disordered region 中文意思是什麼
disordered region
解釋
無序區- disordered : 不正常的
- region : n. 1. 地方，地域，地帶；地區；行政區，管轄區，區；左近，鄰近；（大氣、海水等的）層，界，境。2. 【解剖學；動物學】（身體的）局部，部位。3. （學問等的）范圍，領域。4. 〈罕用語〉天空。
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It is firstly found that for alloys in metastable region, with enhancement of atomic interaction energy, volume fraction and density of " phase particulate are increased, size and nucle ' ation rate of ordered phase raised, decline pace of composition in disordered matrix around the order phase is accelerated, composition order parameter and long range order parameter of ordered phase increased, i. e. process of clustering and ordering are accelerated
首次發現，隨著原子間相互作用勢的增加，亞穩區合金中有序相的體積分數和顆粒密度有所增加，有序相的尺寸和形核率有所提高，有序相周圍的無序基體濃度的降低有所加快，有序相內的成分序參數和長程序參數有所提高，即促進了原子簇聚過程和有序化程度。 -
By means of the calorimetric experimental results and the temperature dependence of heat capacity differences, four kinds of temperature dependences of configurational entropy, dielectric relaxation index and cooperatively rearranging region are studied, on the basis of configurational entropy theory on cooperatively rearranging region in disordered amorphous materials by the methods of the relationship between configurational entropy and heat capacity difference, and the equation of relaxation time with activated energy barriers
摘要基於無序非晶材料「關聯重排區域」的構型熵理論，運用構型熵與熱容量差的關系式、弛豫時間與活化勢壘的基本公式，及聚合物量熱學的實驗結果和熱容量差與溫度的基本關系，研究了4種情況下構型熵、介電弛豫指數和關聯重排區域大小的溫度變化關系。 -
Abstract : polyphenylacetylenes were synthesized by rn ( nbd ) cl 2 and wcl6 / ph4sn catalyst systems in n2 at room temperature. polymers with high yield and high molecular weight were obtained. their structures were characterized by uv, ir, nmr and gpc, respectively. the fluorescence of the polymer solution with different concentration was investigated using variable excitation wavelength from uv to visible region. the relation between fluorescence and polymer structure was studied. the results showed that the molecular chain structure has great influence on fluorescence of the polymers. the emitting peak wavelength of fluorescence for the polymer of high stereoregularity is independent of solution concentration and excitation wavelength. the emitting peak wavelength of fluorescence for the polymer with disordered molecular chain arrangement varies with changing the solution concentration and excitation wavelength, and different emission sites in molecular chains and low emitting yield are shown. the measurement and analysis of fluorescence spectroscopy of polyphenylacetylenes may provide some useful information to judge the molecular chain arrangement in some conjugated polymers
文摘:使用有機金屬銠、金屬鎢/四苯基錫催化劑體系聚合苯乙炔，分別獲得了高產率和高分子量的聚苯乙炔.使用uv ， ir ， nmr ， gpc等分別對聚合物結構進行了表徵.採用不同波長的激發光對聚合物熒光性能進行研究，詳細分析了聚合物結構與熒光性能之間的關系.研究結果發現，不同聚合物結構對聚合物熒光性能產生很大影響，規整性高的聚合物，將有較高的發光量子效率；聚合物規整性差，將可能導致多個熒光發光結構點，其熒光強度降低.聚合物熒光光譜研究將對某些共軛聚合物結構的規整性分析提供一些有用的信息
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