膽甾醇結晶 的英文怎麼說
中文拼音 [dǎnzāichúnjiējīng]
膽甾醇結晶
英文
cholestero crystal- 膽 : 名詞1 [解剖學] （膽囊） gallbladder2 （膽量） courage; guts; bravery 3 （裝在器物內部 可容納水、...
- 甾 : 名詞[化學] （有機化合物的一類） steroid
- 醇 : Ⅰ名詞1 [書面語] （含酒精多的酒） mellow wine; good wine2 [化學] （有機化合物的一大類 含羥基的烴化...
- 結 : 結動詞（長出果實或種子） bear （fruit）; form （seed）
- 晶 : Ⅰ形容詞（光亮） brilliant; glittering Ⅱ名詞1. （水晶） quartz; （rock） crystal 2. （晶體） any crystalline substance
- 結晶 : 1 （析出晶體） crystallize2 （晶體） crystal 3 （成果） crystallization; fruit; product; quintess...
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A super acylation catalyst, 4 - dimethylamino pyridine ( dmap ), was prepared and used to synthesize cholesteryl ester compounds. four kinds of cholesteryl ester compounds such as cholesteryl p - alkoxyl benzoate, cholesteryl dicarboxylate, cholesteryl lumequeic ester and coattail - like cholesteryl ester were synthesized by acylation method and super acylation catalyst method. chemical structures and liquid crystal behaviors of the synthesized samples have been characterized by using element analysis, ftir, dsc and polarized microscopy with a hot stage
本文合成了高效酰化催化劑4 -二甲基氨基吡啶（ 4 - dimethylaminopyridine ， dmap ） ，採用酰氯化法和高效酰化催化劑法分別合成了對烷氧基苯甲酸膽甾醇酯、對稱脂族二羧酸膽甾醇酯、烯酸膽甾醇酯及燕尾型膽甾醇酯四類膽甾醇酯衍生物，並進行了化學結構和液晶性能的表徵。Phenyl group introducing to cholesteryl ester molecules can enhance the phase transition temperatures of the liquid crystals and their stability. an increase in the chain length for cholesteryl dicarboxylate samples reduced stability of liquid crystal phases. while coattail - like structures on the ester group of the molecules have an adverse effect to form cholesteryl liquid crystal phase
化學結構對液晶性的影響表現為：分子中引入苯環剛性結構可以提高液晶的相變溫度和穩定性；脂族二羧酸膽甾醇酯中脂肪鏈的長度增加會降低液晶的穩定性；而末端含有燕尾結構則對液晶態的形成產生不利影響。The research results showed that the dmap is an effective catalyst to synthesize cholesteryl ester compounds. in the reactions, improving yield and purity, reducing toxicity as well as simplifying operation process can be carried out
研究結果表明，高效酰化催化劑法是十分有效的酰化方法，在合成膽甾醇酯液晶中可較大幅度地提高產品的產率與純度、簡化操作、降低反應毒性。
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