轉酯反應 的英文怎麼說
中文拼音 [zhuǎnzhǐfǎnyīng]
轉酯反應
英文
transesterification-
As to the solvent, hexane and butvul acetate is discussed and former is more suitable for biotransformation. among seven kinds of energy source : menthok alcohok glycok glycerou 1 - hexanok butyl alcohol octyl alcohol, glycol is selected as energy source, so hexane - glycol is used as reaction system
從生物相容性和有利於轉化的角度對兩種溶劑,正己烷和乙酸丁酯進行了比較,確定了正己烷?憶二醇為該模型反應的溶劑體系。The article analyze the concrete drying shrinkage mechanism, find the major factors of affecting the drying shrinkage, analyze the lack of shrinkage reducing agent, who be of low molecular weight and line chain, design a new shrinkage reducing agent ? ? shrinkage reducing agent of poly - acrylate. the shrinkage reducing agent of poly - acrylate is mainly composed of crylic acid 、 cinnamene 、 poly - glycol 、 solicitating agent 、 chain transferring agent and activator, which come by these processes of polymerization 、 esterifing and neutralization to form a pectinate polymer, which have a high molecular weight and many poly - oxidative alkenes
論文分析了混凝土乾燥收縮的機理,確定了影響乾燥收縮的關鍵因素,分析已有低分子量的、直鏈型減縮劑的不足,設計了一種新型的減縮劑? ?聚丙烯酸鹽類減縮劑,其主要由丙烯酸、苯乙烯、聚乙二醇、引發劑、鏈轉移劑、催化劑等經過聚合、酯化和中和反應,生成一種高分子量的、含聚氧化烯鏈的聚合物。Abstract : a novel enzymatic reaction ? ammonolysis was introduced in thenineties. this reaction not only provides a synthetically useful and mild alternative method for the synthesis of amides, but also can be used for the kinetic resolution of chiral alcohols or chiral carboxylic acids. in addition to enantioselective hydrolysis, esterification and transesterification, ammonolysis also shows high enantioselectivity in the resolution of racemates
文摘:酶促氨解反應是20世紀90年代中期發現的一種新型反應,在脂肪酸酰胺的合成、手性藥物(手性酸及手性醇等)的拆分中顯示出巨大的應用潛力,是除立體選擇性水解、酯化、轉酯反應之外的另一具有較大開發應用前景的酶促新型反應。Increasing ultrasound intensity in the range of cavitation threshold and cavitation peak value, decreasing monomer concentration and increasing the temperature make the induction period shorter. under optimized reaction conditions, the conversion of ba can reach 90 % in 11 min at high n2 flow rate the viscosity average molecular weight of the obtained pba reaches 5. 24 106. the molecular weight of pba varies with ultrasonic irradiation time, indicating that the ultrasonic induced emulsion polymerization is dynamic and quite complicated, polymerization of monomer as well as degradation of polymer occurs concomitantly
一、實現了無常規化學引發劑存在下的超聲輻照引發丙烯酸正丁酯( ba )間歇乳液聚合,制備了pba納米粒子,在11min內轉化率達到90 ,分子量達5 . 24 10 ~ 6 ,隨反應時間的延長而降低,表明超聲輻照引發乳液聚合是一個動態的復雜過程,單體的聚合和聚合物的降解同時發生。Studied the liquid - phase synthesis of butyl acetate from n - butyl alcohol and acetic acid using the supported heteropoly blue as catalyst. examed several factors imposing on esterification. the results revealed : using this catalyst, the reactions conversion percentage reaches nearly 100 %, product yield is 98. 9 %, selectivity is 98. 9 %. reusing it 10 times, the efficiency is still well. in addition, using this catalyst, the reactions temperature is mild, the reaction time is short and the equipment hasnt any erosion. furthermore, there is no “ threewastesdischarge
對以負載型雜多藍為催化劑的乙酸與正丁醇的液相酯化反應進行了研究.考察了影響酯化反應的因素.結果表明:以負載型雜多藍為催化劑,酯化反應轉化率接近100 % ,收率可達98 . 9 % ,選擇性為98 . 9 % ,重復使用10次催化效果仍好.該催化劑還有反應條件溫和、反應時間短、對設備無腐蝕、無三廢排放等優點Citric acid, taking the place of hno3, solutes the substance which does not solute in solution, and it acts as the ligand of metallic ionic and the hydrolysis catalyst of si ( oc2h5 ) 4, which reduces the pollution caused by no2 which forms at the decompose process of the hot treatment. by changing the means of calcine of the drier gel, choosing the suitable temperature to burn the gel, the high temperature calcine time is shorted, which solves the question of the long period calcine. so the preparation process of the matrix and composite was finished by using more lower temperature than the traditional solid state reaction and more shorter time than the traditional sol - gel process
結果使基質和復合物的制備在比傳統的固相反應法低得多的溫度下和比常規的溶膠凝膠法短得多的時間里完成;五、對基質及復合物的干凝膠、粉體和燒結體進行了ir 、 dta 、 xrd 、 seni及交流阻抗譜表徵,研究結果表明:在溶膠向凝膠的轉化過程中同時存在著正硅酸乙酯自身的聚合作用和檸檬酸鹽絡合物之間的聚合作用:干凝膠向產物粉體的轉化在400600c之間進行;基質li 。Abstract : aim to synthesize a new prodrug, resveratrol trinicotinate. methods in presence of lithium and a catalytic amount of naphthalene, the reaction of p - methoxybenzyl trimethylsilyl ether and 3, 5 - dimethoxylbenzaldehyde gave resveratrol after a series of translation. resveratrol trinicotinate was obtained by the reaction of resveratrol and nicotinoyl chloride hydrochloride. results a mutual prodrug resveratrol trinicotinate was designed and synthesized. conclusion a novel method for synthesis of resveratrol and resveratrol trinicotinate has been afforded. the e - isomer is selectivily obtained by dehydration of the compound 2 with khso4
文摘:目的合成一種前藥白藜蘆醇煙酸酯.方法在金屬鋰片和催化量的萘的存在下, 3 , 5 -二甲氧基苯甲醛與對甲氧基苯甲醇的三甲基硅醚反應經過一系列轉變得到白藜蘆醇,白藜蘆醇與煙酰氯反應得到白藜蘆醇煙酸酯.結果設計併合成了白藜蘆醇煙酸酯.結論提供了一種合成白藜蘆醇及白藜蘆醇煙酸酯的方法,採用khso4脫水可選擇性的得到反式產物Tecbios biodiesel process is based upon transesterification of vegetable oils and animal fat with methanol or ethanol in excess, in the presence of naoh or koh as catalyst
Tecbio公司的生物柴油工藝,主要是使用naoh或koh作為催化劑,對菜油和動物脂肪進行酯基轉移反應,制取甲醇或乙醇。Butylation of diethyl malonate catalyzed by phase - transfer catalyst and microwave irradiation
微波輻射相轉移催化丙二酸二乙酯丁基化反應研究With this initiating system, the number - average molecular weights of the obtained polymers increased in direct proportion with monomer conversion, and the molecular weight distributions ( mwds ) were narrow throughout the reactions ( 1. 31. 4 )
將該體系應用於甲基丙烯酸丁酯的聚合反應,所得聚合物的相對分子質量分佈窄( 1 . 3與單體轉化率呈線性關系。The conversion, the utilization rate of raw materials and the product yield of esterification reactions are raised by applying the catalytic rectification process
摘要催化精餾技術應用於酯化反應體系,提高了反應的轉化率、原材料利用率和產品收率。3the spraying technique has strict process requirement on interior decorative materials. under specific circumstance, ethoxyline or polyester, via their thermosetting property, is converted into modified epoxy i. e. high molecular material so as to obtain the advantages such as smooth surface, uv resistance and air pollution resistance
3噴塗技術對室內外裝飾材料的工藝要求極高,環氧樹脂或聚酯通過熱固性使其環氧樹脂或聚酯能在特定的條件下得到充分的反應,轉化成改性環氧即為高分子材料達到表面平滑抗紫外線,抗空氣污染等特點。分享友人