熱解反應 的英文怎麼說
中文拼音 [rèjiěfǎnyīng]
熱解反應
英文
pyrolytic reaction-
In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術，有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應，提高了聚合物大分子鏈中有機硅鏈節的含量；利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵，並通過對共聚產物力學和吸水率的測試，證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能；從分子設計角度出發，利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體： ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷；利用核磁共振對新型硅烷單體結構進行了證實；研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液，且其聚合產物具有較高的力學及耐水性能。This type of thermal decomposition is called pyrolysis.
這種類型的熱分解反應稱做熱解。The results indicated that the dimension, shape and purity of base material could meet the functional demand of solid lubricant ; the thermal decomposition temperature of ptfe resin exceeds 400 c, but organic and inorganic packing filler added in ptfe made the water absorption rate of composite material increased, melting temperature and decomposition temperature decreased, in the meanwhile oxidative decomposition reaction was accompanied ; polar groups such as c = o, c - o - c and so on in the carbon fiber surface is advantageous to increase compatibility with other components and interlayer shearing strength ; uniform design experimental method could help to find the relationship between formula and frictional property by relatively small tests. the developing trend of each formula ' s friction coefficient could be showed by fitting curve ; the friction coefficient with no copper powder or graphite in formula was relatively big. this fact showed that copper powder and graphite should be used cooperatively ; it was found that when the ratio of copper powder to graphite by weight is 15 : 60, 30 : 30 - 40 and 60 : 15 - 30 respectively, the friction coefficient was relatively small. the degree of crystallinity of pure ptfe reached maximum by air cooling and the abrasion loss also reached maximum among three ones ; at the same time, the abrasion loss of solid lubricant sample was also the biggest among three ones ; when solid lubricant matched with 45 # steel axle or gcrl5 steel axle, lubricant transfer film could be formed on metal surface, thus direct contact between the surface of metal friction pair rings was reduced. their working life was elongated extremely ; there was mainly much graphite, a little ptff, moo3, feso4, cus and so on in lubricant transfer film
試驗結果表明：所選原料的尺寸、形狀及純度可滿足固體潤滑劑的性能要求；聚四氟乙烯樹脂熱分解溫度超過400 ，但在ptfe中加入無機填料會使復合材料吸水率提高，熔融溫度及分解溫度降低，且伴有氧化分解反應；碳纖維表面含有c = o及c - o - c等極性基團，有利於提高其與其它組分的相容性，提高層間剪切強度；均勻設計試驗方法能夠用較少的試驗次數找出配方與摩擦性能間的關系，擬合曲線基本能表示各配方的摩擦系數發展趨勢；配方中不加銅粉或不加石墨，其摩擦系數均較高，說明銅粉和石墨應該配合使用；當銅粉15份、石墨60份時，銅粉30份、石墨30 - 40份時，銅粉60 、石墨15 - 30份時，摩擦系數均具有較低值；純聚四氟乙烯樹脂在空氣冷卻時結晶度最大，磨損量也是三者中最大的；同時，固體潤滑劑試樣在空氣冷卻時的磨損量也是三者中最大的：不論是固體潤滑劑與45 #鋼軸配副或是固體潤滑劑鑲嵌入銅套后與gcr15鋼軸配副，在金屬表面均可形成潤滑轉移膜，從而減少金屬摩擦副表面間的直接接觸，大大延長其使用壽命;轉移膜中主要含有較多的石墨、少量聚四氟乙烯、 moo 。The results provided theoretical basis for down - hole catalytic upgrading of heavy oil
探討了催化劑對稠油水熱裂解反應的催化機理。Heavy oil viscosity reduction of was studied by using toluene as additive for catalytic aquathermolysis reaction in this paper
摘要以鉬酸銨作為稠油水熱裂解反應的催化劑。The results showed that hydrothermal cracking occurred while injecting steam, and the catalyst had catalytic activity for hydrothermal cracking of heavy oil at higher temperature ; viscosity and average molecular weight of heavy oil was thus lowered
實驗結果表明，在注入蒸汽的條件下，遼河稠油可以發生水熱裂解反應，高溫下催化劑對水熱裂解反應具有催化作用。A two - dimensional model is proposed for simulation of gas phase cracking of 1, 2 - dichloroethane ( edc ) to produce vinyl chloride monomer ( vcm ) in tubular reactor furnace, in which side reaction of coke precursor formation is taken into consideration
摘要建立了二氯乙烷在管式反應器中進行氣相熱裂解的二維模型，模型考慮了二氯乙烷熱解生成氯乙烯的主反應和生成焦前體的副反應以及氣體密度變化對裂解反應的影響。Microcalorimetric study of effect of pretreatment on enzymatic hydrolysis of wheat straw
微量量熱法研究預處理對小麥秸稈酶降解反應的影響By control the adulteration of kmno4 powder in the raw materials, we found the adulteration of kmn04 powder decrease the dosage of easy melted metal mn, and release the hot - trap problem, enhance the diffusion velocity as well as cut down the synthesis temperature and combustion propagation velocity of the system
320左右體系內sro _ 2分解放出氧氣，並且和空氣中的co _ 2發生反應生成了srco _ 3發生強烈的放熱反應，緩慢的放熱包。 450左右體系內naclo _ 4分解吸熱， shs反應被觸發，反應劇烈，放出大量的熱。Thermodynamic properties for the dissolution of nickel orthoperiodate hydrate
水合正高碘酸鎳鹽溶解反應的熱力學性質Mechanisms of nonequilibrium plasma - chemical reactions and coal pyrolysis
非平衡等離子體與煤熱解反應機理This text completely and systematically studies the status and the development of the pyrolysis and the fluidization of biomass, which distill the bio - oil in the domestic and international area, as well as the existing problems. this thesis primarily include following aspects : ( l ), by experimenting and measuring the energy ( heat value ) and the content of c, h, n chemical element of right 20 kinds of common biomass, on the base of the experimental result, and respectively established the biomass energy predict experiment formula with the element of h and c is from change, and passed the ro. os examination, which provides the basis and convenience for flash pyrolysis fluidization device energy to convert the rate to compute with biomass energy utilization calculation ; ( 2 ), proceeded the tg and dtg experimentation equal velocity ( 10 ? / min, 20 ? / min, 40 ? / min, 60 ? / min ) heating and constant temperature heating by studying on eight kinds of biomass samples, according to the experimental data and arrhenius formula, we established the dynamics model of pyrolysis of, then, using the goast - redfern and p function, we also solved the dynamics parameters and analyze out every kind of biomass ' s frequency factor and parameters of activation energy, and established the every kind of dynamics model of pyrolysis of biomass, all of these provide the theories and basis to make sure the reactor ' s flash pyrolysis work temperature scope design and the describing of pyrolysis reactor dynamics ; ( 3 ), in order to study and ascertain the process of heat completely getting to pyrolysis time of varied size biomass particles, we observed and measured the ratio of length and diameter ( l / d ) with the varied biomass through electron microscope, we concluded the l / d ratios usually is from 5. 0 to 6. 0, the average is 5. 3 ; ( 4 ), we studied the process of biomass transiting and the theory of complete pyrolysis time with the theory of complicated heat field, we got the time ( t ) of the varied size biomass particles arriving to complete pyrolysis, and we knew that the complete pyrolysis time and the time which get to the biggest production ratio are identical, all of these studies provide the theory base for design and forecasting the flash pyrolysis reactor solid state resort time ; ( 5 ), according to the above experiment result, synthesize to make use of the engineering the mechanics, engineering the material, machine the design to learn the principle, deduce, establish the theory of rotation cone flash pyrolysis reactor material resort time ( t ) and reasonable rotation velocity ( or frequency ) relation theory ; and ( 6 ), we gave the reactor ' s smallest cone angle certain, reactor cone wall strength design theory, the reactor production ability theory, the power design method and the critical rotation velocity theory
本文較全面、系統地綜述了國內外生物質熱解液化制取生物燃油技術研究發展現狀及存在的問題，主要研究內容有： （ 1 ）實驗、測定了20種常見生物質的能量（發熱量）和c 、 h 、 n元素含量，根據實驗結果分別建立了以h和c為自變量的生物質能量預測經驗公式，並通過r _ （ 0 . 05 ）檢驗；為閃速熱解液化裝置能量轉化率計算和生物質能量利用率計算提供了依據和方便； （ 2 ）選擇了8種生物質試樣作了等加熱速率（ 10 min 、 20 min 、 40 min 、 60 min ）和恆溫加熱的tg和dtg實驗，根據實驗數據和阿倫尼烏斯公式建立了生物質熱解反應動力學微分方程，並採用goast - redfem積分法和p函數對其動力學參數進行了求解，解析出各種生物質的頻率因子和活化能參數，進而建立了各種生物質的熱解動力學模型，為科學確定反應器的閃速熱解工作溫度范圍及熱解反應動力學描述，提供了理論和依據； （ 3 ）為研究和確定不同尺度的生物質顆粒中心達到全熱解的時間，在體視顯微鏡下對不同粒度的生物質顆粒的長徑比進行了實驗觀察和測定，得出生物質的長徑比（ l d ）一般在5 . 0 6 . 0之間，平均為5 . 3的結果； （ 4 ）採用復雜溫度場傳熱學理論對生物質傳熱過程及充分熱解時間理論進行了研究，解析推導出了不同尺寸生物質顆粒中心溫度達到充分熱解溫度的時間（ t ） ，得出了理論推導的充分熱解時間與最大產油率的熱解時間相一致的結果，為閃速熱解反應器固相滯留時間設計和預測提供了理論依據； （ 5 ）根據上述實驗結果，綜合運用工程力學、工程材料、機械設計學原理，推導、建立了轉錐式閃速熱解反應器物料滯留時間（ ）與轉速（或頻率）合理匹配理論； （ 6 ）提出了轉錐式閃速熱解反應器的最小錐角設計、錐壁強度設計、生產能力設計理論和功率計算方法及臨界轉速理論等。So in china research with investigate to adapt to the state of the nation, using above and all kinds of abandon biomass with the large quantity ' s resources of low quality and low price food economily, fleetnessly and high - efficiently to convert for that can act for on a certain degree the petroleum conversion of bio - fuel - oil theories with method, have important of economic meaning is with the social meaning, this text author is on check the foundation of the related data of domestic and international large quantity, proceeds living creature quality pyrolysis experiment that solve, established the pyrolysis solution to respond the dyn amics model, combine right turn the main design theories that equip of solution of pyrolysis of quality of rotating cone type living creature that parameter to proceeds the research, provided the theories the basis with experiment the data in the follow - up research
因此，在我國，研究和探索適應國情，將上述各種廢棄生物質和大量的低質低價糧食資源，經濟、快速、高效能地轉化成可在一定程度上替代石油的生物燃油的轉化理論和方法，具有重大的經濟意義和社會意義。本文作者在查閱國內外大量相關資料的基礎上，進行了生物質熱解的實驗，建立了熱解反應動力學模型，並對轉錐式生物質熱解裝置的主要參數的設計理論進行了研究，為后續研究提供了理論依據和實驗數據。The reaction order and apparent activation energy of nanocomposites by emulsion and bulk methods are obviously increased. this also shows that the thermal stability of nanocomposites is much better than pure pmma, which is also confirmed by doyle method
Freeman - carroll差減微分法結果表明：本體法及乳液法復合材料的熱分解反應級數和表觀活化能均明顯高於純pmma ； doyle積分法佐證了這一點。The tg and dta techniques were used to research the decomposition kinetics of depositions. the decomposition mechanism and kinetics - equation were investigated according to phadnis methods, and the equation can be depict as follow : the kinetics parameter of decomposition were obtained by using kissinger methods. the activation energy was 162. 41kj / mol and reaction index was 1. 30
利用phadnis法則，推斷堿式碳酸鈷的熱分解反應機理符合反應級數法則，得到非等溫條件下堿式碳酸鈷的熱分解動力學方程為：並利用kissinger法計算堿式碳酸鉆熱分解反應的表觀活化能為162 . 41kj mol ，熱分解反應級數為1 . 30 。383 what is the feature of this cracker ( cracking furnace, heating furnace, reactor, mixer, centrifuger, belt - conveyer )
這臺裂解器（裂解爐、加熱爐、反應器、攪拌器、離心機、皮帶輸送機）的特點是什麼？Development of twelve - lumped model for product distribution in thermal conversion of heavy oil
12集總重油熱解反應產物分佈模型的開發One set of equipment for gas catalystic reconstruction developed by us own is illustrated in the following figure, in which tar sampling system is also included. in this thesis, the experiment system : biomass tar catalytic pyrolysis, which overcomes the disadvantage of mixture of some typical compound. and some improvement was made to adapt the characters of tar content of china
該試驗裝置克服了當前生物質焦油催化裂解研究中採用焦油的某一種組分或者幾種組分的混合物作為其模擬化合物的缺點，以熱解反應器產生的生物質氣為焦油來源，在實驗中對現有的焦油取樣分析方法進行了改進，提出了適合我國生物質特點的焦油成份分析方法。In view of cost, the clarification effect and environmental protection, the cleaning system with coke as absorbent should be the fairly good choice that can produce less tar content and high quality household gas. the cost will be made fewer as well for the reason that coke in filter and clarifier - tank can be put into gasifier again to pyrolyze. in order to improve the clarification level and make preparations for generating electricity by means of biomass gasification technology
該試驗裝置克服了當前生物質焦汕催化裂解研究中採用焦油的某一種組分或者幾種組分的混合物作為其模擬化合物的缺點，以熱解反應器產生的生物質氣為焦油來源，研究了生物質焦油的催化裂解原理、催化裂解中不同氣化溫度、裂解溫度、停留時間對焦油成分和催化裂解效果的影響，並對比以前的試驗結果進行了初步的理論分析。The oil was studied in detail from different aspects, the results of which showed the effect of pyrolytic temperature on the properties of the oil and the characteristics of the pyrolysis reaction in the rotary kiln reactor
通過不同角度全面考察熱解油品質，從而反映出熱解溫度對熱解油品質的影響和回轉窯反應器內熱解反應的特點。分享友人