高聚物分子量 的英文怎麼說

中文拼音 [gāojùwùfēnziliáng]
高聚物分子量 英文
molecular weight of high polymer
  • 高 : Ⅰ形容詞1 （從下向上距離大; 離地面遠） tall; high 2 （在一般標準或平均程度之上; 等級在上的） above...
  • 聚 : 動詞（聚集; 聚積） assemble; gather; get together
  • 物 : 名詞1 （東西） thing; matter; object 2 （指自己以外的人或與己相對的環境） other people; the outsi...
  • 分 : 分Ⅰ名詞1. （成分） component 2. （職責和權利的限度） what is within one's duty or rights Ⅱ同 「份」Ⅲ動詞[書面語] （料想） judge
  • 子 : 子Ⅰ名詞1 （兒子） son 2 （人的通稱） person 3 （古代特指有學問的男人） ancient title of respect f...
  • 量 : 量動1. （度量） measure 2. （估量） estimate; size up
  • 高聚物 : [有機化學] high polymer; eupolymer; superpolymer; macromol（cule）
  1. In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased

    同時採用有機硅單體延遲滴加及添加水解抑制劑等技術，有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應，提高了聚合物大分子鏈中有機硅鏈節的含量；利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵，並通過對共聚產物力學和吸水率的測試，證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能；從分子設計角度出發，利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體： ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷；利用核磁共振對新型硅烷單體結構進行了證實；研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液，且其聚合產物具有較高的力學及耐水性能。
  2. The article analyze the concrete drying shrinkage mechanism, find the major factors of affecting the drying shrinkage, analyze the lack of shrinkage reducing agent, who be of low molecular weight and line chain, design a new shrinkage reducing agent ? ? shrinkage reducing agent of poly - acrylate. the shrinkage reducing agent of poly - acrylate is mainly composed of crylic acid 、 cinnamene 、 poly - glycol 、 solicitating agent 、 chain transferring agent and activator, which come by these processes of polymerization 、 esterifing and neutralization to form a pectinate polymer, which have a high molecular weight and many poly - oxidative alkenes

    論文分析了混凝土乾燥收縮的機理，確定了影響乾燥收縮的關鍵因素，分析已有低分子量的、直鏈型減縮劑的不足，設計了一種新型的減縮劑? ?聚丙烯酸鹽類減縮劑，其主要由丙烯酸、苯乙烯、聚乙二醇、引發劑、鏈轉移劑、催化劑等經過聚合、酯化和中和反應，生成一種高分子量的、含聚氧化烯鏈的聚合物。
  3. The recombinants were constructed by transforming ppic9 a - xynb into p. pastoris gs115. the assay results revealed that the xylanase gene xynb was overexpressed and secreted effectually in p. pastoris. in 3l fermentor the expression level of xylanase xynba exceeded 1200iu / ml and the expressed xylanase had normal bioactivity. the molecule weight of xynba was determined as about 31kd which is higher than 23kd of original enzyme xynb from streptomyces olivaceoviridis a1. xynbb was gotten by deglycasylation of xynba, whose molecule weight returned to 23kd. we comparised the enzymatic properties of xynba expressed in p. pastoris, xynbb deglycasylated from xynba and xynb produced from streptomyces olivaceoviridis al : there was little difference among the three enzymes on optimal ph, the optimal ph of xynb and xynba were both 5. 2, the optimal ph of xynbb was 5. 0 ; the optimal temperature of xynb and xynba were both 60 c, while the optimal temperature of xynbb was 50 ? ; because of glycosylation the thermal stability of xynba was better than xynb and xynbb ; the specific activity of xynba and xynbb were 883. 88iu / mg and 832. 5hu / mg respectively, which were both lower than 2814. 45iu / mg of xynb ; the km values of xynb and xynba were similar to each other which were 21. 56 ( g / kg ) and 20. 87 ( g / kg ), while the km value of xynbb was 27. 10 ( g / kg ) ; the fmax of xynba and xynbb were 4568umol / mg. min and 5329umol / mg. min respectively which were lower than 27623 umol / mg. min of xynb ; additionally all of the three enzymes did not display cellulase activity. they all had well resistance to pepsion and trypsin, and were not sensitive to metal iron, surface active agent and chelating agent. the analysis of different xylans enzymatic hydrolysate revealed : by xynba, that the main constitutions of enzymatic hydrolysate of birch wood xylans were xylotriose and xyloquaiose, which account for 68. 43 % and 16. 50 % respectively, additionally there was 11. 79 % of xylobiose ; the main constitutions of enzymatic hydrolysate of corncobs xylans were xylobiose and xylotriose, which account for 81. 78 % and 11. 55 %. the result indicated that this xylanase was a kind of 1, 4 - b - d - xylanohydrolase and was fit to used in industrial procession of xylooligosacc harides

    進一步對xynba進行了脫糖基化處理得到xynbb ，其分子量恢復到23kd ，證明xynba是糖基化蛋白。通過對畢赤酵母重組表達的木聚糖酶xynba 、脫糖基化的木聚糖酶xynbb以及橄欖綠鏈黴菌a1所產原酶xynb之間酶學性質的比較發現：三種酶的最適ph差異不大， xynb和xynba均為5 . 2 ， xynbb為5 . 0 ； xynb和xynba的最適溫度均為60 ， xynbb降為50 ：在耐熱性上， xynba由於糖基化作用熱穩定性明顯高於未糖基化的xynb和xynbb ； xynba和xynbb的比活性分別為883 . 88iu mg和832 . 51iu mg ，明顯低於原酶的比活2814 . 45iu mg ； xynb和xynba的km值相當，分別為21 . 56 （ g kg ）和20 . 87 （ g kg ） ，而xynbb的km值較大為27 . 10 （ g kg ） ； xynba和xynbb的vmax相差不大，分別為4568 mol mg ? min和5329 mol mg ? min ，明顯低於xynb的27623 mol mg ? min此外三種酶均無纖維素酶活性，對胃蛋白酶和胰蛋白酶有很好的抗性，且對作用環境中的各種離子、表面活性劑、螯合劑不敏感。通過對不同木聚糖的酶解產物的糖份分析發現：以樺木木聚糖為底物時，酶解產物主要為木三糖和木四糖，含量分別為68 . 43和16 . 50 ，另外還含有11 . 79的木二糖；以玉米芯木聚糖為底物時，酶解產物主要為木二糖和木三糖，含量分別為81 . 78和11 . 55 。
  4. Molecular weight distribution curve of 1, 1 ' - diaformacylferrocene - o - phenylenediamine polycondensate has triplet and polydispersity is a little large. it should be pointed out that the fe2p3 / 2 peak appears basically near fe2 + characterizing 708ev in xps of the two polycondensates, this means that the ferrocene group is rather stable in the polycondensates

    其中， 1 ， l 』一幾甲酞二茂鐵鄰苯二胺縮聚物的分子量分佈曲線呈現三重峰，表明在高轉化率時發生大分子鏈轉移後生成帶支鏈的高分子，其多分散性也較大。
  5. Implants for surgery - ultra - high molecular weight polyethylene - powder form

    外科用植入物.超高分子量聚乙烯.粉劑型
  6. The interface behavior between essence and ethylene - vinyl acetate copolymer pallets was studied so that necessary data were obtained to guide the preparation of fragrant masterbatch. the adsorption type and wettability between essence and the copolymer pallets were analysed by measurements of fourier transform infrared spectrum, surface tension, contact angle and specific surface area. the technical factors affecting absorptivity such as the charge ratio, temperature, pressure and stirring speed were studied by series of adsorption experiments. the results showed that the adsorption of essence on the surface of ethylene - vinyl acetate copolymer pallets is physical in nature. essence couldn ' t moisten the surface of ethylene - vinyl acetate copolymer pallets absolutely, but it could be soaked into the surface of the pallets partly. adsorptivity could be increased by enhancing the temperature, pressure and stirring speed, but the extension of adsorption time had little influence on adsorptivity

    研究了香精與乙烯/醋酸乙烯共聚物粒子之間的界面行為，以便為香型母粒的制備提供必要的理論依據.利用傅立葉變換紅外光譜、表面張力、接觸角及比表面面積等測定手段，分析了香精與載體之間的吸附類型和潤濕作用.並通過一系列吸附實驗，討論了配料比、溫度、壓力、攪拌等工藝條件對吸附量的影響.結果表明，香精在乙烯/醋酸乙烯共聚物粒子表面的吸附為物理吸附；香精無法完全潤濕載體粒子表面，但可以對其形成部分浸潤；提高溫度、壓力、攪拌速度可以增加吸附量，而延長吸附時間對增加吸附量貢獻不大
  7. Abstract : the interface behavior between essence and ethylene - vinyl acetate copolymer pallets was studied so that necessary data were obtained to guide the preparation of fragrant masterbatch. the adsorption type and wettability between essence and the copolymer pallets were analysed by measurements of fourier transform infrared spectrum, surface tension, contact angle and specific surface area. the technical factors affecting absorptivity such as the charge ratio, temperature, pressure and stirring speed were studied by series of adsorption experiments. the results showed that the adsorption of essence on the surface of ethylene - vinyl acetate copolymer pallets is physical in nature. essence couldn ' t moisten the surface of ethylene - vinyl acetate copolymer pallets absolutely, but it could be soaked into the surface of the pallets partly. adsorptivity could be increased by enhancing the temperature, pressure and stirring speed, but the extension of adsorption time had little influence on adsorptivity

    文摘:研究了香精與乙烯/醋酸乙烯共聚物粒子之間的界面行為，以便為香型母粒的制備提供必要的理論依據.利用傅立葉變換紅外光譜、表面張力、接觸角及比表面面積等測定手段，分析了香精與載體之間的吸附類型和潤濕作用.並通過一系列吸附實驗，討論了配料比、溫度、壓力、攪拌等工藝條件對吸附量的影響.結果表明，香精在乙烯/醋酸乙烯共聚物粒子表面的吸附為物理吸附；香精無法完全潤濕載體粒子表面，但可以對其形成部分浸潤；提高溫度、壓力、攪拌速度可以增加吸附量，而延長吸附時間對增加吸附量貢獻不大
  8. Implants for surgery - ultra - high molecular weight polyethylene - moulded forms

    外科用植入物.超高分子量聚乙烯.模壓成型
  9. ( 3 ) volume shrinkage of composite decreases greatly with wpu increasing, even can arrive a negative number, but thermal stability is still good. ( 4 ) toughening mechanism is that : the formation of high molecular linear amino formate construct is the toughening reason ; hydroxyl - terminated pu - prepolymer and pf react to produce chemical bond effect which participate cure ; carboxyl - terminated pu - prepolymer and pf form semi - ipn which make toughened pf occur maximum

    （ 4 ）通過紅外光譜對pf / pu共混物分子結構進行的定性分析、以及掃描電鏡對沖擊斷面形貌進行的分析，可證明聚氨酯預聚物增韌酚醛樹脂的機理是：兩個體系都是由於高分子量的線形氨基甲酸酯結構而增韌；端羥基pu與pf在共固化中產生化學鍵效應，參與pf的固化；而端羧基pu則與pf形成半互穿網路而增韌。
  10. The results indicate that the product of precipitation polymerization has a higher molecular weight and is better in the capability of inhibiting clay expansion than that of water solution polymerization

    結果表明：沉澱聚合產物分子量高於溶液聚合產物的分子量，在抑制粘土顆粒膨脹性質上優于溶液聚合產物，對提高水溶性聚合物在油田化學領域及其它方面的應用，有著積極的意義。
  11. Abstract : water solution polymerization and precipitation polymerization of ethenyl radical monomers were carried out at same conditions, and the differences between the products in molecular weight and other aspects were investigated

    文摘:針對目前溶液聚合體系中、後期粘度高，熱擴散不利，從而影響分子量提高的問題，進行乙烯基類單體在同等條件的水溶液聚合及沉澱聚合，比較了獲得的聚合物產物在分子量及應用性質上的差異。
  12. Aim : to analyze the mechanism, thermadynamic theoretical basis, dynamic mechanism and influencing factors of thermally induced phase separation ( tips ) in order to completely grasp the factors affecting the size, distribution and form of pores, so that the adjusted range of pore can be widened and the preparation of porous membrane can be repeated and controlled. methods : considering from the structural characteristics of tissue engineered materials, the methods of preparing porous membrane using tips technique, the hermadynamic theoretical basis, dynamic mechanism and influencing factors were analyzed, the problems and investigative directions in the future were also analyzed. tips technique is a process of phase separation of polymer homogenous solution under quenching, and it is suitable for diameter and structural form of the micropore materials prepared using tips are closely correlated with the kind and dispensing proportion of polymer attrnuant, polymer concentration and polymer molecular mass, etc. conducted, including determination of polymer - solvent system phase diagram, study of form and appearance of porous membrane of different thickness, study of form and appearance of porous membrane prepared with systems of different x, which is the parameter of polymer - solvent interaction

    目的:分析熱致相分離成膜過程的機理、熱力學理論基礎、動力學機制以及影響因素，以便充分掌握影響孔度大小、分佈、形態的因素，使孔度調控范圍得以拓寬，使多孔膜的制備能重復可控.方法:從組織工程材料結構特點出發，分析熱致相分離聚合物多孔膜的制備方法及該法成膜的熱力學理論基礎、動力學機制以及影響因素.並分析實驗中存在的問題及今後的研究方向.結果:以熱致相分離法可制備聚合物多孔膜.熱致相分離法制備多孔膜是高聚物均相溶液在淬冷條件下發生相分離的過程，它適用於上臨界共溶溫度型聚合物一稀釋劑二元體系.熱致相分離法成膜的過程，可以認為是旋節線機理佔主導地位.熱致相分離法制備的微孔材料，其孔隙率、孔徑大小、結構形態與聚合物稀釋劑的種類、組成配比、聚合物濃度、聚合物分子量等因素密切相關.結論:可採用熱致相分離技術制備多孔膜，通過改變不同的成膜條件可獲得一系列不同孔徑尺寸和孔徑分佈的多孔膜材料.對熱致相分離成膜過程中聚合物-溶劑體系的相圖測定，不同厚度的多孔膜形貌研究，不同x （聚合物-溶劑相互作用參數）體系所制備的多孔膜形貌等需深人研究
  13. The results from basic properties, shear resistance, pressure strength and point film test show that different low molecular polyamide may affect extrodinary by the properties of cured expoxy resin the higher viscosity, the lower cured activity ( rate ) ; the higher amine number, the stronger cure construction. the cured expoxy resin will prossess unfavourable mechanics when it is cured by the polyamide with both too high viscosity and amine number

    用基本性能、剪切強度、抗壓強度、塗膜性能測定等方法研究了3種不同胺值及粘度的低分子量聚酰胺對環氧樹脂固化物性能的影響.結果表明，聚酰胺粘度大使固化交聯變難，胺值過高易造成固化收縮；同時粘度過大、游離胺含量過高的產品將對固化物各項力學性能不利
  14. Phosphate ester polymers with higher molecular weight have been extensively applied in various fields including medicine and plastics auxiliary, and the lower molecular weight ones are very important in fields such as feedstuff and surfactant

    其中，分子量高的聚磷酸酯近年來在醫藥、塑料助劑等方面有廣泛應用，分子量相對較低的磷酸酯類聚合物在飼料、表面活性劑等方面很重要。
  15. Abstract : polyphenylacetylenes were synthesized by rn ( nbd ) cl 2 and wcl6 / ph4sn catalyst systems in n2 at room temperature. polymers with high yield and high molecular weight were obtained. their structures were characterized by uv, ir, nmr and gpc, respectively. the fluorescence of the polymer solution with different concentration was investigated using variable excitation wavelength from uv to visible region. the relation between fluorescence and polymer structure was studied. the results showed that the molecular chain structure has great influence on fluorescence of the polymers. the emitting peak wavelength of fluorescence for the polymer of high stereoregularity is independent of solution concentration and excitation wavelength. the emitting peak wavelength of fluorescence for the polymer with disordered molecular chain arrangement varies with changing the solution concentration and excitation wavelength, and different emission sites in molecular chains and low emitting yield are shown. the measurement and analysis of fluorescence spectroscopy of polyphenylacetylenes may provide some useful information to judge the molecular chain arrangement in some conjugated polymers

    文摘:使用有機金屬銠、金屬鎢/四苯基錫催化劑體系聚合苯乙炔，分別獲得了高產率和高分子量的聚苯乙炔.使用uv ， ir ， nmr ， gpc等分別對聚合物結構進行了表徵.採用不同波長的激發光對聚合物熒光性能進行研究，詳細分析了聚合物結構與熒光性能之間的關系.研究結果發現，不同聚合物結構對聚合物熒光性能產生很大影響，規整性高的聚合物，將有較高的發光量子效率；聚合物規整性差，將可能導致多個熒光發光結構點，其熒光強度降低.聚合物熒光光譜研究將對某些共軛聚合物結構的規整性分析提供一些有用的信息
  16. The designs of composite material using inorganic filling compounds to reinforce ultra high molecular weight polyethylene ( uhmwpe ) and an improvement on thermal conductivity of polymer working as tribological material were selected as the major research subject in this thesis

    本論文選擇無機填料改性超高分子量聚乙烯（ uhmwpe ）復合材料的材料設計和聚合物作為摩擦學材料時導熱性能、抗壓強度及抗蠕變性能的改進研究作為主要研究方向。
  17. Polymerization and characterization of schiff base type liquid crystal polymers containing crown ethers schiff base type liquid crystal polymers containing crown ethers with high moderate weights were polymerized via low temperature solution polymerization

    以二氨基二苯並冠醚和二醛類化合物為單體，通過低溫溶液聚合法合成了中等分子量的schiff堿型液晶高分子。
  18. Two - step procedure is preferable to prepare high molecular weight poly ( olefin - ester ) s with a high polar monomer content and a high melting temperature

    兩段聚合過程適于制備高分子量的烯烴共聚酯，聚合物收率達90 % ，極性單體的插入率大於10 % ，熔融溫度高達120 。
  19. Data computer processing for relative molecular mass of high polymer by viscosimetry

    粘度法測定高聚物相對分子質量的數據微機處理
  20. The improvement in the determination of relative molecular weight of high polymer by using viscosimetry

    粘度法測定高聚物相對分子質量方法的改進
分享友人
分享到 Line

分享到臉書