硅氧聚合體 的英文怎麼說
中文拼音 [guīyǎngjùgětǐ]
硅氧聚合體
英文
dimethicone copolyol-
In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術，有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應，提高了聚合物大分子鏈中有機硅鏈節的含量；利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵，並通過對共聚產物力學和吸水率的測試，證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能；從分子設計角度出發，利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體： ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷；利用核磁共振對新型硅烷單體結構進行了證實；研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液，且其聚合產物具有較高的力學及耐水性能。The two constituents were compatibilized in - situ by mechanochemical reactions induced by pan - milling and the microstructure of the blend can be controlled conveniently by adjusting processing conditions. polyamide 6 / ground limestone powder ( pa6 / caco3 ) and polyamide 6 / silicon dioxide ( pa6 / sio2 ) composites were also prepared through this method. those pa6 blends and composites exhibit improved microstructure and superior mechanical properties to the systems mixed by conventional mixing methods
研究了磨盤碾磨對尼龍6的粉碎機理，制備了就地增容、微相結構可調的聚丙烯/尼龍6 （ pp / pa6 ）及尼龍6 /碳酸鈣（ pa6 / caco _ 3 ） 、尼龍6 /納米級二氧化硅（ pa6 / nano - sio _ 2 ）共混復合材料，各體系混合效果、微相結構及力學性能均明顯優于採用傳統混合設備制備的試樣。And the value drop to the lowest at ph = 0. 8. as the increase of heat treatment temperature, the pore size distribution peak of sio2 microspheres is very narrow, meanwhile the specific surface area is the smallest before 160 c. the polymer template is removed at 350 c, so the pore structure of sio2 particles has a big change which involve the increase of specific surface area and the broaden of pore size distribution peak. with the continuous raise of temperature the sio2 network will shrink little, as a result the average pore size will decrease, but the specific surface area has no obvious change
結果發現：二氧化硅膠體顆粒均勻分佈於脲醛聚合物網路中，煅燒去除有機模板后微球表面變粗糙，而粒徑沒有明顯變化； ph值較小時，復合微球中聚合物含量較大，而ph值較大時，得到復合微球結構鬆散，因此熱處理后的二氧化硅微球孔容及平均孔徑都較大，而在ph = 0 . 8時，得到最小值；武漢理工大學碩士學位論文隨著熱處理溫度的變化，小於160時，空分佈較窄，而比表面積較小，在350時，由於有機模板的去除，微球孔結構發生突變，比表面積明顯增大，而孔徑分佈變寬，溫度繼續升高時，二氧化硅網路發生收縮，平均孔徑變小而比表面積由於有機炭化物的完全去除沒有太大變化;微球中的微孔在熱處理過程中處于平衡狀態，分佈沒有太大變化。Moa is kind of necessary over - voltage protector for safety running in electrical power system, it ' s used for prevent the equipment against the damage of atmosphere and operating over - voltage without gaps is belong to the third dynasty product, it ' s recognized as the up - to - data over - voltage protector, this kind of product is made up of zinc oxide films and polymer housing for example sr, epdm, hdpe it has features of small volume, simple structure, light height, pololution - prool and non - detonation and is suitable to be usde in the densely populated city
避雷器是電力系統安全運行不可缺少的過電壓保護產品，用以保護電器設備免遭大氧過電壓和操作過電壓的損害，而復合外套無間隙氧化鋅避雷器是屬于避雷器第三產品，是當今各項性能最好的產品，其核心元件電阻片全部採用氧化鋅閥片，而外殼材料是採用復合有機材料，如硅橡膠（ sr ） ，改性三元乙丙橡膠（ epdm ）高密度聚乙烯（ hdpe ）等，它具有體積小，結構簡單，重量輕，耐污積強，防爆等優點，最適合人口密度城市中使用。Two kind of ordered macroporous polymethylmetacrylate structures with different pore morphologies were fabricated from colloidal templates of the same silica microspheres, which was assembled by using centrifugation as driving force
摘要以離心沉降技術組裝的二氧化硅膠體晶體為模板，從同種尺寸的二氧化硅微球出發，合成了孔的結構和形貌不同的兩種有序大孔聚甲基丙烯酸甲酯。The resulted films were densely packed uniform amorphous films with substantial overlap between adjacent si02 layers, and can serve the function as antireflection coatings. colloidal ti02 particles of 3 ~ 4nm in diameter were prepared using tetra - h - butyl titauate as precursor, and composite multilayer films of pss / tio2 were electrostatically self - assembled
二氧化硅膠體與聚合物pdda的自組裝多層復合薄膜為均勻、緻密的非晶態膜，復合薄膜內存在層間穿插的現象，薄膜表現出均質單層光學塗層的特性並具有增透作用。Soap - free polymerization method means monomers ( mma ) polymerize around the surface of nano - silica without soup, absorbed by the force of surface. by the means of tem and potential test, the improvement of dispersal of nano - silica has been proved : particle size of aggregates decreased from 120 - 200nm to 80nm
無皂乳液聚合法是在無乳化劑存在的環境中，利用納米二氧化硅表面的吸附力，單體（ mma ）在其表面進行聚合，包裹納米二氧化硅表面，改善界面狀況。Silylate - terminated polyurethanes with built - in hydrophilic sites were synthesized. when the polymer is dispersed in water, the silane alkoxy end - groups of the polymer undergo hydrolysis, followed by condensation to form a stable cross - linked aqueous dispersion. tem studies indicated that with more incorporation of hydrophilic sites, the particle size of the dispersion decreased. it was also found that the film property depended on the particle size when the crosslinking density in particels was much higher. the average molecular weight of the elastically effective network chain mc measured by swelling experiments shows fairly good agreement with the theoretical value of mc. it was also found that the cross - linking density of the casting film may increase during the film formation and drying process
將硅氧烷封端的含親水基團的線性聚氨酯預聚體分散於水中，獲得穩定的聚氨酯分散體.由於硅氧基團水解、縮合，在分散體粒子內產生擴鏈交聯反應，生成了交聯水基聚氨酯分散體.透射電子顯微鏡研究表明分散體粒徑小、分佈寬.掃描電子顯微鏡研究了成膜結構及成膜性能與粒徑的關系.溶脹實驗計算獲得的兩交聯點之間的平均分子量與理論平均分子量相符.研究還發現此分散體膜在乾燥過程中可進一步交聯.膜的水溶脹及機械性能表明，此分散體具有極大的工業應用價值Silicon dioxide spherical particles are widely used in many fields of advanced technology, such as photonic crystals, catalyst supports, chromatographic packing materials and standard materials in measurement etc. in this article, micrometer sio2 spherical particles were synthesized by polymerization - induced colloid aggregation process
由於二氧化硅球形顆粒在光子晶體、催化劑載體、色譜填料、標準計量等許多高新技術領域有著非常廣泛的應用前景。本文用聚合誘導膠體團聚法制備介孔二氧化硅球形顆粒，並對其形成機理及制備條件進行了詳細研究。分享友人