amido group 中文意思是什麼
-
4. the interaction between la3 + and mp - 11 would decrease in the intensity of the soret band and shift the band position, because of the strong coordination action of la3 + with o of the carboxyl group in the heme group and weak interaction of la3 + with o of the amido group in the peptide. the interaction also increases in the non - planarity of the heme group
由於la ~ （ 3 + ）與血紅素上羧基氧o配位鍵合作用較強，而與多肽鏈上的酰氨氧o鍵合作用較弱，因此使mp - 11的soret帶吸收值下降，峰位紅移，血紅素環的非平面性增加。 -
It was found that in the simulated physiological solution, the hydrogen bindings between some amido groups in the mp - 11 molecules are decomposed and the mp - 11 dimers become monomers. it induces the increase in the contents of the a - helical and ( 3 - turn conformation, the decrease in the content of the random coil conformation of mp - 11 as well as the increase in the exposure extent of the heme group. therefore, the reversibility of the electrochemical reaction and the electrocatalytic activity of mp - 11 for h2o2 reduction increase comparing the situation in the aqueous solution
發現在模擬生理條件下， mp - 11分子的多肽鏈上一些酰氨基的氫鍵發生了解離，使部分雙聚的mp - 11分子變成單體分子， mp - 11分子二級結構中-螺旋和-轉角結構的含量增加，無規捲曲結構含量降低，導致了mp - 11分子中血紅素的暴露程度變大，因此mp - 11電化學反應的可逆性和對h _ 2o _ 2還原的電催化活性比在水溶液中有所增加。
分享友人