熱解液體產物 的英文怎麼說
中文拼音 [rèjiěyètǐchǎnwù]
熱解液體產物
英文
pyrolysis liquids-
In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術，有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應，提高了聚合物大分子鏈中有機硅鏈節的含量；利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵，並通過對共聚產物力學和吸水率的測試，證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能；從分子設計角度出發，利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體： ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷；利用核磁共振對新型硅烷單體結構進行了證實；研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液，且其聚合產物具有較高的力學及耐水性能。Inorganic salts, such as a1 ( no3 ) 3, zrocl2, ticl3, et al. was used as raw materials and corresponding hydroxides were deposited on the surface of graphite particle with heterogeneous nucleation process ; composite particles of graphite / oxides were obtained after heat treatment. in this paper, preparing conditions and properties of composite particles were studied
本論文以無機鹽（硝酸鋁、氧氯化鋯、三氯化鈦等）為原料，在石墨的稀懸浮液中應用非均勻成核技術，使水解產物（水合氧化物）沉積到微米級鱗片石墨表面，經洗滌、烘乾和熱處理制備出石墨氧化物復合粉體。This text completely and systematically studies the status and the development of the pyrolysis and the fluidization of biomass, which distill the bio - oil in the domestic and international area, as well as the existing problems. this thesis primarily include following aspects : ( l ), by experimenting and measuring the energy ( heat value ) and the content of c, h, n chemical element of right 20 kinds of common biomass, on the base of the experimental result, and respectively established the biomass energy predict experiment formula with the element of h and c is from change, and passed the ro. os examination, which provides the basis and convenience for flash pyrolysis fluidization device energy to convert the rate to compute with biomass energy utilization calculation ; ( 2 ), proceeded the tg and dtg experimentation equal velocity ( 10 ? / min, 20 ? / min, 40 ? / min, 60 ? / min ) heating and constant temperature heating by studying on eight kinds of biomass samples, according to the experimental data and arrhenius formula, we established the dynamics model of pyrolysis of, then, using the goast - redfern and p function, we also solved the dynamics parameters and analyze out every kind of biomass ' s frequency factor and parameters of activation energy, and established the every kind of dynamics model of pyrolysis of biomass, all of these provide the theories and basis to make sure the reactor ' s flash pyrolysis work temperature scope design and the describing of pyrolysis reactor dynamics ; ( 3 ), in order to study and ascertain the process of heat completely getting to pyrolysis time of varied size biomass particles, we observed and measured the ratio of length and diameter ( l / d ) with the varied biomass through electron microscope, we concluded the l / d ratios usually is from 5. 0 to 6. 0, the average is 5. 3 ; ( 4 ), we studied the process of biomass transiting and the theory of complete pyrolysis time with the theory of complicated heat field, we got the time ( t ) of the varied size biomass particles arriving to complete pyrolysis, and we knew that the complete pyrolysis time and the time which get to the biggest production ratio are identical, all of these studies provide the theory base for design and forecasting the flash pyrolysis reactor solid state resort time ; ( 5 ), according to the above experiment result, synthesize to make use of the engineering the mechanics, engineering the material, machine the design to learn the principle, deduce, establish the theory of rotation cone flash pyrolysis reactor material resort time ( t ) and reasonable rotation velocity ( or frequency ) relation theory ; and ( 6 ), we gave the reactor ' s smallest cone angle certain, reactor cone wall strength design theory, the reactor production ability theory, the power design method and the critical rotation velocity theory
本文較全面、系統地綜述了國內外生物質熱解液化制取生物燃油技術研究發展現狀及存在的問題，主要研究內容有： （ 1 ）實驗、測定了20種常見生物質的能量（發熱量）和c 、 h 、 n元素含量，根據實驗結果分別建立了以h和c為自變量的生物質能量預測經驗公式，並通過r _ （ 0 . 05 ）檢驗；為閃速熱解液化裝置能量轉化率計算和生物質能量利用率計算提供了依據和方便； （ 2 ）選擇了8種生物質試樣作了等加熱速率（ 10 min 、 20 min 、 40 min 、 60 min ）和恆溫加熱的tg和dtg實驗，根據實驗數據和阿倫尼烏斯公式建立了生物質熱解反應動力學微分方程，並採用goast - redfem積分法和p函數對其動力學參數進行了求解，解析出各種生物質的頻率因子和活化能參數，進而建立了各種生物質的熱解動力學模型，為科學確定反應器的閃速熱解工作溫度范圍及熱解反應動力學描述，提供了理論和依據； （ 3 ）為研究和確定不同尺度的生物質顆粒中心達到全熱解的時間，在體視顯微鏡下對不同粒度的生物質顆粒的長徑比進行了實驗觀察和測定，得出生物質的長徑比（ l d ）一般在5 . 0 6 . 0之間，平均為5 . 3的結果； （ 4 ）採用復雜溫度場傳熱學理論對生物質傳熱過程及充分熱解時間理論進行了研究，解析推導出了不同尺寸生物質顆粒中心溫度達到充分熱解溫度的時間（ t ） ，得出了理論推導的充分熱解時間與最大產油率的熱解時間相一致的結果，為閃速熱解反應器固相滯留時間設計和預測提供了理論依據； （ 5 ）根據上述實驗結果，綜合運用工程力學、工程材料、機械設計學原理，推導、建立了轉錐式閃速熱解反應器物料滯留時間（ ）與轉速（或頻率）合理匹配理論； （ 6 ）提出了轉錐式閃速熱解反應器的最小錐角設計、錐壁強度設計、生產能力設計理論和功率計算方法及臨界轉速理論等。This part emphasizes the synthesis of nanoarrays, aiming at controlling the size and distance of nanocrystallites using calixarene derivatives by altering the size, length and chemical structure of the organic molecules ; 2. this part emphasizes in situ synthesis strategy for fabrication of polymer network of zns based nanopowder, aiming at size controls, coating and preventing agglomeration following " one - pot " synthesis ; this method fits to low cost, large scale production ; 3. according to development in zno nanomaterials, we first report on the synthesis, characterization of amorphous zno, aiming at describing the principles and approaches of synthesis techniques, optical properties, spatial structure and doped effect ; the amorphous zno displays cage - like structure, showing a strong ultraviolet emission while the visible emission is nearly fully quenched, a potential uv - emission material ; 4
本論文以量子結構自組裝為出發點，提出利用杯芳烴及其衍生物的化學受限反應實現尺寸可調半導體納米粒子自組裝；提出有機聚合網路原位組裝zns基納米熒光粉方法，把熒光粉的納米化、包敷、防團聚在「一鍋」反應中完成，適于低成本，批量生產；根據當前zno的研究情況，我們首次合成了非晶zno ，研究了它的光學性質，確定了它的結構，並對其摻雜進行了初步的研究，非晶zno表現出強的深紫外發光特性，而可見發射非常弱，是一種有巨大潛在應用價值的深紫外發光材料；利用非晶zno的亞穩特性，對晶化過程中非晶zno納米晶zno三維受限量子結構特性，界面特性進行了深入的研究；利用固相熱分解一般受擴散控制特性，實現了尺寸可控的zno三維量子結構的自組裝；利用非晶zno的高度分散性，容易均勻成膜特性，實現了非晶籽晶誘導低溫液相外延自組裝生長高取向zno晶體薄膜。分享友人