有機聚硅烷 的英文怎麼說
中文拼音 [yǒujījùguīwán]
有機聚硅烷
英文
organopolysilane-
In this thesis, the development of emulsion polymerization theory and related new technologies are comprehensively reviewed, and the synthetic technologies of acrylate latex modified by organosilicon both at home and abroad are also reviewed. based on the current development and research in this field, attentions of this study are focused on three ways for preparing novel acrylate latexes modified by organosilicons, that is, 1 ) the acrylate monomers are copolymerized with unsaturated silicons by emulsion copolymerization ; 2 ) a new latex with microphase separation morphology is synthesized, which shows a core - shell structure character ; 3 ) soap - free polymerization is explored for preparing a higher - performance latex using an unsaturated silicon monomer, different acrylates and a reactive emulsifier. by using techniques of delaying addition of organosilicon monomer and a hydrolysis inhibitor, the hydrolysis and condensation of 3 - ( trimethoxysilyl ) propyl methacrylate during polymerization can be effectively prevented, as a result, organosilicon content in the macromolecular chain is increased
同時採用有機硅單體延遲滴加及添加水解抑制劑等技術，有效防止了-甲基丙烯酰氧基丙基三甲氧基硅烷在乳液聚合過程中的過渡水解及縮合反應，提高了聚合物大分子鏈中有機硅鏈節的含量；利用紅外光譜與差示掃描量熱儀對產物分子結構進行了表徵，並通過對共聚產物力學和吸水率的測試，證實了本研究所制備的有機硅改性丙烯酸酯共聚物具有比純丙烯酸酯聚合物更優良的力學及耐水性能；從分子設計角度出發，利用醇解反應合成出水解、縮合反應速率較慢的兩種新型不飽和有機硅單體： ?甲基丙烯酰氧基丙基三乙氧基硅烷和?甲基丙烯酰氧基丙基三異丙氧基硅烷；利用核磁共振對新型硅烷單體結構進行了證實；研究表明利用新型硅烷單體可以制備出高硅烷含量的有機硅改性丙烯酸酯乳液，且其聚合產物具有較高的力學及耐水性能。Using the semi - batch synthesis techniques, a grafting reaction mechanism is adopted to prepare a core - shell composite latex of siloxane / acrylate based copolymer
利用接枝反應和種子溶脹半連續滴加技術合成了聚有機硅氧烷聚丙烯酸酯復合乳液。Silicone polyesters resins are the reaction product of organo - siloxane intermediates and a suitable polyester resin intermediate ( typically characterized by the absence of drying oils )
硅改性聚酯樹脂是有機硅氧烷和相應的聚酯樹脂中間產物反應而得到的產品。Using the dynamic mechanical analyzer ( dma ), pdms / pma ipn was investigated at temperature of 5 - 180 c. the initiator, the component ratio, the type of pdms and the filler effected the damping properties. the result showed that the damping ability varied with the parameter and there was an optimal value. the excellent damping material in the papers was ipn, where tan man was 0. 735, and the damping functional temperature ranged with tan 8 > 0. 3 was 46 c. the micro - morphology and structure of pdms / pma ipn were characterized by two kinds of sem
高分子阻尼材料的有效阻尼功能區是在ipn材料的t _ g區間內，而研究常溫條件下的阻尼性能更具有重要應用價值，運用動態熱機械分析（ dma ）儀對ipn阻尼材料進行表徵，在5 180內對其損耗因子（ tan ）進行研究，發現引發劑和交聯劑的用量、聚硅氧烷的用量和分子量等參數對ipn阻尼性能的影響較大，存在一個合理配比值，當pma與粘度為3300pa ? s的pdms之比（質量比）為1 . 17 ： 1 、交聯劑用量為1時， tan最大值為0 . 735 ，大於0 . 3的溫域差達到46 。Through the research of crosslinking of matrix resin, heating treatment of composite and mixing of different polymer, we draw some conclusions : 1 、 percolation theory can explain the phenomenon of the jump of resistance when the content of cb reach a critical volume ; 2 、 based on ohm conduct theory, abounded to the percolation the wbibull statistical theory and other theory, an adapted theory was obtained to explain the jump of resistance and the other phenomenon ; 3 、 the ntc phenomenon was eliminated by crosslinking the matrix of conductive composite, at the same time the stability of composite was improved
通過對基體樹脂的交聯、復合材料的熱處理、聚合物共混物的研究得出了如下的結論： 1 、滲濾理論能夠很好的解釋導電粒子含量達到某一值時電導率劇增的問題； 2 、在歐姆導電模型的基礎上，綜合應用了weibull統計理論模型，結合原來的體積膨脹等理論，成功的解釋了ptc復合材料在基體材料熔點附近的跳變問題、 ntc現象以及熱循環穩定性等問題； 3 、有機ptc導電復合材料經硅烷交聯以後能夠消除ntc現象，改善了導電復合材料的穩定性能。Silane coupling agents are compatible with almost every type of organic polymer.
硅烷偶聯劑幾乎對每一種類型的有機聚合物都是合適的。Organic silicon : silicon oil ( silicon grease, silicon suckling liquid, silicon surfactants ), silane coupling agent ( organic silicon chemistry reagent ), high temperature sulfur rubber, liquid silicon rubber, organic silicon polymer, silicon resin, organic silicon singles, compound etc., organic silicon produce and the related raw material, aid chemical preparation, technique
有機硅：硅油（硅脂、硅乳液、硅表面活性劑） ，硅烷偶聯劑（有機硅化學試劑）高溫硫化橡膠、液體硅橡膠、有機硅聚合物、硅樹脂、有機硅單體、復合物等，有機硅生產相關原料、助劑、技術。The silicone and silicone emulsion, hydrophobic additive, were preparaed by the method of hydrolytic polymerization and emulsion polymerization, respectively. the technical factors and properties of the coating were optimized. the design mothod of the heat - insulated coating film was studied
首先用硅氧烷水解聚合法和乳液聚合法制備了高效疏水性硅酮樹脂和有機硅乳液型疏水添加劑，並對制備工藝參數、性能進行了優化。The different ratio and dosage of composite surfactants were researched about the polymer latex ' s stabilization and structure. afterwards, the emulsion polymerization of tris, mma, and p ( mma - co - ptris ) were carried out. some different monomer ratio copolymer latex and homopolymer latex are prepared by emulsion polymerization used self - made organosilicone monomer - [ tris ( trimethylsiloxy ) silyl ] propylmethacrylate and mma
用ir ， tem ， dma ，水滴接觸角測試等方法表徵所制備的均聚物和共聚物膜發現：採用有機硅表面活性劑與十二烷基硫酸鈉復配使用，用量在6 8 （相對單體量）可得到粒徑分佈均勻且穩定的均聚和共聚乳液。This product which is odourless, safe and concentrated, can offer you the best convenience and prolong the using lifetime of machine
本品是濃縮乳聚硅氧烷乳劑，對消除各類清洗機械操作中所產生的泡沫有良好的效果，並能延長機械使用壽命。Organosilicon polymer ( silicone ) has the potential application in many industry areas as new material owing to its excellent properties
摘要以聚硅氧烷為基礎的有機硅材料作為一種新型材料，具有特殊的物理化學性能，在許多工業領域中得到了廣泛應用。The vulcanization reaction of the ipn and pdms was determined by the fourier transform infrared ( ft - ir ). the mechanism of the vulcanization did ' t change, no chemical reaction between the ma and the pdms appeared
紅外光譜儀對聚硅氧烷和ipn固化前後的化學結構的分析表明，反應按照各自機理進行，丙烯酸甲酯與聚硅氧烷之間沒有發生化學反應，說明反應具備ipn形成的基本條件。Silylate - terminated polyurethanes with built - in hydrophilic sites were synthesized. when the polymer is dispersed in water, the silane alkoxy end - groups of the polymer undergo hydrolysis, followed by condensation to form a stable cross - linked aqueous dispersion. tem studies indicated that with more incorporation of hydrophilic sites, the particle size of the dispersion decreased. it was also found that the film property depended on the particle size when the crosslinking density in particels was much higher. the average molecular weight of the elastically effective network chain mc measured by swelling experiments shows fairly good agreement with the theoretical value of mc. it was also found that the cross - linking density of the casting film may increase during the film formation and drying process
將硅氧烷封端的含親水基團的線性聚氨酯預聚體分散於水中，獲得穩定的聚氨酯分散體.由於硅氧基團水解、縮合，在分散體粒子內產生擴鏈交聯反應，生成了交聯水基聚氨酯分散體.透射電子顯微鏡研究表明分散體粒徑小、分佈寬.掃描電子顯微鏡研究了成膜結構及成膜性能與粒徑的關系.溶脹實驗計算獲得的兩交聯點之間的平均分子量與理論平均分子量相符.研究還發現此分散體膜在乾燥過程中可進一步交聯.膜的水溶脹及機械性能表明，此分散體具有極大的工業應用價值分享友人