磷鉬酸反應 的英文怎麼說
中文拼音 [līnmùsuānfǎnyīng]
磷鉬酸反應
英文
phosphomolybdic acid reaction-
In order to improve the electro - catalytic activity of platinum based catalyst to methanol oxidation, in this thesis, firstly prepare heteropoly acid modified pt / gc electrode with different concentration by cyclic voltammetry method, and then test the cyclic voltammetry curves individually in vitriolic and methanol solution. the study shows the best concentration for both phosphomolybdic acid and phosphotungstic acid is 1 10 ~ ( - 3 ) mol / l. and find the more heteropoly acid modified on electrode, the lower peak - up potential towards methanol because of the existence of oxygenous species
為了改善鉑基催化劑氧化甲醇的催化活性,本論文首先通過循環伏安掃描法制備了不同濃度磷鉬酸和磷鎢酸修飾的pt / gc電極,通過研究pt / gc電極在修飾前後在硫酸溶液中及含甲醇的硫酸溶液中的循環伏安行為發現,磷鉬酸和磷鎢酸均能在ptru / c電極上發生氧化還原反應,而且雜多酸修飾濃度對pt / gc電極氧化甲醇的催化活性有很大影響。The traditional catalyst used in acetal ( ketal ) synthetic reaction is strong inorganic acid. but there is some limits to its use because of its side reaction, strong erosion and liability to pollute the environment. molybdophosphoric acid is used as catalyst and three condensation products are prepared through the direct reaction of aldehydes ( ketones ) and ethylene. in addition, several elements of affecting the reaction is researched. it is proved that molybdophosphoric acid is very active as catalyst in less addition, the product yield is quite high and the quality of reuse is quite good
縮醛(酮)合成反應的傳統催化劑為無機強酸,但由於副反應多、腐蝕性強和易污染環境等缺點,其使用受到限制.用磷鉬酸為催化劑,通過醛(酮)與乙二醇直接反應得到了三種縮合產物.對影響反應的諸因素進行研究,結果表明,用磷鉬酸作催化劑,用量小,活性高,產品收率較高,且重復使用性能較好Abstract : the traditional catalyst used in acetal ( ketal ) synthetic reaction is strong inorganic acid. but there is some limits to its use because of its side reaction, strong erosion and liability to pollute the environment. molybdophosphoric acid is used as catalyst and three condensation products are prepared through the direct reaction of aldehydes ( ketones ) and ethylene. in addition, several elements of affecting the reaction is researched. it is proved that molybdophosphoric acid is very active as catalyst in less addition, the product yield is quite high and the quality of reuse is quite good
文摘:縮醛(酮)合成反應的傳統催化劑為無機強酸,但由於副反應多、腐蝕性強和易污染環境等缺點,其使用受到限制.用磷鉬酸為催化劑,通過醛(酮)與乙二醇直接反應得到了三種縮合產物.對影響反應的諸因素進行研究,結果表明,用磷鉬酸作催化劑,用量小,活性高,產品收率較高,且重復使用性能較好
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