環低聚作用 的英文怎麼說
中文拼音 [huándījùzuòyòng]
環低聚作用
英文
cyclooligomerization-
Activation of calix 6 arene in the ring - opening polymerization of - caprolactone catalyzed by rare earth aryloxide catalysts in low temperature
己內酯低溫開環聚合中的活化作用The present work is to develop a new high performance single component waterproofing construction putty powder with cement fly asb quartz powder cmc and pp fiber as its main constitutes. its result can be a basis to popularize cement putty and a reference to establish national criterion. firstly, the influence of some major materials on the basic performances of putty was studied, and find the major constitutes and mix proportion, simultaneity, the principle to select element is cheap unpolluted and comprehensive
為了提高建築工程的裝修質量以及適應我國當前建築事業的發展要求，本文選用水泥、粉煤灰、石英粉等常用建材並摻入適量纖維素、聚丙烯纖維及助劑配製出一種高性能單組分且具防水性的新型水泥基膩子，成本低廉且符合環保要求，其成果可作為推廣水泥基膩子產品應用的依據，並對國家外墻膩子行業標準的制定提供參考。So we figured that the influence of the electron - electron interactions must be considered in our work. added an electron - electron interaction ( up to the fourth neighbor ) term to the baranowski - buttner - voit ( bbv ) model for polyaniline, we carried out a self - consistent - variation calculation for an biexciton in the pernigranlilne - base polymer, in order to confirm the model hamiltonian. the results showed that two peaks ( near l. oev and 1. 5ev ) appeared in the calculated optical absorption, besides the reproduced electronic structure, bond order wave ( bow ) and ring - torsion angles
發現引入電子?電子相互作用后，聚苯胺靜態激子的性質受到影響，該聚合物的鍵序波、芳環扭角和電子中文摘要結構發生了變化，而且在理論吸收譜的低能端出現了明顯的二特徵吸收峰（ 1 . 0ev和1 . 5ev附近） ，這一結果與實驗數據很好的吻合，從而這一點表明我們所考慮的因素是合理的。The recombinants were constructed by transforming ppic9 a - xynb into p. pastoris gs115. the assay results revealed that the xylanase gene xynb was overexpressed and secreted effectually in p. pastoris. in 3l fermentor the expression level of xylanase xynba exceeded 1200iu / ml and the expressed xylanase had normal bioactivity. the molecule weight of xynba was determined as about 31kd which is higher than 23kd of original enzyme xynb from streptomyces olivaceoviridis a1. xynbb was gotten by deglycasylation of xynba, whose molecule weight returned to 23kd. we comparised the enzymatic properties of xynba expressed in p. pastoris, xynbb deglycasylated from xynba and xynb produced from streptomyces olivaceoviridis al : there was little difference among the three enzymes on optimal ph, the optimal ph of xynb and xynba were both 5. 2, the optimal ph of xynbb was 5. 0 ; the optimal temperature of xynb and xynba were both 60 c, while the optimal temperature of xynbb was 50 ? ; because of glycosylation the thermal stability of xynba was better than xynb and xynbb ; the specific activity of xynba and xynbb were 883. 88iu / mg and 832. 5hu / mg respectively, which were both lower than 2814. 45iu / mg of xynb ; the km values of xynb and xynba were similar to each other which were 21. 56 ( g / kg ) and 20. 87 ( g / kg ), while the km value of xynbb was 27. 10 ( g / kg ) ; the fmax of xynba and xynbb were 4568umol / mg. min and 5329umol / mg. min respectively which were lower than 27623 umol / mg. min of xynb ; additionally all of the three enzymes did not display cellulase activity. they all had well resistance to pepsion and trypsin, and were not sensitive to metal iron, surface active agent and chelating agent. the analysis of different xylans enzymatic hydrolysate revealed : by xynba, that the main constitutions of enzymatic hydrolysate of birch wood xylans were xylotriose and xyloquaiose, which account for 68. 43 % and 16. 50 % respectively, additionally there was 11. 79 % of xylobiose ; the main constitutions of enzymatic hydrolysate of corncobs xylans were xylobiose and xylotriose, which account for 81. 78 % and 11. 55 %. the result indicated that this xylanase was a kind of 1, 4 - b - d - xylanohydrolase and was fit to used in industrial procession of xylooligosacc harides
進一步對xynba進行了脫糖基化處理得到xynbb ，其分子量恢復到23kd ，證明xynba是糖基化蛋白。通過對畢赤酵母重組表達的木聚糖酶xynba 、脫糖基化的木聚糖酶xynbb以及橄欖綠鏈黴菌a1所產原酶xynb之間酶學性質的比較發現：三種酶的最適ph差異不大， xynb和xynba均為5 . 2 ， xynbb為5 . 0 ； xynb和xynba的最適溫度均為60 ， xynbb降為50 ：在耐熱性上， xynba由於糖基化作用熱穩定性明顯高於未糖基化的xynb和xynbb ； xynba和xynbb的比活性分別為883 . 88iu mg和832 . 51iu mg ，明顯低於原酶的比活2814 . 45iu mg ； xynb和xynba的km值相當，分別為21 . 56 （ g kg ）和20 . 87 （ g kg ） ，而xynbb的km值較大為27 . 10 （ g kg ） ； xynba和xynbb的vmax相差不大，分別為4568 mol mg ? min和5329 mol mg ? min ，明顯低於xynb的27623 mol mg ? min此外三種酶均無纖維素酶活性，對胃蛋白酶和胰蛋白酶有很好的抗性，且對作用環境中的各種離子、表面活性劑、螯合劑不敏感。通過對不同木聚糖的酶解產物的糖份分析發現：以樺木木聚糖為底物時，酶解產物主要為木三糖和木四糖，含量分別為68 . 43和16 . 50 ，另外還含有11 . 79的木二糖；以玉米芯木聚糖為底物時，酶解產物主要為木二糖和木三糖，含量分別為81 . 78和11 . 55 。The electrode was found to decrease the solubility of dithizone in alkalescence solution and effectively minish the lose of deoxidize state of metal. third, a potentiometric sensor was prepared by adding copper diethyldithiocarbamate directly into the carbon paste mixture, and the electrode was found has nerst response to copper ion in solution. and in our research two pharmaceutical selective electrodes were fabricated by coating polyvinyl chloride ( pvc ) which contained electroactive material on carbon rod electrode
第二，利用- cd與環氧氯丙烷形成的交聯聚合物（ - cdp ） （不溶性）包合了雙硫腙，然後將- cdp與雙硫腙包合物樹脂作為修飾劑制備了碳糊修飾電極，利用陽極溶出伏安法（ asv ）測定了pd ~ （ 2 + ） ，實驗發現通過包合降低了雙硫腙在堿性溶液中的溶解度並且減少了金屬還原態的流失，取得了較好的效果。Abstract : by modifing epoxy resin with functional polysiloxane, the reduction of the internal stress of encapsulant made from polysiloxane - modified epoxy was realized. the thermal and mechanical properties of the modified epoxy encapsulant were introduced
文摘:綜述了用功能性聚硅氧烷對環氧樹脂封裝料進行改性從而實現環氧封裝料低應力化的幾種方法；並對改性后封裝料的結構、熱性能和機械性能作了詳細介紹。The analysis of the large - scale synoptic situation shows that strong precipitation is closely related to the explosion of monsoon and the intensification of cross - equatorial flow which bring a lot of vapor and meet with cold masses at the eastern of northwest district on 8th, june causing extremely heavy rainfall ; that subtropical high - level jet at 200hpa, subtropical high at 500hpa and low - level jet at 850hpa are the weather backgrounds favorable to strong precipitation ; that the pattern of eastern highs and western lows and the establishment of a low - level jet and the coupling between upper - and low - level patterns that determine that the rain occurred in the east of the northwest china ( on average, this is the rainy season for the south of china, but not for the northwest china ) ; that water vapor comes from southerly and easterly flow which converge at the eastern of northwest district with convergence mainly in lower levels and pbl ; that the high value of the whole - level apparent heat source < q1 > is near the area of large rainfall in the direction of northeasterly - southwesterly agreeable to shear line very well and the condensation latent heat releasing is main heat source with vertical advection item playing key role in q1 and q2 ; that there is a vertical secondary circulation crossing low - lever jet whose ascending branch is at the area of large rainfall ; that the construction of convection instability and conditional symmetry instability results that there is not only deep thermal instability, but also moisture influx and triggering mechanism of thermal instability causing strong torrential rain
作為對比，本文還對2002年6月24 - 25日發生在北京地區的強地形雨進行了分析，並討論陜南、北京地區兩地暴雨的異同點以及地形作用的共性和個性，為兩地暴雨預報提供有益的參考，得出了一些很有意義的結果： 1大尺度環流背景分析表明： （ 1 ） 「 02 . 6 」強降水與6月上旬越赤道氣流和季風爆發密切相關，攜帶大量水汽的偏南氣流與冷空氣於6月8日交匯在西北地區東部，導致了這次強降水的發生； （ 2 ） 200hpa的副熱帶西風急流、 500hpa副高以及850hpa的低空急流的配置非常有利於本文分析之陜西強降水的發展與維持。大尺度形勢分析表明，東高西低形勢場、低空急流的建立和高低空形勢的配置決定了這場降雨出現在西北地區東部。與暴雨區相聯系，存在一支橫越低空急流的經向垂直環流，暴雨區處于該垂直環流的上升支； （ 3 ）偏南和偏東氣流水汽通道在西北地區東部交匯，水汽的輻合積聚主要在對流層低層和行星邊界層內完成； （ 4 ）整層的視熱源< q _ 1 >高值區在暴雨區附近呈東北-西南向分佈，與切變線走向非常一致，降水產生的凝結潛熱釋放是強降水區大氣的主要熱源。As the content of vermiculite minerals increased, the content of the " intercalated " shape, in which crystal gallery breadth was about of 40nm, also increased. in the curing reaction processing of polybenzoxazine / vermiculite hybrid nanocomposites intercalated with bisphenol a type precursor. according to the content of vermiculite minerals, while different shape of crystal was forming, these crystals were retarding the heat ring - opening polymerization of bisphenol a type precursors in the nanocomposites
通過對雙酚a型ben蛭石納米插層物固化過程的分析：不同蛭石含量的插層物，在形成不同納米分散狀態固化結構的過程中，蛭石晶片對雙酚a型ben的熱開環聚合有明顯不同的阻礙作用，蛭石含量為3的插層物160的凝膠化時間較純樹脂的延長約7min ，活化能高約8kj mol ，固化反應熱晗低約14j g ，使得固化物的固化程度較純樹脂低約10 ，阻礙作用最大，其它含量的次之。From the results of the experiment, we can see that simultaneity electrochemical polymerization of 3 - pyrrole - dna and 3 - [ 2, 5, 8, 11 - tetraoxa - tridecyl - 13 - ol ] - pyrrole was a new promising method for preparing dna chips because this method had such following advantages : first, the immobilization procedure can be controlled easily. second, with the progress of microelectronics, the miniaturization and integraterization of polypyrrole - based dna chip can be achieved in the future ; third, using an electrochemical active compound like the mb, the hybridization detection will be performed more easily
從以上實驗結果可看出，電化學聚吡咯方法制備dna晶元和傳統的方法相比具有下列優越性：首先，固定可通過電化學信號控制和完成，操作簡單易行；其次，微電子技術和電化學的進一步結合，可以提高晶元的集成程度，將dna晶元進一步向產業化方向推進；第三，通過應用電化學活性物質，有望建立無標記的dna晶元檢測技術，有利於減少環境污染、提高靈敏度、降低成本。Tem reveals that the complex possessed good dispersibility in the system and the status varied reversibility with the ph value and the size of the complex is within 20 ~ 40nm. the complex was characterized by ft - ir, uv - vis, fluoresence and electrical conductivity methods. paa - ag nanospheres were also synthesized by coordination of polyacrylic acid and silver ( i ) ion and queued in line in lr
本論文還以低分子量的聚丙烯酸和硝酸銀為主要原料，通過控制體系的ph值合成響應環境ph值變化的聚丙烯酸銀納米微球和納米柱狀物，通過tem觀察尺寸達20 - 40nm ，用ir 、 uv - vis 、熒光、電導率法分析聚丙烯酸和銀的配位作用、所形成配合物的組成與結構，並將聚丙烯酸和硝酸銀置於「線性反應器」中進行配位聚合，合成出線性排列的paa - ag納米微球。分享友人