超分子化學 的英文怎麼說
中文拼音 [chāofēnzihuàxué]
超分子化學
英文
supramolecular chemistry- 超 : Ⅰ動詞1 (越過; 高出) exceed; surpass; overtake 2 (在某個范圍以外; 不受限制) transcend; go beyo...
- 分 : 分Ⅰ名詞1. (成分) component 2. (職責和權利的限度) what is within one's duty or rights Ⅱ同 「份」Ⅲ動詞[書面語] (料想) judge
- 子 : 子Ⅰ名詞1 (兒子) son 2 (人的通稱) person 3 (古代特指有學問的男人) ancient title of respect f...
- 學 : Ⅰ動詞1 (學習) study; learn 2 (模仿) imitate; mimic Ⅱ名詞1 (學問) learning; knowledge 2 (學...
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The imported transparent glaze fired at lower temperature was analysed semi - quantitatively by adopting emission spectroscope. the stripping of lead and cadmium from this transparent glaze fired at lower temperature in ceramic product was determined by atomic absorption spectroscope. the effect of chemical composition on the stripping of lead and cadmium was analysed. upon the author s opinion, the overproof lead stripping from the imported transparent glaze fired at lower temperature can only be settled by adopting lead - free glaze instead of adopting low - lead prescription. the author succeeded in developing an excellent lead - free transparent glaze fired at the lower temperature of 1000 1050. the success is based on an inquiry into the feasibility of using such new agents of fusion as li2o and sro in replacement of pbo ; and on a study of the effects of the contents of sio2 , al2o3 , b2o3and other metallic oxides on such performances of glaze as coefficient of linear expansion, fusion temperature and transparency. it is also based on an analysis of coefficient of linear expansion of blank and glaze on an analysis of coefficient of linear expansion of blank and glaze on their correlation ; and on a study of technology for preparing glaze
採用發射光譜儀對進口低溫透明釉進行半定量分析,並用原子吸收光譜儀測定其陶瓷製品的鉛、鎘的溶出量,分析化學成分對鉛、鎘溶出量的影響.結果表明,進口低溫透明釉採用低鉛配方不能解決鉛溶出量的超標問題,只有採用無鉛釉才能解決.探討用氧化鋰和氧化鍶等新型熔劑完全代替氧化鉛的工藝,研究釉料中氧化硅、氧化鋁、氧化硼和各種金屬氧化物的含量,對釉的線膨脹系數、熔融溫度和透明度等性能的影響.分析坯料、釉料的線膨脹系數及其相互關系和釉料制備的工藝,研製出優質的1000 1050低溫無鉛透明釉Supramolecular is a rapidly developed area in chemistry recent years
超分子化學是目前化學學科中發展比較迅速的一個領域。Molecular self - assembly is a topic of current interest in supramolecular chemistry
摘要分子自組裝是超分子化學最重要的研究內容之一。We research on the carbon dioxide dimers ( c2h and c2v ) by dft too. the results indicate that dissociation energies is kjmol - 1 and intermolecular vibration frequencies are small of both carbon dioxide dimers ( cah and civ ). therefore we prove that the carbon dioxide dirners are weakly bound molecule indeed
採用量子化學計算手段,我們研究了co _ 2二聚體( dimer ) ,證實了co _ 2二聚體確實是弱結合分子,因而在超臨界狀態下co _ 2具有很強的動力學特徵。The theory hypothesis of " pore restriction " is first proposed in this paper. during polymerization, one end of linear molecule inserts the channels of zeolite to form hard end through chemical bond or supermolecule acting force, the other end forms soft end through condensing or polymerizing with other monomer molecule. on the basis of the theory hypothesis, a kind of novel pattern of organic - inorganic composite materials - pu / zeolite composite materials - has been designed
本文首次提出了「孔約束」的理論假說,即在高分子材料聚合過程中,線型分子的一端通過化學鍵或超分子作用力插入分子篩的孔道中形成硬端,而另一端則與其它單體分子縮合或聚合形成高分子材料的軟端;在此假說的基礎上,設計了一類孔約束型有機?無機復合高分子材料的新模式,即聚氨酯/沸石分子篩復合材料。Layered and pillared material are a kind of multifunctional material which were developed in recent years, much attention has been paid to this kind of material for its application in ion - exchange catalysts solid state proton conductivity, nonlinear optics and physic. a lot of literature have reported the intercalation behavior of a - zirconium phosphate ( abbreviated as a - zrp ), different guest molecules inserted into a - zrp have been studied in detail, those guest molecules include amine, alcohok amino acid protein, enzyme coornadiate compound and coronal compound. the intercalation guest is restricted by their size and basicity
層柱材料是近年來發展起來的一類多功能材料,由於其在離子交換、催化、固態質子導體、非線性光學以及醫學等方面的廣泛應用而受到國內外研究者的重視,大量文獻報道了-磷酸氫鋯zr ( hpo _ 4 ) _ 2 ? h _ 2o ( - zirconiumphosphate ,縮寫為- zrp )的超分子插層化合物及插層性能,其中對不同的客體分子對磷酸鋯的嵌入做了詳細的報道,客體分子的種類包括氨、醇、氨基酸、蛋白質、酶、配合物、冠狀化合物等。The significant preponderance of the host - guest complex formation is that the host structure can be easily controlled by two ways. the one way is the host structure can be changed under the different synthesis condition. the other is that the suitable guest can be selected according to the different molecular structure
從分子水平上通過對主體、客體及超分子配合物材料的結構調節,以期獲得對電流變材料性能的調控,從而為電流變材料的化學設計提供一種有效方法。12 qin yong chao *, yi ping hang, bin hu, zucheng jiang adsorption behavior of noble metal ions ( au, ag, pd ) on nanometer - size titanium dioxide with icp - aes. analytical sciences, 2003, 19, 1353
14李春香、秦永超* 、梁沛、胡斌、江祖成用等離子體原子發射光譜法研究納米二氧化鈦對鎢酸根離子的吸附行為,分析化學, 2001 , 29 ( 12 ) , 1419 - 1422Supramolecular chemistry is interdisciplinary - cross subject, which has been of great importance for developments within coordination chemistry, organic synthesis, analytical chemistry, and bioorganic and bioinorganic chemistry
超分子化學是一門高度交叉的學科,它對配位化學、有機物合成、分析化學、生物有機化學和生物無機化學的發展都是十分重要的。How to obtain the useful biochdrical informaton on this scale is the new tren in the research fie1d of analytical chehascy therefore, single molecule detection, sing1e cell detection, dna ~ and the shaple dna analysis were one of the main research direeons ofanalytcal chendscy nove1 molecular probe and ultrasmali biosensor for real tiine and in vivo detection has been the focuses in the research field of analytical chendstry according to the above mentioned advanced direetions, two pnd of inveshgations has been pdrirmed in thes thesis
人們對生命現象的觀察和研究已經深入到納米尺度和單細胞,單分子的水平,如何在這樣一個尺度范圍內獲取有用的生物化學信息對分析化學的各個研究領域均提出了新的要求。單分子、單細胞檢測、生物晶元的開發以及納米技術的應用漸漸成為現代分析化學研究的主流領域之一。可進行實時、在線、原位、活體檢測的分子探針和超微型生物傳感器成為人們研究的熱點和重點。Study on the characteristics of candied dates ' convectional drying mass transfer
超分子化學的研究和進展Supramolecular chemistry seeks to control the formation of molecular assembly by means of the interactions between the partners
超分子化學尋求的是如何通過各成分間的相互作用來控制分子集合體的形成。Supramolecular chemistry is one of the new branches of the chemistry. the origin, the category, the ways of the synthesis and the applications of the supramolecular complexes are studied
摘要超分子化學是化學的一個嶄新的分支學科。綜述了超分子化學的發展歷程、超分子的化學分類、超分子化合物的合成以及應用等問題。A variety of artificial receptor molecules, such as cyclodextrin ( cd ), crown ethers, calixarenes and porphyrin, as typical host compounds, have attracted enormous research interest in their molecular recognition. among them, cds having an interior hydrophobic cavity and an exterior hydrophilic environment, as a buildup element of second generation supramolecule, can accommodate many organic, inorganic and biological molecules in their toroidal cavity to form stable host - guest inclusion complexes. therefore, they have been paid much attention by the researchers of supramolecular chemistry
在已報道的多種人工超分子主體物質中,以冠醚、環糊精( cyclodextrin ,簡稱為cd ) 、杯芳烴及卟啉( porphyrin )為主體的分子識別研究引起了人們的廣泛關注,其中環糊精( cd )作為第二代超分子的構築體,其內腔疏水而外部親水,可以與許多有機、無機和生物分子形成包合物,從而成為超分子化學工作者感興趣的研究對象。The inclusion interaction and molecular recognition of cyclodextrin and its derivatives are discussed, also, the paper introduced development of cyclodextrin supermolecular chemistry is briefly introduced
摘要本文介紹了環糊精超分子化學領域的研究概況,從環糊精的包合作用及其分子識別功能兩個方面進行了簡要概述。Supramolecular chemistry of shape - persistent arylene ethynylene macrocycles, including aggregation, host - guest chemistry, liquid crystal behavior and 2d, 3d supramolecular structures is reviewed in this article
摘要重點介紹具有納米尺寸的苯炔剛性大環的超分子化學:包括聚集效應,主客體化學、液晶行為及二維、三維超分子結構等。Electrochemlcal sensor was widely used in the analytical determination recentlythe studyofchemlcal modified electrode ( cme ) whlchact as electrochemlcal sensor was very plentiful the chemical modified carbon paste electrode ( cmcpe ) which was fabricated by mingling modifier with carbonpaste 叩 plledmore often the cpe has the characteristic ofeaslly modified , wide using range , fabricated easily3 innoculty , long llte span etc because modified spedal substance cmcpe has spedal mnctlon , it is studied more and more byelectfochemlcal worker now supermolecule chemistry , the emerging and up to date cross su 刊 ect , involves all su 刊 ects of chemistry biochemistry and material science etc inthatsupralllolecule c 卜 cthlstry chcffi1stfy offers an effective method for chemists to solve the long term puzzle of improving selectivity , ithas gotten a great devebpment from it ’ s theory beingput forward we can expect the greatly wide application ofsupermolecule chemistry on cme but because the difficulty how to station it on the surface of ethetrode cannot be solved easily , the application of supermolecule chemistry on cme was defined
Cmcpe具有了一般碳糊電極的特點,同時又因為修飾了特定物質,使cmcpe具有了特定的功能,越來越受到電分析工作者青睞。而超分子化學是一個新興的跨學科的交叉前沿領域,由於超分子化學解決了一直困擾化學工作者的選擇性問題,因而從其理論提出以來,就得到了巨大的發展。可以預期超分子化學在化學修飾電極方面將有非常廣闊的應用前景,但現在由於將超分子試劑修飾在電極這一環節上存在困難,所以現在超分子試劑在cpe上應用較少,在cmcpe中的應用更少。The classic synthesis methods of polycyclic aromatic hydrocarbons ( pah ), the most recent development in the synthetic methodology of the functional pah, their application to construction of complex architectures ( liquid crystals, shape persistent linear and cyclic macromolecules ), and their supramolecular behavior are reviewed in this article
摘要對稠環芳香烴的合成方法、官能團化稠環芳香烴最新合成進展、官能團化稠環芳香烴構建的復雜分子體系(液晶、剛性線型和環狀的大分子)及其超分子化學進行了評述。This article gives a review on the progress of the recognition and complexation between cucurbiturils as a noval macrocyclic host compound and metal ion, including the synthesis methods of supermolecular adducts, crystal structures, thermodynamics of binding and potential applications
摘要概述了新一代大環主體化合物南瓜尼與金屬離子的識別及配合作用的研究進展,包括其超分子配合物的合成方法,晶體結構,鍵合的熱力學性質及其應用前景。The first order nonlinear hyperpolarizabilities in second - harmonic generation process and electro - optical pockels effect are computed. the basis set effects in ab - mitio quantum - chemical computation are mainly studied. the correction to the nonlinear optical properties due to the electronic correlation energy is discussed and the relationship between the first order hyperpolarizabilities and the frequencies of the external electric field is also investigated
計算了二次諧波振蕩過程和電光pockels效應過程的一階非線性超極化率,研究了電子的相關能對pna分子的非線性光學性質的影響以及pna分子的一階非線性超極化率與外加光電場頻率之間的色散關系,並著重討論了量子化學從頭計算中基矢組的選取對計算結果的影響。分享友人