質子性溶劑 的英文怎麼說
中文拼音 [zhízixìngróngjì]
質子性溶劑
英文
protic solvent- 質 : Ⅰ名詞1 (性質; 本質) nature; character; essence 2 (質量) quality 3 (物質) matter; substance;...
- 子 : 子Ⅰ名詞1 (兒子) son 2 (人的通稱) person 3 (古代特指有學問的男人) ancient title of respect f...
- 性 : Ⅰ名詞1 (性格) nature; character; disposition 2 (性能; 性質) property; quality 3 (性別) sex ...
- 溶 : 動詞(溶化; 溶解) dissolve
- 劑 : Ⅰ名詞1 (藥劑; 制劑) a pharmaceutical or other chemical preparation 2 (某些有化學作用的物品) a...
- 質子 : [物理學] proton; uron; hydrion; merron質子泵 proton pump; 質子層 proton sphere; 質子轟擊 proton b...
- 溶劑 : dissolvant; solvent; resolvent; solventia; menstruum
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A method to calculate quantitatively the adsorption volume or adsorption space of per mass of adsorbent derived from both the adsorbed molecule volume and the maximum adsorbance of a solute in an adsorption isotherm under a given experimential condition is presented firstly for a solid / liquid adsorption system of the solute in a dilute aqueous solution. this method is suitable for not only mono - layer adsorption, but also mani - layer adsorption and micelle adsorpion of surfactant constructed by hydrophile and lipophile groups. therefore, the surface concentration of the adsorbate, cs, deduced from the adsorption volume is possessed of the meaning of true concentration, and the value of the patition coefficient of the adsorbate between solid and liquid phass, p, attained by the cs and the c, solution concentration of the adsorbate, can be accurate. the foregoing a set of calculations are presented for the solid - liquid adsorption systems consisted of the wool fiber and separately dodecyltrimethyl - ammonium bromide ( dtab ) and hexadecyltrimethyl - ammonium bromide ( ctab ) in this paper. this provides a strong basis for adsorption thermodynamic investigation of adsorbate
對稀溶液中溶質的固/液吸附體系,首次提出了根據吸附分子體積和實驗條件下吸附等溫線中的最大吸附量計算單位質量吸附劑的吸附體積或吸附空間的方法.此法適用於單層吸附,也適用於多層吸附和具有親水親油結構的表面活性劑分子的膠團吸附.由此,吸附質的表面相濃度cs具有真實濃度的含義,相應地,計算得到的溶質的固/液分配系數p就有了準確值.分別計算由溴代十二烷基三甲銨( dtab )和溴代十六烷基三甲銨( ctab )與羊毛纖維構成的液/固體系分配系數等,為溶質吸附的熱力學研究奠定了基礎Carbonium ions in solution derive much of their stability from solvation effects and are formed more easily in more polar media.
正碳離子在溶液中由溶劑效應獲得更高的穩定性,而且在極性較高的介質中更容易形成。Abstract : numerous mushrooms are toxic to insects. to identify the chemicals involved in insecticidal activity, the toxicity of 14 species has b een studied for water solubility, thermolability, and dialysis. the data strongly s uggest that proteins are responsible for most of the insecticidal avtivity in mu shroom fruitbodies and may be a source of genes available for plant protection a gainst insects. among proteins, lectins and haemolysins are good insecticide candi dates because the toxicities are not affected by protease
文摘:許多蘑菇都對昆蟲表現出毒性.為了證實與殺蟲毒性有關的化合物,對14種蘑菇的毒性在水溶性、熱敏性和可透析性等方面進行了研究.研究數據表明,蛋白質對大多數蘑菇子實體的殺蟲活性起著重要作用,也許是一種可以用於植物抵抗害蟲的基因源.在數種蛋白質中,凝集素和溶血素因不受蛋白酶的影響而成為良好的殺蟲劑候選材料In this paper, in order to study the influence of electrolyte to the lithium - ion battery performance, we assembled the lithium - ion battery using the different electrode material ( limn _ 2o _ 4, licoo _ 2 and natural graphite ) and the electrolytes which were mainly composed of lipf _ 6 as the electrolyte lithium salt and the different solvents ( including additives ) which were mixed according to the certain proportion
本論文主要以lipf _ 6為電解質鋰鹽,採用不同溶劑(添加劑)按一定比例混合,對有機電解液進行優化,與不同的電極材料( limn _ 2o _ 4 、 licoo _ 2或天然石墨)組裝成電池,研究電解液對鋰離子電池性能的影響。The solvent effects on the nonlinear optical properties of pna molecule are also chiefly studied on the base of time dependent density functional theory
本文還在含時密度泛函理論基礎上著重研究了溶劑效應對pna分子的非線性光學性質的影響。It is found that the relationship between the nonlinear optical properties and the polarities of the solvents is non - monotonic, which is quite different from the previous conclusions
研究發現pna分子的非線性光學性質與溶劑極性之間的關系並不是單調的。這一結論不同於以往的理論研究結果。When the molecule is solvated in the solution, the solutions have effects on the structure and optical properties of the molecule. the solvent effect is introduced in the third chapter
當分子被溶解在溶劑中時,溶劑將影響分子的幾何結構和光學性質,第三章我們介紹了溶劑效應。When molecules are solvated in the solution, the solute molecule polarize solvent molecules around it and this gives rise to a field reaction field acting back - ob - the molecule, which will have effects on the structure of solvated molecules and their optical properties
當分子溶解在溶劑中時,溶質分子將使溶劑發生極化現象,被極化的溶劑反過來又會產生一個反應場作用於溶質分子,從而影響溶質分子的幾何結構和光學特性。The results show that effects of alkali metal salts on conductivity are different because of their different anion radium, crystal lattice energy, ionic mobility and solubility in electrolytes, that different ionic conduction modes of electrolytes result to double - peak of salt concentration dependence of conductivity and different temperature dependence, and that different influences of plasticizer to conductivity result from their different action
結果表明,不同堿金屬鹽對電解質電導率的影響因其陽離子半徑、晶格能、離子淌度以及在電解質中的溶解度的不同而不同;電導率的鹽濃度依賴性因電解質的離子傳導方式不同而明顯呈現雙峰形;增塑劑對電導率的影響則因其作用方式不同而產生不同的效果;電導率的溫度依賴性也因電解質的離子傳導方式不同而呈現不同的規律。In this article, the bellcore method was used to prepare polymer electrolyte membrane based on pvdf - hfp, and polymer electrolyte membranes under different conditions were prepared by changing sorts of solvents 、 ratio of dbp and solvent. effects of ratio of plasticizer and solvent on the liquid uptake 、 sem 、 mechanism capability 、 ionic conductivity 、 electrochemical stability window of polymer electrolyte membrane were also studied. through optimizing the preparation technics, the integrated effects of additives such as pc 、 ec 、 dbp and nanophase al2o3 on the ionic conductivity 、 liquid uptake were studied
本文以聚偏氟乙烯-六氟丙烯共聚物pvdf - hfp為基質,採用bellcore制膜法制備了pvdf - hfp聚合物電解質膜,通過改變增塑劑dbp的含量、溶劑的種類及溶劑的含量制備了不同條件下的聚合物電解質膜,分別研究了增塑劑含量、溶劑含量等對聚合物電解質膜的吸液率、表面形貌、機械性能、離子電導率、電化學穩定窗口等的影響;對制備工藝進行了優化,研究了各種添加劑如pc 、 ec 、 dbp及納米al2o3對聚合物電解質膜的離子電導率、吸液率等性能的綜合影響。In order to study the influence factors of aoa of rose flowers, the effects of drying and extraction methods on the aoa of rose flowers were investigated. the results indicated that drying after high - temperature short - time pretreatment was rather effective to maintain their aoa ; the aoa of water extracts was stronger when the temperature was raised from 25 to 100 ; by using orthogonal test, the optimum extraction conditions of rose flowers were : solvent - 75 % ethanol ; ratio of material and solven - 1 : 10 ; extraction times - three times with 24 h at one time, at the room temperature. the extracts obtained by 75 % ethanol were fractionatedly extracted with petroleum, diethyl ether, ethyl acetate and n - butanol in turn, and the various fractions " aoa were analyzed
為了探討玫瑰花抗氧化活性的影響因子,比較了不同乾燥方法、提取方法對其抗氧化活性的影響,發現:經短時高溫處理后再進行乾燥有利於較好地保持玫瑰花的抗氧化活性;以水作溶劑提取時, 25 100范圍內水提液的抗氧化活性隨著溫度的升高而增強;通過正交實驗篩選得到常溫下玫瑰花抗氧化活性物質的最佳提取方法為: 75乙醇為溶劑,液料比1 : 10 ,提取3次,每次24h ; 75乙醇提取物依次用石油醚、乙醚、乙酸乙酯、正丁醇等有機溶劑進行兩相分部萃取,發現玫瑰花的抗氧化活性物質主要存在於乙酸乙酯部,說明玫瑰花抗氧化活性主要成分可能是單寧類、黃酮苷類和原花色素類化合物; 4Nonpolar solvent with little dielectric constant has good effect to the rate of the reaction, while larger polar solvent without h ( superscript + ) also can increase the rate of the reaction
可以知道對甲醇羰基化這一反應,在極性溶劑中,極性較大且為非質子型的溶濟能顯著提高反應的速率;非極性溶劑中,介電常數較小的溶劑能增加反應速率。Secondly, the nonlinear optical properties with pna molecule in different solvents are studied through using the polarized continuum model and few states approach on the base of time dependent density functional theory, and the first order nonlinear hyperpolarizabilities in second harmonic generation process are computed
然後在含時密度泛函理論基礎上採用極化連續模型和少態方法研究了不同溶劑中pna分子的非線性光學性質,計算了二次諧波振蕩過程的一階非線性超極化率,並討論了pna分子的非線性光學性質與溶劑極性之間的關系。The long range interaction simulated by polarizable continuum model, the hydrogen bonding interaction, and the whole interaction between the solute and the medium were separately investigated
分別研究了由極化連續模型模擬的溶劑和溶質分子的長程相互作用,溶劑和溶質分子的氫鍵作用,以及溶劑和溶質分子的整體作用對分子結構和性質的影響。The further study of the six - member ring mechanism with the participation of iso - propanol demonstrates that the calculated ratio of enantiomers agrees with the experimental results essentially
而對質子性溶劑異丙醇參與的六元環機理的研究發現反應產物的對映體組成的計算結果與文獻實驗值吻合較好。Our goal is to establish a simple and effective empirical approach to calculate the conformational entropy and the binding free energy by analysis of j : protein interface. three variables of the binding interface information of 20 protein complexes, including the binding accessible number ( nb ), hydrophilic pair ( n ^, ) and apolar solvent - accessible surface areas ( & asaapol ) are analyzed
本論文在此分析了20組蛋白質二聚體分子的結合界面三個有效的參數信息,即界面殘基側鏈可接觸數( n _ b ) 、親水對數( n _ ( pair ) )和非極性溶劑可接近表面積的變化( asa _ ( apol ) ) 。Using non - proton organic solvent as reaction medium, then reactions in definite conditions after reactants being separated 、 dryed 、 weighed and compared productivity, test the new compound by dsc
將槲皮素和大豆卵磷脂共溶於不同非質子性溶劑中,在一定條件下進行反應,然後將反應物分離、乾燥、稱重,比較收率,並用dsc進行分析。The analytic results of the effects on the micromorphological structure of the film by the electrochemical condition ' s showed that the carbon is apt to improve the boundary combination between the scfs and the surface of the cathode and the seperation of the films, and that the micromorphological structure of the mpgcfs is greatly affected by the dring and the power voltage, which remarkably affluence ion move in swelling cathode film, and that higher temperature and concentration of cu2 + in the medium solution are also advanagable to the deposition of cu in scfs. the plot of deformation behavior of mpgcfs showed that the maximum strench ratio decreases and the brittleness increases due to the existence of the metal phase, and that the strengh trend of the composite films is fistly up and down followed with the content of metal phase because of the change of the role of the metal phase from acting as the physical cross - linking to weakening the films due to destroying the whole structure of the polymer
另外它作為基體的另一個突出的優點是制備的溶脹復合膜( scf )中的溶劑與電解液中的溶劑相同都是水,克服了以前膜內外不同溶劑之間擴散的問題,結果使得電流最終趨於一種穩態,因此可以更好實現用電化學條件來控制mpgcf的形態結構;硬質石墨材料的多孔的結構和石墨本身的結構性能特點使得碳作為陰極材料時有利於溶漲復合膜( scf )與電極表面的結合以及膜的剝離,因此是作為陰極的理想材料;電化學條件中的乾燥程度和電壓能夠明顯的影響離子在膜內的遷移,從而對mpgcf的形態結構造成較大的影響;而提高反應溫度和增大電解液中銅離子的濃度也有利於銅在膜中的沉積生長。It will be helpful for our finding and synthesizing strong tpa materials. this thesis used density functional theory ( dft ) to optimized the organic molecules, then studied their tpa cross sections, solvent effect and structure - to - property by response theory and few states model
本論文採用密度泛函理論對二苯乙烯系列衍生物分子結構進行優化,然後分別採用響應場方法和少態模型方法對分子的雙光子吸收截面、溶劑效應及結構與性質的關系進行了計算與研究。The selectivity and activity of enzyme in the reaction media, especially in ionic liquids and supercritical liquids was reviewed in the paper
文章以溶劑分類,探討溶劑,特別是引入新的反應介質離子液體和超臨界流體對酶催化活性和選擇性的影響。分享友人