本體熱聚合 的英文怎麼說
中文拼音 [běntǐrèjùgě]
本體熱聚合
英文
bulk thermal polymerization- 本 : i 名詞1 (草木的莖或根)stem or root of plants 2 (事物的根源)foundation; origin; basis 3 (本錢...
- 體 : 體構詞成分。
- 聚 : 動詞(聚集; 聚積) assemble; gather; get together
- 合 : 合量詞(容量單位) ge, a unit of dry measure for grain (=1 decilitre)
- 本體 : 1 [哲學]noumenon; thing in itself (德國哲學家康德唯心主義哲學中的主要概念,指與現象對立的不可認...
- 聚合 : 1 (聚集到一起) get together2 [化學] (單體結合成高分子化合物) polymerization; polymerize 3 [生...
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In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術,有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應,提高了聚合物大分子鏈中有機硅鏈節的含量;利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵,並通過對共聚產物力學和吸水率的測試,證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能;從分子設計角度出發,利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體: ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷;利用核磁共振對新型硅烷單體結構進行了證實;研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液,且其聚合產物具有較高的力學及耐水性能。The results indicated that the dimension, shape and purity of base material could meet the functional demand of solid lubricant ; the thermal decomposition temperature of ptfe resin exceeds 400 c, but organic and inorganic packing filler added in ptfe made the water absorption rate of composite material increased, melting temperature and decomposition temperature decreased, in the meanwhile oxidative decomposition reaction was accompanied ; polar groups such as c = o, c - o - c and so on in the carbon fiber surface is advantageous to increase compatibility with other components and interlayer shearing strength ; uniform design experimental method could help to find the relationship between formula and frictional property by relatively small tests. the developing trend of each formula ' s friction coefficient could be showed by fitting curve ; the friction coefficient with no copper powder or graphite in formula was relatively big. this fact showed that copper powder and graphite should be used cooperatively ; it was found that when the ratio of copper powder to graphite by weight is 15 : 60, 30 : 30 - 40 and 60 : 15 - 30 respectively, the friction coefficient was relatively small. the degree of crystallinity of pure ptfe reached maximum by air cooling and the abrasion loss also reached maximum among three ones ; at the same time, the abrasion loss of solid lubricant sample was also the biggest among three ones ; when solid lubricant matched with 45 # steel axle or gcrl5 steel axle, lubricant transfer film could be formed on metal surface, thus direct contact between the surface of metal friction pair rings was reduced. their working life was elongated extremely ; there was mainly much graphite, a little ptff, moo3, feso4, cus and so on in lubricant transfer film
試驗結果表明:所選原料的尺寸、形狀及純度可滿足固體潤滑劑的性能要求;聚四氟乙烯樹脂熱分解溫度超過400 ,但在ptfe中加入無機填料會使復合材料吸水率提高,熔融溫度及分解溫度降低,且伴有氧化分解反應;碳纖維表面含有c = o及c - o - c等極性基團,有利於提高其與其它組分的相容性,提高層間剪切強度;均勻設計試驗方法能夠用較少的試驗次數找出配方與摩擦性能間的關系,擬合曲線基本能表示各配方的摩擦系數發展趨勢;配方中不加銅粉或不加石墨,其摩擦系數均較高,說明銅粉和石墨應該配合使用;當銅粉15份、石墨60份時,銅粉30份、石墨30 - 40份時,銅粉60 、石墨15 - 30份時,摩擦系數均具有較低值;純聚四氟乙烯樹脂在空氣冷卻時結晶度最大,磨損量也是三者中最大的;同時,固體潤滑劑試樣在空氣冷卻時的磨損量也是三者中最大的:不論是固體潤滑劑與45 #鋼軸配副或是固體潤滑劑鑲嵌入銅套后與gcr15鋼軸配副,在金屬表面均可形成潤滑轉移膜,從而減少金屬摩擦副表面間的直接接觸,大大延長其使用壽命;轉移膜中主要含有較多的石墨、少量聚四氟乙烯、 moo 。The essential elements and process of gas reservoir formation of ordovician in ordos basin have been annalysed systematicly and scientificly by means of the theory and method of organic geochemistry and tectonic geology in this dissertation. the several advanced techniques, such as gas generation thermal simulation, on - line individual gas compounds carbon isotope determination ( py - gc - c - ir - ms ), the analysis technique of light hydrocarbons and biomarkers in natural gas, gas migration simulation and gas carbon isotope determination in fluid inclusions, have been applied to focuse on the study of the gas generation mechanism of souce rock, correlation between gas and source rock, reservoir formation history, migration direction, charging road in detail
應用有機地球化學和構造地質學理論和方法對鄂爾多斯盆地奧陶系天然氣地質研究中薄弱環節成藏要素和作用進行了系統科學分析。利用烴源巖生氣定量熱模擬技術、熱模擬在線碳同位素實驗技術、氣體輕烴和生物標志物分析技術、運聚成藏物理模擬技術和包裹體中碳同位素分析技術等多種先進的實驗技術對烴源巖的生氣機理、氣源和混合比、成藏史、充注路徑、運移方向和構造作用與成藏關系等問題進行了深入的研究,在前人研究的基礎上,經過本次大量的實驗分析和綜合研究,提出了一些新的認識。The nanometer tin dioxide powder aspects were prepared with the colloid - hydrothermal system which takes the merit of sol - gel law and hydrothermal method, and combine forming new preparing method - colloid - hydrothermal after the analysis of a large number of documents to the home and abroad and comparing to more than ten kinds of methods preparing the nanometer powder aspect, the nanometer stannic dioxide powder is prepared with the colloid hydrothermal system, and has avoided the pure sol - gel law to calcine with high temperature later period which causes the hard agglomeration
本文通過對國內外大量文獻的分析,對制備納米粉體的十多種方法進行了比較。取溶膠?凝膠法和水熱法各自的優點,結合形成新的制備方法? ?膠體水熱法。用膠體水熱法制備納米二氧化錫粉體,避免了純溶膠?凝膠法後期用高溫煅燒得到二氧化錫超細粉體時產生的硬團聚現象。This dissertation focuses on how to develop a high performance damping mechanism based on multi - energy transitions, which is independent or little dependant with the viscoelasticity of polymer matrix. three sections are mainly included in this dissertation as follows : chlorinated polyethylene ( cpe ) / piezoelectric ceramic ( pzt ) / vapor grown carbon fiber ( vgcf ) composites ; cpe / 2, 2 ' - methylene - bis - ( 4 - methyl - 6 - cyclohexylphenol ) ( zkf ) / vgcf composites ; organic hybrids made from cpe and small molecules cpe / pzt / vgcf composites : the damping composites of multi - energy transitions mechanism were produced by mixing pzt and vgcf into cpe. in this system, the mechanical vibration energy that was transmitted to cpe was found to convert into joule ' s heat through conduction paths between vgcf in the polymer matrix, so the vibration fades away
本論文主要包括三個方面的研究內容: ?氯化聚乙烯( cpe ) /壓電陶瓷( pzt ) /氣相生長碳纖維( vgcf )復合材料; ? cpe /雙[ ( 2 -羥基- 3 -環己基- 5 -甲基) -苯基]甲烷( zkf ) / vgcf復合材料; ? cpe基有機小分子混雜型復合材料cpe / pzt / vgcf減振復合材料:利用壓電和導電填料填充高聚物基體,當復合材料受到機械振動時,通過高聚物基體將機械振動能傳遞到壓電陶瓷粒子上,利用壓電陶瓷的壓電效應,將機械能轉換成電能,則電流在導電粒子產生的迴路中流動,由於導電迴路具有一定的電阻,所以電能又轉變成熱能耗散掉,從而起到減振的目的。In this paper srco3 powders are first time synthesized successfully by low temperature solid state reaction with srcl2. 6h2o and ( nh4 ) 2co3. the size of srco3 is about 30 - 50nm. compared with liquid state method, this method produces little conglomeration and is easy to synthesize nanopowders
本論文根據低熱固相化學反應原理首次以srcl _ 2 ? 6h _ 2o和( nh _ 4 ) _ 2co _ 3為原料成功合成了30 ? 50nm的srco _ 3粉體,克服了一般液相沉澱法易發生粉體團聚和難于制備納米級srco _ 3粉體的弊端,並通過研究找到了低熱固相反應終點的標志。With 5 % - 15 % ( by mass fraction ) ethyl - benzene as diluent, styrene - acrylonitrile random copolymer was synthesized by means of the continuous bulk polymerization of styrene and acrylonitrile initiated by heating
摘要以苯乙烯、丙烯腈在添加質量分數為5 % ~ 15 %的乙苯作稀釋劑的條件下,進行熱引發連續本體聚合,合成了無規苯乙烯丙烯腈共聚物。The apparent activation volume calculated by the model is about 2500a3, which was ten times larger than that of usual amorphous alloy and was at the same range of the amorphous polymer. the model shows the main deformation mechanism of nanocrystalline ag is grain boundary sliding, which in some extent declares the similar forms of equation with amorphous alloys. with the ananlysis to the hrem of nanocrystalline ag, the discrepancy of the apparent activation volume between the nanocrystalline ag and amorphous alloys is interpreted by the loss of atoms participating in grain boundary sliding without enough reconstruction by the movement of atoms under the low temperature
運用晶界滑移的熱激活理論對壓縮實驗結果進行了數值擬合,擬合曲線與實驗數據符合很好,得到了晶界滑移的表觀激活體積(熱激活基本單位體積與局域瞬態應變的乘積) ,約為2500a ~ 3 ,先當于幾十個原子體積大小的瞬態變化,約為非晶合金的10倍以上,與非晶高聚物的表觀激活體積相當。The effect of organic crystal on the conductive property of pu / cb composites was studied in this paper weightily. the structure and thermal property of composites are indicated with sem, xrd and dsc
本文重點研究了有機晶體對聚氨酯炭黑復合體系的電性能的影響,並用sem 、 xrd 、 dsc等測試方法對體系結構和熱性能進行了表徵。This part emphasizes the synthesis of nanoarrays, aiming at controlling the size and distance of nanocrystallites using calixarene derivatives by altering the size, length and chemical structure of the organic molecules ; 2. this part emphasizes in situ synthesis strategy for fabrication of polymer network of zns based nanopowder, aiming at size controls, coating and preventing agglomeration following " one - pot " synthesis ; this method fits to low cost, large scale production ; 3. according to development in zno nanomaterials, we first report on the synthesis, characterization of amorphous zno, aiming at describing the principles and approaches of synthesis techniques, optical properties, spatial structure and doped effect ; the amorphous zno displays cage - like structure, showing a strong ultraviolet emission while the visible emission is nearly fully quenched, a potential uv - emission material ; 4
本論文以量子結構自組裝為出發點,提出利用杯芳烴及其衍生物的化學受限反應實現尺寸可調半導體納米粒子自組裝;提出有機聚合網路原位組裝zns基納米熒光粉方法,把熒光粉的納米化、包敷、防團聚在「一鍋」反應中完成,適于低成本,批量生產;根據當前zno的研究情況,我們首次合成了非晶zno ,研究了它的光學性質,確定了它的結構,並對其摻雜進行了初步的研究,非晶zno表現出強的深紫外發光特性,而可見發射非常弱,是一種有巨大潛在應用價值的深紫外發光材料;利用非晶zno的亞穩特性,對晶化過程中非晶zno納米晶zno三維受限量子結構特性,界面特性進行了深入的研究;利用固相熱分解一般受擴散控制特性,實現了尺寸可控的zno三維量子結構的自組裝;利用非晶zno的高度分散性,容易均勻成膜特性,實現了非晶籽晶誘導低溫液相外延自組裝生長高取向zno晶體薄膜。The intercalation and exfoliation behavior of lamellar clay in the thermoset resin / clay composites during curing was studied in this paper. for epoxy / organoclay system, intercalation and exfoliation behavior of organoclays in epoxy resin has been investigated
本論文以熱固性樹脂/粘土復合體系為研究對象,主要研究了分散在聚合物基質中的層狀粘土在固化過程中插層和剝離行為。The synthesis of midbody lactide for the preparation of pla is also catching more attention in this field. the present situation of lactide synthesis is high reaction temperature and low production ratio which lead to its high production cost and hamper its application in the material. the present research hot spot mainly focus on the improvement of reaction technique as well as the selection of catalyst
制備聚乳酸的中間體丙交酯( lactide )的合成也越來越受到重視。丙交酯的合成長期以來存在合成溫度高,收率較低的現狀,以至生產成本偏高,不能比較經濟規模化地應用於材料領域。研究的熱點主要包括丙交酯合成工藝條件的改進,催化劑的選擇與優化。The important research is about the theory and methods of the cluster analysis in view of statistical theory, the theory and methods of fuzzy cluster analysis, the fkn " s structure and the fkn ' s study algorithm ( fkn, fuzzy kohonen network ) - the organic fusion of the fuzzy c - means algorithm and self - organized feature map neural network. the paper proposes the ifkn ( improved fkn ) on the basis of the hard classification idea and the soft classification idea, then carries on the cluster analysis of the artificial synthetic control chart time series through matlab program and tt ? cluster result matches the cluster result of the famous dataengine " s software of the intellectual data analysis and data mining from german mit company. finally, the paper discusses the applying of the cluster analysis to the control process, which can be widely applied to the pattern recognition of the parameter " s changing trend during the control process and the image partition processing, and utilizes the ifkn to recognize the thermotechnical parameter " s changing trend based on the engineering of clinker sintering rotary kiln automatic control system of guizhou " s aluminium factory, through which good effect is obtained
數據挖掘技術在商業領域中已廣泛使用,然而在工業過程式控制制中的應用卻極少,本文正是在這種背景下,對數據挖掘中的聚類分析方法及其在工業過程式控制制中的應用研究作了償試,重點研究了基於統計理論的聚類分析理論和方法,模糊聚類分析理論和方法及模糊kohonen網路( fkn )的結構與學習演算法,即模糊c ? ?均值演算法與自組織特徵映射神經網路( kohonen網路)的有機融合,並根據硬分類思想及軟分類思想提出了改進的模糊kohonen網路( ifkn ) ,通過matlab編程對人工合成控制時序圖數據集進行聚類分析,其聚類效果與當今廣泛使用的數掘挖掘軟體平臺,德國mit公司著名的dataengine智能數據分析和數掘挖掘軟體的聚類效果相當,最後,論述了聚類分析在控制中的應用,它可以用於過程式控制制中的參數變化趨勢的模式識別及圖象分割處理等具體應用中,並以貴州鋁廠熟料燒結回轉窯自動控制系統為工程背景,利用ifkn識別其熱工參量變化趨勢,取得了較理想的效果。Conclusion : based on bulk polymerization of phema artificial cornea, we use 2 biocompatibility methods to increase the toughness of porous skirt, which greatly increase the tear resistance of artificial cornea
術語解析:本體聚合:不加其他介質,只有單體本身,在引發劑、熱、光等作用下進行的聚合反應。Polymer / montmorillonite ( mmt ) nanocomposites is a kind of novel composites and arouses great interest due to its excellent synthetical properties. in this paper, different polymerization methods are used to prepare pmma / mmt nanocomposites, whose thermal property and mechanical properties are obviously improved. the effects of mmt and organo - mmt ( ommt ) on the bulk polymerization mechanisms of methyl methacrylate and terminal polymer structure are also studied
本文通過不同的聚合方式制備得聚甲基丙烯酸甲酯蒙脫土納米復合材料,改善了材料的耐熱性能和力學性能等;重點研究了蒙脫土( mmt )以及有機蒙脫土( ommt )對本體法甲基丙烯酸甲酯( mma )聚合反應機理以及聚合物結構的影響。The tio2, cds and cds - tio2 films on the common glass substrate were prepared, respectively, using ti ( oc4h9 ) 4, cd ( cooch3 ) 2 and scn2h4 as raw materials by sol - gel method. the influences of manifold preparing parameters ( such as the concentration of sol, the amount of the peg. the number of coatings, the heat - treated temperature and time ) on the structure and performance were studied
本文採用溶膠-凝膠技術,以鈦酸丁酯、乙酸鎘和硫脲為原料,以普通玻璃片為載體,制備了納米tio _ 2薄膜、 cds薄膜和cds - tio _ 2復合半導體薄膜,研究了制備過程中多種制備參數(如溶膠的濃度,聚乙二醇( peg )的加入量,鍍膜層數,熱處理溫度及時間)對薄膜結構和性能的影響,採用x -射線衍射( xrd ) 、掃描電鏡( sem ) 、能譜分析( edxa ) 、紫外-可見吸收光譜( uv - vis )等測試手段對各薄膜進行了結構和物性表徵。分享友人