烯丙基聚合 的英文怎麼說
中文拼音 [xībǐngjījùgě]
烯丙基聚合
英文
allylic polymerization- 烯 : 名詞[化學] (有機化合物的一類) alkene; olefince
- 丙 : Ⅰ名詞1. (天乾的第三位) the third of the ten heavenly stems2. (姓氏) a surname Ⅱ數詞(第三) third
- 聚 : 動詞(聚集; 聚積) assemble; gather; get together
- 合 : 合量詞(容量單位) ge, a unit of dry measure for grain (=1 decilitre)
- 聚合 : 1 (聚集到一起) get together2 [化學] (單體結合成高分子化合物) polymerization; polymerize 3 [生...
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The results suggested that the ph value, the type of monomers, the type, concentration and surface properties of inorganic nanoparticles, the type and concentration of emulsifier have a great influence on the encapsulating emulsion polymerization and the obtained latex stability. if selecting cationic emulsifier ( ctab ), low water soluble monomers ( such as ba, st ) and hydrophobic nano - silica, the inorganic nanoparticles would be encapsulated by polymers through ultrasonic irradiation successfully under alkalescent condition
系統研究了ba 、甲基丙烯酸甲酯( mmal苯乙烯舊t )以及它們的共聚體系在超聲輻照作用下包裹聚合的主要影響因素,結果表明: ph值、單體的種類、無機納米粒子的種類、濃度及表面性能、乳化劑的種類及濃度等對超聲輻照包裹乳液聚合以及復合體系的穩定性有較大的影響。Microemulsion polymerization of methyl butyl - acrylate
甲基丙烯酸丁酯微乳液聚合The obtained polysilane - polyacrylate gradient films showed no macro - interface with the silicone content reducing gradually from the top surface to the bottom one. dma thermograms indicated that polysilane - polyacrylate gradient films contained two glass temperatures with their bands drifting from and their range extending much from each component. the good properties of waterproof, calorifics, and ultraviolet - absorption were also determined by dsc, uv and water contact angle measurements
結果表明:有機硅聚合物-聚丙烯酸酯梯度膜有一個較寬的玻璃化轉變溫區,玻璃化轉變范圍相對組分材料的玻璃化轉變范圍發生了擴展:有機硅聚合物-聚甲基丙烯酸酯梯度膜具有較好的熱學性能;硅含量的提高有利於改善膜層的憎水性能和紫外吸收性能。First, a terminal double bond was introduced into 3 - amino - 9 - ethylcarbazole ( aec ) via methacryloyl chloride to obtain the compound, 3 - ( n - methacryloyl ) amino - 9 - ethylcarbazole ( mec ). second, mec was copolymerized with butyl methacrylate to prepare the mec - immobilized polymer particles. the resultant polymer particles were used as a fluorescence probe, which was almost free of dye leaching, and had higher photostability in comparison with free aec
首先利用甲基丙烯酰氯向3 -氨基- 9 -乙基咔唑( aec )分子中引入末端雙鍵,得到帶末端雙鍵的熒光指示劑3 - ( n -甲基丙烯酰基)氨基- 9 -乙基咔唑( mec ) ,然後通過乳液聚合技術將mec共價固定到聚甲基丙烯酸丁酯基體上,制得一種共價固定了mec的聚合物顆粒。In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術,有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應,提高了聚合物大分子鏈中有機硅鏈節的含量;利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵,並通過對共聚產物力學和吸水率的測試,證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能;從分子設計角度出發,利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體: ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷;利用核磁共振對新型硅烷單體結構進行了證實;研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液,且其聚合產物具有較高的力學及耐水性能。Properties of poly n - butyl methacrylate prepared by reverse atom transfer radical polymerization in aqueous dispersed system
乳液聚合法合成聚甲基丙烯酸丁酯的性能研究Three water - soluble acrylic resins are prepa red by polymerizing esters acrylate, acrylic acid , methylacrylic acid , esters methylacrylate with phenyl - ethene or ethylene acetate in present of water or alcohol and initiating agent. properties of the acrylic resins are characterized. results show that the resins possess excellent character, i. e. adhibity, water - solubility, expansion after dry for water , anti acidity or bascity and brightness in the products of same type
以丙烯酸、丙烯酸酯、甲基丙烯酸、甲基丙烯酸酯等作為基料,在引發劑的存在下,以水或醇作溶劑進行聚合,加入苯乙烯、醋酸乙烯等改性,合成了3種不同的水溶性丙烯酸改性樹脂,並對其性能進行了測定.結果表明:這3種樹脂的粘度、水溶解性、乾燥后膜的吸脹性、抗酸堿性、光亮度等性能均優于同類產品( 2 ) an aminobenthiazole schiff base has been synthesized as a new fluorescence carrier by reacting 2 - aminobenthiazole with p - allyoxybenzoldohyde. the new kind of schiff base can be utilized for preparing an optical sensor, used for determining furazolidone based on the fluorescence quenching. aminobenthiazole schiff base immobilized on a glass plate surface by covalent bonding can circumvent the leakage of the fluorephore from the sensor surface and guarantee a relatively long working lifetime
( 3 )用強熒光基團2 -氨基苯並蒽酮與對烯丙氧基苯甲醛合成了另一種新的schiff堿類化合物,與甲基丙烯酸羥乙酯、丙烯酰胺、環乙二醇二丙烯酸酯共聚制得光極膜,制備了一種苯並蒽酮schiff堿光化學傳感器,可用於單質碘的測定。In this paper, pan based metal gradient composites films ( pmgcf ) were prepared by electrochemical reduction. the effect of polymer matrix on pmgcf and preparation and its forming mechanism of pmgcf were invested, they are as follows : lacrylonitrile - methyl - methacrylate copolymer, acryonitrile - itaconic acid copolymer, acrylonitrile - methyl methacry late - sodium allyl sulfonate terpolymer have been synthesized seperately in order to analyze the effects of the mma monomer unites and the hydrophilic unites of acryonitrile terpolymer on the process of copper deposition in polyacrylonitrile - based metal gradient composite film ( pmgcf ) as well as the flexibility of the film
其內容如下: 1通過合成的丙烯腈?甲基丙烯酸甲酯二元共聚物( p ( an - mma ) ) ,丙烯腈?亞甲基丁二酸二元共聚物( p ( an - ita ) ) ,丙烯腈-甲基丙烯酸甲酯?丙烯磺酸鈉三元共聚物( p ( an - mma - as ) )分別作為基體制備了聚合物基金屬梯度復合膜材料( pmgcf ) ,以分析加入的mma基團和親水性基團對pmgcf沉積層中金屬銅的梯度分佈形態和膜的柔韌性的影響。Poly ( methacrylic acid ) ( maa ) and poly ( acrylic acid ) ( aa ) microgels have been prepared as templates by employing inverse emulsion polymerization techniques. four types of spherical organic - inorganic nano - composites have been prepared by introduction of precipitation agent into the pmaa / paa microgels containing appropriate rate metal ions
本課題開展了兩個模板體系的研究,即分別以丙烯酸( aa )和甲基丙烯酸( maa )為聚合單體,利用反相乳液聚合方法合成了幾種包埋有不同金屬離子的高分子微凝膠。For the first time, agbr organosol was obtained by using oleic acid to extract and modify the agbr nanoparticles in hydrosol. and the optimum molar ratio of oleic acid to agbr nanoparticles was found. agbr nanoparticles, modified by oleic acid were mixed with mma
首次採用油酸萃取並包覆了水溶膠中的agbr納米粒子,制備了agbr有機溶膠;並找到了萃取率最佳時的油酸與agbr的摩爾比;再將油酸包覆的agbr摻雜到甲基丙烯酸甲酯中,進行本體聚合,從而制備了agbr光致變色有機玻璃。Studies on the synthesis of grafted copolymer polyol with dimethyl ally phosphite onto unsaturated flame retardant polyether polyol
不飽和阻燃聚醚多元醇接枝烯丙基膦酸二甲酯共聚物的合成研究Ir, sem - edx, and water contact angle measurements on polysilane and polyacrylate film obtained by double operations and single operation showed that the influence of weight ratio of polymers, the molecular of pmma on film structure was great. the film translucence dropping while the ratio of pmma / pmts grew and the compatible reducing while the molecular of pmma increased
通過測定所配製的系列濃度聚合物甲苯溶液、 thf溶液的表面張力發現:有機硅聚合物溶液的表面張力值在有機硅聚合物濃度低於30時變化不明顯;而甲基丙烯酸酯聚合物溶液表面張力值隨甲基丙烯酸酯聚合物濃度的變化比有機硅聚合物溶液明顯。( 1 ) in chapter 1, renewable amperometric immunosensor based on sol - gel technique has been developed by dispersing graphite, complement 3 antiserum and sol - gel at low temperature for the determination of complement 3 in human serum
同時還研究了1 - o -烯丙基- 4 -羥基蒽醌的電化學行為以及2 -氨基吡啶聚合膜修飾玻碳電極的制備及其電化學性質。The prepn. of dimethyldiallylammonium chloride monomer and the related polymers was summarized, and the use of the derivatives in text, dyeing and printing as antistatic, color fixing and flocculating agents were presented
摘要簡述了二甲基二烯丙基氯化銨單體及其相關聚合物的制備方法,介紹了聚二甲基二烯丙基氯化銨及其衍生物產品在紡織印染行業中作為抗靜電劑、固色劑和絮凝劑的應用。Furthermore, its response changed little even after the sensor was soaked in water for 30 min. four kinds of multi - layers nanocomposite humidity sensitive films, including sodium polystyrenesulfonate / poly ( diallyldimethylammonium chloride ) ( napss / pdda ), sodium polystyrenesulfonate / poly4 - vinylpyridine quaternized with butyl bromide ( nbubr - p4vp ), sodium polysryrenesulfonate / zinc oxide ( napss / zno ) and sodium poly ( acrylic acid ) / zinc oxide ( paana / zno ), have been prepared by means of self - assembly
用靜電吸引自組裝法制備了聚苯乙烯磺酸鈉( napss )聚二烯丙基二甲基氯化銨( pdda ) 、 napss溴代正丁烷季胺化聚4 -乙烯吡啶( nbubrp4vp ) 、聚苯乙浙江大學碩士學位論文摘要烯磷酸鈉則apss們化鋅面ox聚丙烯酸鈉p句zno四個體系的自組裝納米復合濕敏膜及濕敏元件。Polymer networks have been produced in a variety of liquid crystal phases in cells without surface treatment. the liquid crystal / monomer mixtures are prepared using a ferroelectric liquid crystal and a diacrylate monomer. the polymerisation of the monomer is carried out by uv curing the mixture when it was kept in a specific phase which can be obtained by controlling the temperature of the ferroelectric liquid crystal. both the monomer and the polymer network will depress phase transition temperatures. the effects of the polymer network on the packing arrangement of the ferroelectric liquid crystal molecules are examined by means of optical microscopy. the molecular packing arrangement of the ferroelectric liquid crystal in a specific mesogenic phase is frozen on the formation of a polymer network in the ferroelectric liquid crystal in that phase. the existence of the diacrylate based polymer network can improve the electrooptical switching of the ferroelectric liquid crystal
在灌裝于未經表面處理的樣品盒內處于不同狀態的液晶中制備聚合體網路.液晶/單體混合物由鐵電液晶和雙丙烯酸單體製成.單體的聚合通過維持該混合物處在一定的液晶態的條件下經紫外線固化來完成.不同的液晶態可通過控制鐵電液晶的溫度來獲得.雙丙烯酸單體或聚合體網路的存在會導致鐵電液晶載體的相變溫度降低.通過光學顯微鏡可觀察聚合體網路對鐵電液晶分子組合排列的影響.結果發現:在某一液晶態中鐵電液晶分子的組合排列可被在該液晶態中聚合而成的聚合體網路所穩定,雙丙烯酸基聚合體網路的存在可改良鐵電液晶的電光開關特性Then, surface tension measurements on various solution of pmma, pmts, mts - mma copolymer indicated that the change of polysilane ' s surface tension was not significant when its concentration was lower than 30 %, while that of polyacrylate ' s varied much more significant yet
隨之,用溶液聚合法制備了具有不同分子量及分子量分佈的有機硅聚合物、有機硅-丙烯酸酯共聚物( mts - 35 、 mts - 65 )和甲基丙烯酸酯聚合物。Catalytic synthesis of diallyl - polyethylene glycol by quaternaryammonium salt
季銨鹽催化合成二烯丙基聚乙二醇的研究Study on property of turbidity removal of pdmdaac flocculant series
二甲基二烯丙基氯化銨聚合物的除濁性能研究分享友人