中子猝發 的英文怎麼說
中文拼音 [zhōngzicùfā]
中子猝發
英文
neutron burst-
The activation effect of zn2 + modification, including enhancement of emission intensity, slowing of luminescence decay and increasing of quantum yields, results from the formation of zns shell outside the nanoparticles, which is passivating the surface of nanoparticles, eliminating the surface quenching centers, so as to block the nonradiative transition pathways through these kind of quenching centers
Zn ~ ( 2 + )表面修飾在納米顆粒表面形成了zns殼層,鈍化了納米顆粒的表面,消除了表面猝滅中心,阻塞了通過表面猝滅中心進行無輻射躍遷的通道,從而使得發光強度增加,衰減變慢,量子效率提高。We have prepared a series of neodymium binary / ternary complexes, such as nd ( acac ) 3 ' 2h2o, nd ( tfa ) 3 ' 2h2o, nd ( hfa ) 3 ' 2h2o, nd ( dbm ) 3 ' h2o, nd ( acac ) 3phen, nd ( tfa ) 3phen, nd ( hfa ) 3phen, nd ( dbm ) 3phen, nd ( tta ) 3 ( tppo ) 2, nd ( hfa ) 3 ( tppo ) 2, nd ( acac ) 4hpy, nd ( tta ) 4hpy and ndq3. the effects of organic ligands, synergistic coordination agents and different substitution groups for - diketones on effective line width and photoluminescence intensity of neodymium complexes were investigated. the photoluminescence spectra indicate that synergistic coordination agents can shield neodymium ion and impede water molecules penetrating into inner coordination shell to satisfy large coordination number of nd3 + during hydrous synthesis process, so the luminescence intensity of neodymium ternary complexes is stronger than that of neodymium binary complexes
發光光譜研究表明,由於協同試劑的參與,屏蔽了水分子參與配位,降低了羥基( oh )對釹離子激發態能級~ 4f _ ( 3 2 )的猝滅,三元配合物的熒光強度均比二元配合物強,其中配合物nd ( tta ) _ 3 ( tppo ) _ 2在1340nm處的熒光強度最強,適合作為摻雜的光學活性物質,來制備有源光波導材料;在有水工藝條件下,單純地氟化配體未必能提高釹配合物的近紅外發光性能。The fluorescence spectra of the conjugationed polymer containing of n - ( a - naphthyl ) carbazole show that the emission sprctra in aromatic solvents are more red - shifted than that in aliphatic solvents although these solvents have the same polarity. the fluorescence chatacteristics were different from th e n - ( a - naphthyl ) carbazole ' s. the fluorescence of the conjugationed polymer can be quenched by electron donors and cm and cannot be quenched by electron acceptors
對含有n - ( -荼基)咔唑基團的共軛高聚物,它在芳香族溶劑中的熒光發射比非芳香族溶劑中明顯紅移,也不具有n - ( -萘基)咔唑單元所具有的分子內電荷轉移特性,它的熒光只能被電子給體和c _ ( 60 )猝滅而不能被一般的電子受體猝滅。These quenching centers can quench both blue emission related to the surface defects and the orange emission of mn2 + impurities. they are most likely originated from the dangling bonds of the lone pairs on surface s2 " or the zn2 + vacancies
這種表面猝滅中心對自激活藍光和橙光發射都有猝滅作用,它們極有可能來自表面s ~ ( 2 - )孤對電子的懸空鍵或zn ~ ( 2 + )空位。Based on the theoretical analysis and experimental researches, it is presented that the wider spectra are resulted from the many fluorophores with large numbers of vibrational energy levels on the ground level in the blood cells, and the reduction of the spectral intensity is due to the reabsorption of the blood cells and the energy transfer of the collisions between the fluorophore and another one or other macromolecule. on the other hand, when the concentration of the blood cells is increased, the reabsorption of the blood cells, the secondary fluorescence due to the reabsorption and the influence of the concentration on the energy levels of fluorophores are all the factors of the red - shifted spectral peaks
在進行理論分析和研究的基礎上,提出了因血細胞中存在多種熒光團,且這些熒光團的電子能級上又存在大量的不同的振動能級,從而導致被激發的熒光團發出較寬的熒光光譜;血細胞濃度的增大,熒光團以及其他大分子之間的距離變小,造成它們之間因碰撞的能量轉移概率加大,因而易產生熒光猝滅,結果導致熒光強度的變小;血細胞溶液中重吸收所導致的熒光猝滅和二次熒光發射,以及血細胞濃度的變化對其中熒光團能級系統的影響都是導致熒光峰值波長「紅移」的原因;進而研究了led光誘導血細胞產生熒光光譜的機理。Genetic research led by professor nelson tang leung - sang at the department of chemical pathology and professor patrick yuen man - pang at the department of paediatrics of the chinese university of hong kong has successfully identified a genetic disease which could cause sudden infant deaths. the finding was reported in a recent issue of a major genetic journal
香港中文大學化學病理學系鄧亮生教授聯同兒科學系阮文賓教授,最近發現引致卡尼丁缺乏癥的基因,而該癥可導致嬰兒猝死。此研究成果已在國際權威遺傳學期刊《人類分子遺傳學》 (We also have analyzed the photoluminescence ( pl ) spectra of some zno films, it turns out that the emission of ultraviolet light comes from the radiative recombination of excitons within nano - crystal energy band - gap, and the pl peaks move to smaller wavelength because zn are substituted by fe, co, and cu, which cause the size of the film grains smaller and the effective band - gap bigger. the red emission of zno films is due to, on the one hand, decrease of the film grains size which causes the emission intensity smaller and smaller until it disappears abruptly, on the other hand, the transition of electrons from deep donor level of the oxygen vacancies to the valence band
另外,我們還對薄膜光致發光性質進行了分析和研究,結果表明:納米結構zno薄膜的紫外發光來源於帶間激子的輻射復合發光, pl譜的帶邊發射峰發生藍移是由於fe 、 co 、 cu對zn的替代使薄膜粒子的尺寸減小,使薄膜的有效帶隙增寬; zno薄膜的紅色發光,一方面是zno顆粒尺寸的減少,帶間的激子發射峰越來越弱直至猝滅,另一方面主要是與zno晶格中的o空位有關,由深能級復合發光引起紅光發射。We consider that surface state act as quenching centers. with the irradiation, the surface state decreases and therefore luminescence of mn2 + increases. reduction of quenching centers is the result of chemical change by obtaining energy from zns excited by uv light
熒光增強的原因是由於zns基質向mn2 +離子和表面態的能量傳遞是兩個相互競爭的過程,紫外光輻照下表面猝滅中心數目不斷減少從而mn2 +離子的發光增強。分享友人