硅氧聚合體烷 的英文怎麼說
中文拼音 [guīyǎngjùgětǐwán]
硅氧聚合體烷
英文
dimethicone copolyol- 硅 : 名詞[化學] silicon (14號元素符號 si)
- 氧 : 名詞[化學] (氣體元素) oxygen (o)
- 聚 : 動詞(聚集; 聚積) assemble; gather; get together
- 合 : 合量詞(容量單位) ge, a unit of dry measure for grain (=1 decilitre)
- 體 : 體構詞成分。
- 烷 : 名詞[化學] (有機化合物的一類) alkane
- 聚合體 : aggregate
- 聚合 : 1 (聚集到一起) get together2 [化學] (單體結合成高分子化合物) polymerization; polymerize 3 [生...
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In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術,有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應,提高了聚合物大分子鏈中有機硅鏈節的含量;利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵,並通過對共聚產物力學和吸水率的測試,證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能;從分子設計角度出發,利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體: ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷;利用核磁共振對新型硅烷單體結構進行了證實;研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液,且其聚合產物具有較高的力學及耐水性能。Silylate - terminated polyurethanes with built - in hydrophilic sites were synthesized. when the polymer is dispersed in water, the silane alkoxy end - groups of the polymer undergo hydrolysis, followed by condensation to form a stable cross - linked aqueous dispersion. tem studies indicated that with more incorporation of hydrophilic sites, the particle size of the dispersion decreased. it was also found that the film property depended on the particle size when the crosslinking density in particels was much higher. the average molecular weight of the elastically effective network chain mc measured by swelling experiments shows fairly good agreement with the theoretical value of mc. it was also found that the cross - linking density of the casting film may increase during the film formation and drying process
將硅氧烷封端的含親水基團的線性聚氨酯預聚體分散於水中,獲得穩定的聚氨酯分散體.由於硅氧基團水解、縮合,在分散體粒子內產生擴鏈交聯反應,生成了交聯水基聚氨酯分散體.透射電子顯微鏡研究表明分散體粒徑小、分佈寬.掃描電子顯微鏡研究了成膜結構及成膜性能與粒徑的關系.溶脹實驗計算獲得的兩交聯點之間的平均分子量與理論平均分子量相符.研究還發現此分散體膜在乾燥過程中可進一步交聯.膜的水溶脹及機械性能表明,此分散體具有極大的工業應用價值
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