電化學循環 的英文怎麼說
中文拼音 [diànhuàxuéxúnhuán]
電化學循環
英文
electrochemical cycling- 電 : Ⅰ名詞1 (有電荷存在和電荷變化的現象) electricity 2 (電報) telegram; cable Ⅱ動詞1 (觸電) give...
- 學 : Ⅰ動詞1 (學習) study; learn 2 (模仿) imitate; mimic Ⅱ名詞1 (學問) learning; knowledge 2 (學...
- 循 : 循動詞(遵守; 依照; 沿襲) follow; abide by
- 環 : Ⅰ名詞1 (環子) ring; hoop 2 (環節) link 3 (姓氏) a surname Ⅱ動詞(圍繞) surround; encircle;...
- 循環 : circulate; circle; round; repeat; loop; period; recurrence; cycling; circulating; mixing; circula...
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In this thesis, in order to reducing the amount of the pt catalyst, improving the electrocatalytic activity of the pt catalysts and utilization ratio of pt, the electrochemical codeposition method by cyclic voltammetry ( cv ) was used to prepare a series pt / moox / glassy carbon ( gc ) composite electrodes with high dispersibility. the composite electrode, pt / moox / gc, was characterized to study its composition and its electro chemical behavior by cv. using the xrd and sem techniques, the size and the dispersion degree of the catalyst particles were studied in presence or absence of moox in the catalyst
為了降低主催化劑pt的用量、提高pt的活性和利用率,本論文利用循環伏安法共沉積制備高分散的pt moo _ x催化劑顆粒,利用循環伏安電化學表徵、 xrd和sem技術研究了引入moo _ x后的催化劑即pt moo _ x顆粒的粒子大小、分散狀態;利用icp - aes定量分析pt moo _ x催化劑顆粒的組成含量;並藉助于電化學方法分別評價了pt moo _ x gc電極催化劑的對甲醇的電催化活性和穩定性、氧還原電催化活性。In the work, it was systemically studied that the effects of two suggested modifying ways on electrochemical characteristics of lithium metal electrode and its behaviors in lithium cell. finally, the action mechanisms of these two modifying ways were analyzed. through the study on pretreatment effects of different cyclic ether on lithium electrode, it was found that 1, 4 - dioxane ( doa ) and 1, 3 - dioxolane ( dol ), both could form a favorable passivating sei film on lithium electrode surface through
研究不同環醚對鋰電極的預處理作用發現, 1 , 4 -二氧六環( doa )和1 , 3 -二氧五環( dol )對金屬鋰電極的表面預處理均可以在金屬鋰表面形成一層良好的sei鈍化膜,對鋰金屬電極起到了保護性作用,使鋰電極具有較小的界面阻抗,有效地提高了金屬鋰電極的充放電循環效率,改善了鋰金屬電極在循環過程中的表面形貌;而doa和dol對金屬鋰電極的表面預處理,不會明顯的影響鋰電極的動力學性能。It combained potentiostat, potentiostatic circuit instrument and ac impedance measurement organticace, which can measure usual dynamic potentio - scan, experiment of dynamic potentio - scan, but also unique measurement of ac impedance measurement, also, this new type electrochemical workstation can carry on complex experiment, sucn as potentio / current scan ac impedance measurement procedural measurment, life - span - circle ac impedance measurement procedural measurement in order to fullfill the goal of track and analysis of parameter in various electrochemical conditions. this graduation thesis indicate the structure, function of the multifunct - ional electrochemical workstation
它把恆電位儀,恆電流儀和電化學交流阻抗分析儀有機地結合到一起,既可以做常規的基本測試如動電位掃描、動電流掃描試驗和電化學交流阻抗測量,也可以做基於這三種基本試驗的程式化試驗,如恆電流充電-電化學交流阻抗測量,電池壽命循環試驗-電化學交流阻抗測量試驗,從而完成多種狀態下電化學體系的參數跟蹤和分析。In this paper, high concentration vanadium electrolyte has been prepared by electrolysis, graphite and graphite felt electrode also have been made, moreover, the electeodes have been activated, and based it, a lab - level vanadium battery has been manufactured. cyclic voltammetry, current step and invariable current charge / discharge method have been used to study the reactive mechanism of electrolysis, of vanadium electrode reaction and of electrode activation, also to investigate maiden charge process and electricity performance of vanadium battery. the influence of electrode activation and trace stibium ion, indium ion added into vanadium electrolyte has been discussed
利用循環伏安法、恆電流階躍法、恆電流充放電循環等電化學方法,探討了電解法制備釩液流電解質的反應機理,考察了釩的電極反應、電極表面活化處理對釩的電極反應的影響,結合電極反應分析了活化的機理;還考察了釩電池初次充電活化過程及恆流充/放電循環的電性能;並且考察了添加銻離子、銦離子對釩電池電性能特別是析氫行為的影響。The low solubility of calcium zincate produced from the chemical reaction of zinc oxide and calcium hydroxide in alkaline solution can improve the cycling life the zinc electrode, and the discharge capacity will tend to be stable. furthermore, the effects of la2o3 additives on the electrochemical performances of zinc electrodes were investigated. the results shows that the addition of la2o3, in zinc electrode can improve the area of reduction peak and the hydrogen evolution potential which means the cathodic hydrogen evolution reaction can be hindered
氧化鋅與氫氧化鈣在堿性溶液中化學反應生成的難溶於堿的鋅酸鈣可以使鋅電極的循環壽命得到提高,放電容量也趨于平穩,此外還考察了氧化鑭對鋅酸鈣電極電化學性能的影響,結果表明:添加適量氧化鑭能明顯改善鋅電極的電化學性能,使鋅電極的還原峰電位正移,電極反應可逆性得到改善,同時也可抑制鋅電極析氫反應的發生,提高了鋅電極的陽極電流,對陽極反應有一定的活化作用;同時還可以改善鋅電極的放電特性,增加電極的放電容量。The corrosion behavior of nanocrystalline ( nc ) copper bulks with various grain sizes prepared from igc ( inert gas condemsation ) and vacuum annealing in comparison with conventional microcrystalline ( mc ) copper ( as - rolled and electrolytic ) in acid copper sulphate solution and neutral solution containing chlorides under free corrosion conditions and anodic polarizations has been studied using potentiodynamic polarization, potentiometric analysis, cyclic voltammetry and electrochemical impedance spectroscopy. x - ray diffraction was used to estimate the grain size of the annealed nc copper. field emission gun scanning electron microscopy and x - ray energy - dispersive spectroscopy was used to characterize the surface morphology and analyze the surface composition after the polarization and potentiometric test of both nc and mc copper
本文研究了用igc (惰性氣體蒸發凝聚原位溫壓法)制備並真空退火到不同晶粒尺寸的納米晶銅和微米晶銅(冷軋紫銅、電解銅)在酸性硫酸銅溶液和中性含氯溶液中,在自腐蝕狀態和陽極極化狀態下的腐蝕性能。使用了動電勢極化、電位測定、循環伏安法( cv )和電化學阻抗譜( eis )等方法。 x -射線衍射( xrd )的方法用來估算納米晶銅晶粒尺寸。The theoretic cycle capacity of limno2 is 286 mah g - 1, which has attracted a great deal of people to research. aim at the impurity of limno2 which was synthesized by the predecessor and the phase change during the electrochemical process, we try several methods, including wet moist chemical method, liquid state method, solide state method and liquid dipping method. at the same time, we study the synthesis of limnc > 2 in defferent atmosphere, for example air, argon and nitrogen
Limno _ 2具有286mah ? g ~ ( - 1 )的理論容量,這種高容量材料深受廣大研究者的關注,針對前人合成出的還有少量雜相和在電化學循環過程中出現相變四川人學碩l :學位論文的問題,我們嘗試了幾種合成方法:濕化學法、液相法、固相法和溶液浸漬法,並在不同氣氛:空氣、氮氣和氫氣中進行limnoz的合成研究。4. a novel amperometric sensor has been constructed for the determination of h2o2. it was based on catalyzing electroreduction of hydrogen peroxide by metal hexacyanoferrate, which were electrodeposited on gold wire electrodes, under a certain potential
利用循環伏安法,在金電極表面電化學沉積一層鐵氰酸鎳膜( nihcf ) ,在一定電位條件下,它能快速催化還原過氧化氫,其響應電流與過氧化氫的濃度呈線性關系。Secondly, better performance lifepo4 / c composite was synthesized by adding proper content of sucrose to the reactants, test results exhibited the initial discharge capability could get 130mah. g - 1 and the capability didn ’ t fade down after more than ten cycles ’ test
2 .添加適量的蔗糖制備出電化學性能良好的lifepo _ 4 / c復合的正極材料,其初始放電比容量高達130mah . g - 1 ;經10次充放電循環,材料的比容量幾乎不衰減。Results obtained by different electrochemical measurements show that the amounts of co in samples have great influence on their electrochemical capacities. while measured co was doped, the electrode has better capacity property, lower impedance and higher utilization, and can be charge - discharged at high current of 40ma
電化學測試結果得出化學摻雜的配比對電化學性能影響很大,適量摻雜的mno _ 2電極比未摻雜的mno _ 2電極具有更好的循環性能和電容性能。The results show that mno which not be modified can not be use as electrode active materials because of its poor electrochemical activity. meanwhile, the rechargeabilify of mno modified by bi and pb is improved. bismuth could prolong the second electron equivalent discharge and lead could improve the first electron equivalent discharge performance
I44 )對熱分解產物進行了充放電,循環伏安,恆電流極化, tafe曲線分析,交流阻抗分析,得出未摻雜的mno直接作為電極活性材料,其電化學活性很差,但通過摻bi , ph進行改性,提高了其可充性, 1的影響主要在於第二電子放電, ph則可以延長第一電于放電The charge and discharge performances of different composites were studied by the charge and discharge ; the structures of composites were characterized by sem ; the electrochemical properties of sulfur positive materials were characterized by cyclic voltammetry and eis. we studied the charge process, discharge process, charge - discharge efficiency, self heat, and self - discharge of lithium - sulfur system on system shuttle constant, conduct the mechanism of these processes and simply analyse them
以充放電技術研究了不同類別復合正極的充放電性能;以掃描電鏡技術觀測了復合正極的表面形貌;以循環伏安技術和交流阻抗技術研究了復合正極電極的電化學性能;並初步探討了鋰-硫電池體系中充電過程、放電過程、充放電效率、自熱和自放電等對體系飛梭常數的影響,推導了這些過程的機理並簡要的進行了分析。Sub - c mh - ni power batteries were prepared with excellent electrochemical performance based on the research of the high rate performance at different temperature. the change of temperature, impedance and weight loss was investigated in the process of recycle at high rate. it showed that the discharge time is 5. 9min at 10c and the middle voltage is 1. 05v
三、根據對電池大電流和溫度性能的研究,研製了具有較好電化學性能的動力型鎳氫電池,並分別測試了電池在大電流循環過程中的溫度、內阻、重量和正負極板等的變化情況,以此分析引起電池性能衰減的原因。Some novel results are obtained, which will not only provide some theoretical bases for the optimal design and performance improvement of real thermodynamic cyclic equipments such as ferroelectric refrigerators, magnetic refrigerators and gas heat engines but also promote the development of new fields such as gas refrigerators for ultra - low temperature applications, molecule refrigerators and laser refrigeration technologies
這些結論將對鐵電製冷機、磁製冷機、氣體熱機等實際的熱力學循環裝置的優化設計或性能改善提供理論指導,對極低溫下的氣體製冷機、分子製冷機和激光製冷技術等新領域也將所啟發和促進。There are two main factors resulting in fading capacity and poor cyclability, one is the john - teller distortion of mn3 +, and the other is mn dissolution to electrolyte. the main objects of this paper are to resolved these key problems effecting on the performance of batteries. during the research of suppressing jahn - teller distortion, low valence cation ( al 、 mg ) and anion ( f ) doped method are usually adopted
針對limn2o4正極材料在電化學循環過程中發生jahn - teller畸變和mn在電解液中溶解這兩個導致容量衰減和循環性能劣化的關鍵問題,分別採用al 、 mg陽離子摻雜和al / f 、 mg / f陰陽離子復合摻雜兩種措施,對尖晶石結構limn2o4正極材料進行了改性研究。The significant capacity loss of the spinel limn2o4 during cycling hereby prevents its wider use as cathode materials for lithium secondary batteries. there are two main factors resulting in fading capacity and poor cyclability, one is the jahn - teller distortion of mn3 +, and the other is mn dissolution to electrolyte. the main objects of this paper are to resolved these key problems effecting on the performance of batteries
針對limn _ 2o _ 4正極材料在電化學循環過程中發生jahn - teller畸變和mn在電解液中溶解這兩個導致容量衰減和循環性能劣化的關鍵問題,分別採用陰陽離子復合摻雜和尖晶石晶粒表面包裹兩種措施,對尖晶石結構limn _ 2o _ 4正極材料進行了改性研究。Our group has prepared nanometer - scale metal films in layer structures on glassy carbon ( gc ) substrate by cyclic voltammetric deposition. by using co as probe molecule, we have revealed for the first time, abnormal ir effects ( aires ) on these layer nanostructured films. the alres consists of several abnormal ir features including the enhancement of ir absorption, the inversion of ir band direction ( anti - absorption ), and the increase of fwhm ( increase of the number of different adsorption sites )
本研究小組採用電化學循環伏安電沉積法在gc基底上制備層狀納米結構金屬薄膜,以co作為分子探針,觀察到異常紅外效應( aires )光譜特徵,即co等探針分子發生紅外吸收增強、紅外譜峰方向倒反(反吸收)和譜峰變寬(振動能級離散程度增加) 。The surface treatment was founded to be effective in reducing the rate of mn dissolution into electrolyte and improving cyclability of spinel. after bulk ni - doped spinel lini0. 1mn1. 9o4 was coated with licoo2, the cyclability of material is better than that of pure s
電化學性能測試表明, oz型層狀理錳氧化物具有優良的電化學循環性能, co摻雜使其容量提高, zn摻雜則使其容量降低。At the same time, we test the catalytic activity by electrochemistry circle volt - ampere method, testing dissociation efficiency of methanol using gas chromatography, analyzing and characterization by sem, xrd and laser particle size analysis
用電化學循環伏安法測試催化劑的電催化活性、用氣相色譜( gc )法測試甲醇分解效率,並用sem 、 xrd 、激光粒度分析等分析和表徵催化劑的結構形貌、物相組成、粒度分佈。The results of electrochemistry circle volt - ampere tests show that that ru02 - tio2 has catalytic activity for methanol oxidation, ni - al2o3 perpetrated by anode oxidation method has obvious catalytic activity. pt / c catalyst is the best catalysts for methanol oxidation of all the prepared catalysts
電化學循環伏安測試表明, ruo _ 2 - tio _ 2催化劑顯示了一定的催化活性,採用陽極氧化法制備的ni - al _ 2o _ 3對甲醇表現出較為明顯的催化活性, pt c催化劑粉體的電催化活性最強。分享友人