分子的酶。The most important carboxylase in plants is ribulose bishosphate carboxylase ( rubisco ), which catalyzes the carboxyation of ribulose bisphosphate, the ‘ carbon - fixing ’ first step in the calvin cycle
在植物中最重要的羧化酶是核酮糖二磷酸羧化酶,它可以羧化核酮糖二磷酸,在卡爾文循環中是二氧化碳固定的第一步。The ability of clay minerals to catalyse decarboxylation has long been recognised.
粘土礦物能催化脫羧基作用是早已認識到的問題。Long chain alkyl benzenes is the product of cyclization - decarboxylation - aromatization of fatty acid, with the help of clay minerals catalytic effect, which comes from bacteria, seaseed and higher plant lipid ; or the reaction product of monocylic aromatics and fatty acid alkyl group under the same conditions
長鏈烷基苯主要是細菌、藻類和高等植物類脂化合物中脂肪酸在粘土礦物催化下發生環化脫羧再芳構化或單環芳烴與脂肪酸烷基化反應形成的產物。An one - pot process including direct condensation of ethyl isodehydracetate and hydrocitronellal, followed by decarboxylation, isomerization and isomer resolution, was developed for practical preparation of zr juvenile hormone analogue series with high content of effective component
以異脫氫乙酸乙酯與甲氧基香茅醛直接縮合為起點,將縮合、脫羧、異構化、 (順、反)異構體拆分等採用多步反應連續一鍋法的操作方法,成功地得到高有效含量的zr型保幼激素類似物。The microorganism which produce ethanol from lignocellulose must be able to dissimilate both five - carbon and six - carbon sugars and consist of the pdc and adh ii which are key enzymes in ethanol formation. regretfully, no naturally occurring organism can efficiently1 produce ethanol from all monosaccharides
要從木質纖維素生成乙醇,所利用的微生物必須能同化所有的戊糖、已糖成分,而且含有生成乙醇的關鍵酶:丙酮酸脫羧酶( pdc )和乙醇脫氫酶( adh ) 。Glycerate 3 - phosphate is the first product of the dark reactions of photosynthesis, formed by the carboxylation and cleavage of ribulose bisphosphate
甘油3 ?磷酸是光合作用暗反應的一種產物,在二磷酸核酮糖的羧化分解后形成。Abstract : methanesulfonic acid method was used to prepare five acylated chitins. except heptanoyl chitin, four of them, i. e. acetyl chitin, propionyl chitin, butyryl chitin and hexanoyl chitin, had high degree of substitution ( from 1. 5 to 2. 0 ) and exhibited lyotropic liquid crystalline behavior and cholesteric phase. as the length of the side chain increased the critical concentration ( w / w ) somewhat increased from 0. 21 to 0. 26 because the chain rigidity dropped. the critical concentration values of all the four derivatives were much higher than that of chitin ( 0. 12 ) due to the decrease of intramolecular hydrogen bonds. the four acylated chitin can form typical banded texture after being sheared. there minimum concentrations to form banded texture of them were evidently different, varied from 0. 25 ( for acetyl chitin ) to 0. 37 ( for hexanoyl chitin ). these results further indicated that liquid crystallinity decreased while the length of flexible side substituents increased
文摘:四種羧酰化甲殼素即乙酰化、丙酰化、丁酰化和己酰化甲殼素在二氯乙酸溶液中均呈現膽甾型溶致液晶相.臨界濃度隨側基長度增加而略有增加,衍生物的臨界濃度明顯都比原甲殼素高許多,這些規律都可以用鏈剛性的變化來解釋.四種羧酰化甲殼素在剪切時均能形成條帶織構,而且能形成條帶織構的最低濃度有明顯差別,隨側基長度增加而提高,進一步表明側基較長,液晶性減少New developments of polycarboxylic acid derivative catalysts, ion exchange resin catalysts, macrocyclic chelating compound catalysts, quaternary phosphonium salt catalysts, heterogeneous hydrotalcite - type catalysts and other catalysts which to be used in ethylene oxide catalytic hydration, and the catalysts of synthesis method of ethylene glycol via preparation and reaction of ethylene carbonate are expounded
闡述了用於環氧乙烷催化水合反應中的多羧酸衍生物催化體系、離子交換樹脂催化體系、大環螯合物催化體系、季?鹽催化體系、多相水滑石型催化體系及其他催化體系近年來的研究進展;同時闡述了用於碳酸亞乙酯法合成乙二醇反應中的催化體系的新進展。Abstract : researches on unformaldehyde unironing finishing are summarized in this paper. functions and deficiencies of glyoralamido, water soluble heat reactive polyure thane, bishydroxyethyl - sulfoue, natural high precision chitosan, reactive organosilicon, amyloidosis epoxide, multiple carboxyl acid compound are also analyzed and compared
文摘:綜述了無甲醛免燙整理方面的研究,分析比較了乙二醛-酰胺類整理劑、水溶熱反應性聚氨酯、雙羥乙基碸、天然高聚物殼聚糖、反應性的有機硅、澱粉改性物、環氧類整理劑、多羧酸化合物等無甲醛抗皺整理劑的功能以及各種整理劑存在的不足The most commonly used method for the covalent binding of biomolecules onto 1 - d nanostructures is through the diimide - activated amidation of carboxylic acid terminated nanostructures
最常用的方法是通過端羧酸基納米結構的二酰亞胺活化氨基化合物來進行生物分子與1 - d納米結構的共價結合。The experimental method includes selecting pure complexes of histidine - containing or cysteine - containing materials, from c - and n - terminal group of these amino acids to link to a group which have color or fluorescence or ultraviolet absorption, elucidating their binding affinity, fluorescence or uv - visible spectrum properties with zinc at physiological concentration and to elucidate their structure in the solid state via infrared spectroscopy. with the help of the concerned the data, the analysis was done to prove whether it can be applied to the zinc detection, in other words, whether it can be used as a new fluorescence probe for zinc detection
本實驗首次選用在生物體內與zn ~ ( 2 + )鍵合能力很突出的物質? ?組氨酸和半胱氨酸,採用類似於多肽合成的方法,在其羧基或氨基分別嫁接上一個帶有標記的基團,生成穩定的共價鍵化合物;在此化合物中模擬生理濃度條件加入鋅離子,通過紅外圖譜、紫外圖譜或熒光圖譜的變化分析鋅離子對標記基團是否產生影響,再結合有關數據分析其是否適合檢測鋅離子,即是否可能作為新的鋅離子熒光探針。Using water - soluble carbodiimide as condensation agent, biomacromolecules such as gelatin, collagen and chitosan were covalently grafted on the plla - g - pmaa membranes. solution of the biomacromolecules was further coated on the above membranes to increase the surface density of the biomacromolecules. this technology was designated " grafting and coating " method
為了將生物大分子化學接枝于plla膜表面,首先在plla膜表面接枝pmaa ,將羧基引入plla表面,利用水溶性碳化二亞胺edac作為縮合劑,與含有氨基的生物大分子反應,可將生物大分子如明膠、膠原和殼聚糖化學接枝在plla膜表面。A super acylation catalyst, 4 - dimethylamino pyridine ( dmap ), was prepared and used to synthesize cholesteryl ester compounds. four kinds of cholesteryl ester compounds such as cholesteryl p - alkoxyl benzoate, cholesteryl dicarboxylate, cholesteryl lumequeic ester and coattail - like cholesteryl ester were synthesized by acylation method and super acylation catalyst method. chemical structures and liquid crystal behaviors of the synthesized samples have been characterized by using element analysis, ftir, dsc and polarized microscopy with a hot stage
本文合成了高效酰化催化劑4 -二甲基氨基吡啶( 4 - dimethylaminopyridine , dmap ) ,採用酰氯化法和高效酰化催化劑法分別合成了對烷氧基苯甲酸膽甾醇酯、對稱脂族二羧酸膽甾醇酯、烯酸膽甾醇酯及燕尾型膽甾醇酯四類膽甾醇酯衍生物,並進行了化學結構和液晶性能的表徵。They were used as efficient lewis acid catalysts for esterification reactions of carboxylic acids with alcohols to afford corresponding saturated esters with 87 % ~ 98 % yields and unsaturated and tertiary ones with 90 % ~ 94 % and 54 % ~ 68 % yields, respectively
結果表明,該有機錫化合物是合成酯的優良催化劑,產品收率高,飽和一元羧酸酯的收率為87 % ~ 98 % ,對不飽和羧酸酯和空間位阻大的叔醇酯也能得到較滿意的收率,分別為90 % ~ 94 %和54 % ~ 68 % 。The arylcarboxylato compounds are more soluble, e. g., in chcl3 and acetone, but the solutions are extremely air-sensitive.
芳羧基化合物較易溶,例如它們能溶於CHCl3和丙酮中,但這些溶液對空氣是極為敏感的。Pig liver esterase ( ple ) is one of the best bio - catalysts used in chiral industry, which is extracted from pig liver previously, and full of strong capability of hydrolyzing esterases
豬肝酯酶( pigliveresterase ,簡稱ple )是手性催化工業中最常用的三種生物催化劑之一。它是從豬肝中提取出來的一種羧酸酯水解酶( ec3Terrestrial plants are classified into three major photosynthetic types, namely, c3, c4 and crassulacean acid metabolism ( cam ) plants, according to the mechanism of their photosynthetic carbon assimilation. c4 plants have co2 concentrating mechanism and higher photosynthetic efficiency than c3 plants, especially under high light intensity, high temperature, high oxygen partial pressure and drought conditions
本研究利用c _ 3植物、 c _ 4植物、旱稻與稗草等的雜交後代的材料,進行光合速率的測定,進一步分析植株在光能吸收傳遞、氣孔調節、羧化反應等生理特性,研究高光效的生理機制。In this study, the preparing processes of zro2 - ni nanocrystalline composite powder aremixing the nickel salt, zirconium salt and stabilizer, solvent ( distilled water ) together to prepare the mixing solution according to certain ratio ; commingling the mixing solution, coordination solution of carboxylic ammonia, intrusion aid in accordance with certain rate to form sol, drying the sol and turning it into gel, pre - sintering the gel to get the zro2 - nio powder and gaining zro2 - ni nanocrystalline composite powder by reducing the zro2 - nio powder. xrd, x - ray wide - angle diffractometer, bet, sem, tem, hrtem analyses are used to study the zro2 - ni nanocrystalline composite powder and zro2 - ni cermet. the sintering temperature is determined
本研究的zro _ 2 - ni納米復合粉末的制備方法如下:將鎳鹽、鋯鹽、穩定劑和溶劑(水)按所需成分配成混合溶液,再將混合溶液、外加劑和氨羧絡合劑按比例混合形成溶膠,溶膠經乾燥成為凝膠,凝膠經預燒得到zro _ 2 - nio納米粉,將該氧化物粉還原得到zro _ 2 - ni納米復合粉。Peg and superfluous aa reaction by complete concatenation method, the esterify production " esterify water " and acid number were mensurated, it shows that the esterify reaction would be processed under 100 esterify temperature and with amine accelerantthe tide of esterify reaction was substantiated by ir. in the ir spectrum, the characteristic peak of hydroxy of peg and carboxyl of aa were weakened. and the ester link of peg was reinforce. the " esterify water " was increased gradually and the acid number of esterify production was debased gradually along with the extent of esterify time and the augmentation of molecular weight of peg
通過聚乙二醇與過量的丙烯酸採用全連續法進行反應,測定酯化產物「酯化水」和酸值等宏觀手段反映出在胺類促進劑、 100的酯化溫度等條件下的酯化進程,而利用紅外光譜( ir )分析所反映的聚乙二醇的羥基和丙烯酸的羧基特徵峰減弱,而pea的酯基特徵峰加強等特徵進一步證實了宏觀手段所表現出來的酯化趨勢:隨著酯化時間的延長和聚乙二醇分子量的增大,產生的「酯化水」逐漸增加,酯化產物的酸值逐漸降低;從酯化時間看,當反應時間達到300min時,酯化物的酸值達到最小,而從ir分析來看,酯化物pea4的羥基峰在300min時減弱到最小, pea23在120min時羥基峰的表現出酯化基本完全。分享友人