熱原子化學 的英文怎麼說
中文拼音 [rèyuánzihuàxué]
熱原子化學
英文
hot atom chemistry-
As addenda, a tennis and fives court, a shrubbery, a glass summerhouse with tropical palms, equipped in the best botanical manner a rockery with waterspray, a beehive arranged on humane principles, oval flowerbeds in rectangular grassplots set with eccentric ellipses of scarlet and chrome tulips, blue scillas, crocuses, polyanthus, sweet william, sweat pea, lily of the valley bulbs obtainable from sir james w. mackey limited wholesale and retail seed and bulb merchant and nurseryman, agent for chemical manures, 23 sackville street, upper, an orchard, kitchen garden and vinery, protected against illegal trespassers by glasstopped mural enclosures, a lumbershed with padlock for various inventoried implements
可以增添一個網球兼手球場，一片灌木叢，用植物學上最佳辦法設置一座熱帶椰子科植物的玻璃涼亭，有噴泉裝置的假山石，按照人道的原則設計的蜂窩。在矩形的草坪上布置一座座橢圓形花壇，將深紅和淡黃兩色的鬱金香藍色的天蒜報春花西櫻草美洲石竹香豌豆花和歐鈐蘭都栽培成別致的卵形球根購自詹姆斯w馬凱伊爵士247的股份有限公司，他是個種籽與球根批發兼零售商，苗木培養工，化學肥料代理商，住在上薩克維爾街二十三號。果樹園蔬菜園和葡萄園各一座。Surface states and the topmost surface atoms of the batio3 thin films have been analyzed by x - ray photoelectron spectroscopy ( xps ) and angle - resolved x - ray photoelectron spectroscopy ( arxps ). the results show that the as - grown batio3 thin films have an enriched - bao nonstoichiometric surface layer which can be removed by ar + ion sputtering, and the atomic ratio of ba to ti decreases with increasing the depth of ar + ion sputtering
用x射線光電子能譜技術（ xps ）和角分辨x射線光電子能譜技術（ arxps ）研究了薄膜的表面化學態以及最頂層原子種類和分佈狀況，結果顯示在熱處理過程中薄膜表面形成一層富含bao的非計量鈦氧化物層，並且鋇-鈦原子濃度比隨著探測深度的增大而逐漸減小。Al - doped zno thin films are emerging as an alternative potential candidate for ito flims recently. al doped zno thin films also can obtain a tunable band gap. especially, zno : al thin films with high c - axis orientated crystalline structure along ( 002 ) plane are potential device applications in broadband ultra - violet
Al摻雜的zno薄膜不僅具有與傳統ito薄膜相比擬的光電性質，而且原材料豐富、價格低、無毒、沉積溫度低、熱穩定性高，在氫等離子體環境中具有很高的化學穩定性，不易導致太陽能電池材料活性降低。Because of the extensive applications of condensed matter in various fields, the investigations on the equation of state of compressed solids are not only necessary in many basic sciences and interdisciplinary areas, e. g. geophysics, planetary science, astrophysics, physics of condensed matter, atomic and molecular physics, thermodynamics, statistical physics, material science etc., but also of important utilized values in the explosive mechanics, energy engineering, aviation technicality and so on applied sciences
由於固體材料在實際生活、生產中具有的廣泛應用性，這就決定了對固體材料物態方程的研究不僅在熱力學、統計物理學、凝聚態物理、原子與分子物理、地球物理、天體物理、化學物理等基礎學科中是不可缺少的，而且在材料科學、能源工程、爆炸力學、武器物理、宇航技術等應用學科中也具有重要的應用價值。Chemists have been using the laws of the atom and of heat transfer to deal with the reactions they study.
化學家們一直在利用原子和熱傳遞等定律來論述他們所研究的化學反應。According to the law of mass action, the law of mass conservation and the principles of chemical thermodynamics, mathematics model about components " modes of occurrence ( that is simple ions, complex anions and complex compounds ) and their concentration in dam foundation solution has been set up with balance constant method
本文根據質量作用定律、質量守恆定律和化學熱力學的基本原理，應用平衡常數法建立了地下水水質組份存在形式（即單一離子、絡陰離子和絡合物）及其濃度分佈的數學模型。Our first organic - synthesis experiments in 1996, and much more extensive research by thomas mccollom of the woods hole oceanographic institution, demonstrate that f - t reactions can build molecules with 30 or more carbon atoms under some hydrothermal - vent conditions in less than a day
1996年我們完成第一個有機合成實驗，加上伍茲赫爾海洋研究所的麥科洛姆所作的廣泛研究，兩者都顯示，在某種深海熱泉情境中，相關化學反應在一天之內就可合成含30個碳原子以上的長鏈分子。Microstructure of the composite layer was analyzed with help of optical microscope, scanning electronic microscope ( sem ), electronic probe microanalysis ( epma ) and x - ray diffraction ( xrd ). the compacting of the billet and the forming mechanism of the carbide reinforcement were studied based on thermodynamics and kinetics of reaction, sintering theory and the result of dta. at the same time, the wear - resistance of the composite layer was studied under condition of dry sliding friction
利用光學顯微鏡、掃描電子顯微鏡、電子探針以及x -射線衍射儀，分析了表面復合層的基體組織結構；運用反應熱力學、動力學、粉末燒結理論和燃燒合成理論，結合差熱分析結果，探討了表面復合層壓坯的燒結緻密化原理和碳化物增強相的形成機理；利用坯塊在真空燒結爐不同溫度下的燒結出來的顯微組織分析，模擬出坯塊的燒結過程中的化學反應過程。The dynamics equations of soil water vaporizing and ammonia volatilizing hcluding the factors of water and temperature, and the dynamics - like equation of urea transforming into ammonium nitrogen in soil are founded in the paper, by taking the effect of interaction of water and temperature as subject, the dynamic change character of object studied as basis and using principle of chemical dynamic ; the empirio - equations of soil water retention curve including temperature and the empirio - equations including temperature between water potential of millet seedling leaves and soil water are founded in order to make the equation of relation between water potential and water content in soil suit the demand of temperature change much better
本文以水熱耦合效應為主題，基於研究對象的動態變化特徵，應用化學動力學原理，建立了含水、熱因子以及水熱耦合效應的土壤水分蒸發、肥料氨揮發動力學方程，以及施入土壤中的尿素轉化為銨態氮的動力學型方程；為使水勢?含水量關系式更好適應變溫條件應用的要求，建立了含溫度因子直接表徵土壤持水曲線的經驗方程，以及含溫度因子的穀苗葉水勢與土壤含水量關系經驗方程。At same time macroscopical and microcosmic mathematical model of nitridation are investigated. in this paper the thermodynamics of direct - nitridation, effect of temperature and nitrogen ambience on nitridaton and self - diffusion are discussed in the theory of physical chemistry in detail
同時本文用物理化學的原理討論了矽片氮氣直接氮化的熱力學方程、氮化條件的理論根據和原子的自擴散，從理論上證明隨溫度升高氮化加劇，氣氛純度越高氮化越容易的結論。How to obtain the useful biochdrical informaton on this scale is the new tren in the research fie1d of analytical chehascy therefore, single molecule detection, sing1e cell detection, dna ~ and the shaple dna analysis were one of the main research direeons ofanalytcal chendscy nove1 molecular probe and ultrasmali biosensor for real tiine and in vivo detection has been the focuses in the research field of analytical chendstry according to the above mentioned advanced direetions, two pnd of inveshgations has been pdrirmed in thes thesis
人們對生命現象的觀察和研究已經深入到納米尺度和單細胞，單分子的水平，如何在這樣一個尺度范圍內獲取有用的生物化學信息對分析化學的各個研究領域均提出了新的要求。單分子、單細胞檢測、生物晶元的開發以及納米技術的應用漸漸成為現代分析化學研究的主流領域之一。可進行實時、在線、原位、活體檢測的分子探針和超微型生物傳感器成為人們研究的熱點和重點。As miniaturization brings closer the day when each atom will store one bit of information for us, the useful shannon entropy of the state - of - the - art microchip will edge closer in magnitude to its material ' s thermodynamic entropy
隨著微型化的快速進展，一個原子能夠儲存一個位元資訊的日子也越來越近；對于最新穎的微晶片來說，有用的夏儂熵將會逐漸逼近晶片材料的熱力學熵。This text completely and systematically studies the status and the development of the pyrolysis and the fluidization of biomass, which distill the bio - oil in the domestic and international area, as well as the existing problems. this thesis primarily include following aspects : ( l ), by experimenting and measuring the energy ( heat value ) and the content of c, h, n chemical element of right 20 kinds of common biomass, on the base of the experimental result, and respectively established the biomass energy predict experiment formula with the element of h and c is from change, and passed the ro. os examination, which provides the basis and convenience for flash pyrolysis fluidization device energy to convert the rate to compute with biomass energy utilization calculation ; ( 2 ), proceeded the tg and dtg experimentation equal velocity ( 10 ? / min, 20 ? / min, 40 ? / min, 60 ? / min ) heating and constant temperature heating by studying on eight kinds of biomass samples, according to the experimental data and arrhenius formula, we established the dynamics model of pyrolysis of, then, using the goast - redfern and p function, we also solved the dynamics parameters and analyze out every kind of biomass ' s frequency factor and parameters of activation energy, and established the every kind of dynamics model of pyrolysis of biomass, all of these provide the theories and basis to make sure the reactor ' s flash pyrolysis work temperature scope design and the describing of pyrolysis reactor dynamics ; ( 3 ), in order to study and ascertain the process of heat completely getting to pyrolysis time of varied size biomass particles, we observed and measured the ratio of length and diameter ( l / d ) with the varied biomass through electron microscope, we concluded the l / d ratios usually is from 5. 0 to 6. 0, the average is 5. 3 ; ( 4 ), we studied the process of biomass transiting and the theory of complete pyrolysis time with the theory of complicated heat field, we got the time ( t ) of the varied size biomass particles arriving to complete pyrolysis, and we knew that the complete pyrolysis time and the time which get to the biggest production ratio are identical, all of these studies provide the theory base for design and forecasting the flash pyrolysis reactor solid state resort time ; ( 5 ), according to the above experiment result, synthesize to make use of the engineering the mechanics, engineering the material, machine the design to learn the principle, deduce, establish the theory of rotation cone flash pyrolysis reactor material resort time ( t ) and reasonable rotation velocity ( or frequency ) relation theory ; and ( 6 ), we gave the reactor ' s smallest cone angle certain, reactor cone wall strength design theory, the reactor production ability theory, the power design method and the critical rotation velocity theory
本文較全面、系統地綜述了國內外生物質熱解液化制取生物燃油技術研究發展現狀及存在的問題，主要研究內容有： （ 1 ）實驗、測定了20種常見生物質的能量（發熱量）和c 、 h 、 n元素含量，根據實驗結果分別建立了以h和c為自變量的生物質能量預測經驗公式，並通過r _ （ 0 . 05 ）檢驗；為閃速熱解液化裝置能量轉化率計算和生物質能量利用率計算提供了依據和方便； （ 2 ）選擇了8種生物質試樣作了等加熱速率（ 10 min 、 20 min 、 40 min 、 60 min ）和恆溫加熱的tg和dtg實驗，根據實驗數據和阿倫尼烏斯公式建立了生物質熱解反應動力學微分方程，並採用goast - redfem積分法和p函數對其動力學參數進行了求解，解析出各種生物質的頻率因子和活化能參數，進而建立了各種生物質的熱解動力學模型，為科學確定反應器的閃速熱解工作溫度范圍及熱解反應動力學描述，提供了理論和依據； （ 3 ）為研究和確定不同尺度的生物質顆粒中心達到全熱解的時間，在體視顯微鏡下對不同粒度的生物質顆粒的長徑比進行了實驗觀察和測定，得出生物質的長徑比（ l d ）一般在5 . 0 6 . 0之間，平均為5 . 3的結果； （ 4 ）採用復雜溫度場傳熱學理論對生物質傳熱過程及充分熱解時間理論進行了研究，解析推導出了不同尺寸生物質顆粒中心溫度達到充分熱解溫度的時間（ t ） ，得出了理論推導的充分熱解時間與最大產油率的熱解時間相一致的結果，為閃速熱解反應器固相滯留時間設計和預測提供了理論依據； （ 5 ）根據上述實驗結果，綜合運用工程力學、工程材料、機械設計學原理，推導、建立了轉錐式閃速熱解反應器物料滯留時間（ ）與轉速（或頻率）合理匹配理論； （ 6 ）提出了轉錐式閃速熱解反應器的最小錐角設計、錐壁強度設計、生產能力設計理論和功率計算方法及臨界轉速理論等。3. bring forward a new idea : the ideology of synergetics used in atomic simulation and multi - scale simulation of materials design. on the basis of this, next tasks were put forward : ( 1 ) analyzing the changes of stress - strain curves of the interphase before and after pre - treatment ; ( 2 ) the efficient of the coupling effect of o2, na2s04 and h2o stream on the oxidation and erosion resistance of interphase ; ( 3 ) the methods of improving environment performance of interphase above 1273k
提出將協同學的思想用於原子級模擬及跨尺度模擬的思路，並在此基礎上，提出下一步的工作設想： （ 1 ）分析熱處理前後界面相區域應力-應變曲線的變化； （ 2 ）航空發動機模擬環境中，氧、硫酸鈉蒸汽及水蒸汽耦合效應對界面相抗氧化性、抗腐蝕性的影響； （ 3 ） 1273k以上界面相環境性能提高的方法。In this paper, the thermoelectric properties of ca3co2o6, and ca3co409 with layered structure are investigated by the quantum chemistry calculation. their conductivity and good thermoelectric properties are explained
本文運用量子化學計算方法對ca _ 3co _ 2o _ 6和ca _ 3co _ 4o _ 9層狀氧化物體系的熱電性質進行了研究，解釋了其傳導特性及其具有良好熱電性能的原因。Research of infrared spectrum and dsc curve indicate that there is no chemical bond between fe3o4 and pvdf. fe3o4 particles exist in the form of metal oxide particles. however, there is some force between fe3o4 and fluorine atom
紅外光譜和差示掃描量熱分析結果則表明， fe3o4與pvdf基膜間無化學鍵，是以純金屬氧化物晶粒存在於膜孔中和膜表面，但其與f原子間有一定的作用力。Using the microwave selective heating property for materials, by setup equivalent equation, and first time inducing the electromagnetic field perturbation theory to the design of heating materials for substrate in mpcvd, three temperature distribution modes were established, including temperature distribution comprehensive mode of inhomogeneous plasma, temperature distribution composite mode of composite substrate materials, temperature distribution perturbation mode of composite materials, which ii provided an whole new technology route to the design of substrate heating system in mpcvd and guided the preparation of heating materials for substrate. and then the heating materials for substrate were designed and optimized to obtain large area homogeneous temperature distribution even larger than substrate holder ' s diameter. as an important part, this thesis researched the nucleation and growth of diamond films in mpcvd, systematically researched the effects of substrate pretreatment, methane concentration, deposition pressure and substrate temperature etc experimental technologic parameters on diamond films " quality on ( 100 ) single crystal silicon substrate in the process of mpcvd, characterized the films qualities in laser raman spectra ( raman ), x - ray diffraction ( xrd ), scanning electron microscopy ( sem ), infrared transmission spectra ( ir ), atomic force microscopy ( afm ), determined the optimum parameters for mpcvd high quality diamond in the mpcvd - 4 mode system
該系統可通過沉積參數的精確控制，以控制沉積過程，減少金剛石膜生長過程中的缺陷，並採用光纖光譜儀檢測分析等離子體的可見光光譜以監測微波等離體化學氣相沉積過程；利用微波對材料的選擇加熱特性，通過構造等效方程，並首次將電磁場攝動理論引入到mpcvd的基片加熱材料的設計中，建立了非均勻等離子體溫度場綜合模型、復合介質基片材料的復合溫度場模型及復合介質材料溫度場攝動模型，為mpcvd的基片加熱系統設計提供了一條全新的技術路線以指導基片加熱材料的制備，並對基片加熱材料進行了設計和優選，以獲取大面積均勻的溫度場區，甚至獲得大於基片臺尺寸的均勻溫度區；作為研究重點之一，開展了微波等離體化學氣相沉積金剛石的成核與生長研究，系統地研究了在（ 100 ）單晶硅基片上mpcvd沉積金剛石膜的實驗過程中，基片預處理、甲烷濃度、沉積氣壓、基體溫度等不同實驗工藝參數對金剛石薄膜質量的影響，分別用raman光譜、 x射線衍射（ xrd ） 、掃描電鏡（ sem ） 、紅外透射光譜（ ir ） 、原子力顯微鏡（ afm ）對薄膜進行了表徵，確立了該系統上mpcvd金剛石膜的最佳的實驗工藝參數。Catalysts were prepared by impregnation reduction, thermal reduction, advanced thermal reduction and sol - gel methods from these metals. electrochemistry measurements, xrd, tem were used to test these catalysts. the results showed that these metals have some electrocatalysis activities towards hydrogen oxidation reaction
本文選擇了w 、 mo 、 co等金屬，採用浸漬還原法、熱還原法、改進的熱還原法以及溶膠凝膠法分別制備了這幾種金屬的碳載催化劑，對制備出的非貴金屬催化劑進行了電化學測試、 x -射線衍射（ x - raydiffraction ， xrd ） 、透射電子顯微鏡（ transmissionelectronmicroscopy ， tem ）等測試，研究結果表明:這些非貴金屬在硫酸體系中對氫氣的氧化反應均有一定的催化活性。This is just a simple aspect of chemistry in that any material crumbles into atoms if made hot enough. the technique is called vacuum pyrolysis - pyro means fire, lysis means to separate. a number of factors make prolysis more attractive than other technique
這其實是顯淺的化學原理，任何物質當加熱到某一個程度，便會分解為原子，而研究小組所用的方法稱為真空熱解法。This part emphasizes the synthesis of nanoarrays, aiming at controlling the size and distance of nanocrystallites using calixarene derivatives by altering the size, length and chemical structure of the organic molecules ; 2. this part emphasizes in situ synthesis strategy for fabrication of polymer network of zns based nanopowder, aiming at size controls, coating and preventing agglomeration following " one - pot " synthesis ; this method fits to low cost, large scale production ; 3. according to development in zno nanomaterials, we first report on the synthesis, characterization of amorphous zno, aiming at describing the principles and approaches of synthesis techniques, optical properties, spatial structure and doped effect ; the amorphous zno displays cage - like structure, showing a strong ultraviolet emission while the visible emission is nearly fully quenched, a potential uv - emission material ; 4
本論文以量子結構自組裝為出發點，提出利用杯芳烴及其衍生物的化學受限反應實現尺寸可調半導體納米粒子自組裝；提出有機聚合網路原位組裝zns基納米熒光粉方法，把熒光粉的納米化、包敷、防團聚在「一鍋」反應中完成，適于低成本，批量生產；根據當前zno的研究情況，我們首次合成了非晶zno ，研究了它的光學性質，確定了它的結構，並對其摻雜進行了初步的研究，非晶zno表現出強的深紫外發光特性，而可見發射非常弱，是一種有巨大潛在應用價值的深紫外發光材料；利用非晶zno的亞穩特性，對晶化過程中非晶zno納米晶zno三維受限量子結構特性，界面特性進行了深入的研究；利用固相熱分解一般受擴散控制特性，實現了尺寸可控的zno三維量子結構的自組裝；利用非晶zno的高度分散性，容易均勻成膜特性，實現了非晶籽晶誘導低溫液相外延自組裝生長高取向zno晶體薄膜。分享友人