配位羥離子 的英文怎麼說
中文拼音 [pèiwèiqiǎnglízi]
配位羥離子
英文
complex hydroxy ion- 配 : Ⅰ動詞1 (兩性結合) join in marriage 2 (使動物交配) mate (animals) 3 (按適當的標準或比例加以...
- 位 : Ⅰ名詞1 (所在或所佔的地方) place; location 2 (職位; 地位) position; post; status 3 (特指皇帝...
- 羥 : 名詞[化學] (羥基) hydroxyl (group)
- 離 : Ⅰ動詞1 (離開) leave; part from; be away from; separate 2 (背離) go against 3 (缺少) dispens...
- 子 : 子Ⅰ名詞1 (兒子) son 2 (人的通稱) person 3 (古代特指有學問的男人) ancient title of respect f...
- 離子 : [物理學] ion
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In all those complexes, no matter which conformation ida assumes ( mer - or fac - style ), the two 0 atoms of 1n2o are both from carboxylic hydroxyl. however, by comparing the bond length, we can find that o ( 4 ) and o ( 2 ) atom is from different group in this complex, 0 ( 4 ) atom from carboxylic hydroxyl, whereas, 0 ( 2 ) from carboxylic carboxide
值得注意的是:在這個雙核配合物中,我們首次發現一種新穎的配位方式: ida上與金屬離子配位的三齒螯合原子是亞氨n原子、一個羧基上的羥基o原子和另外一個羧基上的羰基o原子。We have prepared a series of neodymium binary / ternary complexes, such as nd ( acac ) 3 ' 2h2o, nd ( tfa ) 3 ' 2h2o, nd ( hfa ) 3 ' 2h2o, nd ( dbm ) 3 ' h2o, nd ( acac ) 3phen, nd ( tfa ) 3phen, nd ( hfa ) 3phen, nd ( dbm ) 3phen, nd ( tta ) 3 ( tppo ) 2, nd ( hfa ) 3 ( tppo ) 2, nd ( acac ) 4hpy, nd ( tta ) 4hpy and ndq3. the effects of organic ligands, synergistic coordination agents and different substitution groups for - diketones on effective line width and photoluminescence intensity of neodymium complexes were investigated. the photoluminescence spectra indicate that synergistic coordination agents can shield neodymium ion and impede water molecules penetrating into inner coordination shell to satisfy large coordination number of nd3 + during hydrous synthesis process, so the luminescence intensity of neodymium ternary complexes is stronger than that of neodymium binary complexes
發光光譜研究表明,由於協同試劑的參與,屏蔽了水分子參與配位,降低了羥基( oh )對釹離子激發態能級~ 4f _ ( 3 2 )的猝滅,三元配合物的熒光強度均比二元配合物強,其中配合物nd ( tta ) _ 3 ( tppo ) _ 2在1340nm處的熒光強度最強,適合作為摻雜的光學活性物質,來制備有源光波導材料;在有水工藝條件下,單純地氟化配體未必能提高釹配合物的近紅外發光性能。Complex hydroxy ion
配位羥離子And tg - dsc. 3. n, n ' - disalicylidenedianilines and its transition metal complexes of nicl2 6h2o are synthesized by liquid and solid state reaction at room temperature, and their thermochromism are investigated by ir, far i. r
文中的配合物就是其中之一,中心離子是與c = n雙鍵的n原子以及苯環上鄰位的羥基的氧原子同時進行配位的。分享友人