1 ) the synthesis and structural characterization of 5, 10, 15 - tris ( penta - fluorophenyl ) corrole and its corresponding [ 5, 10, 15 - tris ( pentafluorophenyl ) corrolato ] manganese ( iii ) ; 2 ) the synthesis and structural characterization of series of porphyrin and metalloporphyrins as follows : chloro [ 5, 10, 15, 20 - tetra ( p - methyl - phenyl ) - porphinato ] manganese ( iii ), chloro [ 5, 10, 15, 20 - tetra ( p - methyl - phenyl ) - porphinato ] iron ( iii ), [ 5, 10, 15, 20 - tetra ( p - methyl - phenyl ) - porphinato ] copper ( ) and - oxo - bis [ 5, 10, 15, 20 - tetra ( p - methyl - phenyl ) - porphinatomanganese ( iii ) ]. 2. in the third charpter, a highly selected silver electrode based on 5, 10, 15 - tris ( pentafluorophenyl ) corrole has been prepared, and its response was compared with that of metallo corrole counterpart and 5, 10, 15, 20 - tetra ( phenyl ) porphyrin
3 、制備了以-氧-雙（ 5 ， 10 ， 15 ， 20 -四（對甲基苯基） ）錳
卟啉載體的鉬酸根選擇性電極，並與5 ， 10 ， 15 ， 20 -四（對甲基苯基）
鐵卟啉、 5 ， 10 ， 15 ， 20 -四（對甲基苯基）錳
卟啉、 5 ， 10 ， 15 ， 20 -四（對甲基苯基）銅
卟啉電極的響應性能進行了比較，對電極的膜組份進行了優化，並分別考查了電極的選擇性、 ph值影響、穩定性和壽命等，並將該電極應用於腐蝕抑制劑中鉬酸根的測定。
It is found in porphyrins, and is essential for chlorophyll synthesis
卟啉結構中具有
鐵，是組成葉綠素的必要物質。
Examples of such metalloporphyrins are the iron porphyrins ( e. g. heme in hemoglobin ) and the magnesium porphyrin, chlorophyll, the photosynthetic pigment in plants
例如金屬
卟啉象
鐵卟啉（如血紅素中的亞
鐵）以及鎂
卟啉、植物中的葉綠素與光合色素。
Co ( ii ) - porphyrin all exhibit optical limiting effect excited by three different wavelength ar + laser : 457. 9, 514. 5 and 488 nm and saturable absorption especially for 457. 9 nm
實驗表明，對514 . 5nm波長的光，
鐵卟啉（ fe （ ） tppcl ）有可能作為好的光限幅材料。
Moreover, for co ( ii ) - porphyrin and fe ( iii ) - porphyrin, nonlinear optical absorption and optical limiting properties are studied respectively. results suggest that fe - porphyrin probably become a potential candidate as optical limiting material excited by wavelength 514. 5nm ar + laser
在第四章，研究了
鐵卟啉（ fe （ ） tppcl ）和鈷
卟啉（ co （ ） tpp ）的非線性吸收和熱自散焦光限幅特性。
Figure 2 : the picture are the right is of the heme group in hemoglobin and shows the fe ( ii ) iron atom
血紅蛋白和肌紅蛋白是球蛋白，其結構為血紅素中的鐵在卟啉環平面的上下方再與配位體進行配位，達到配位數為六的化合物。
