離子配合物 的英文怎麼說
中文拼音 [lízipèigěwù]
離子配合物
英文
ionic complex- 離 : Ⅰ動詞1 (離開) leave; part from; be away from; separate 2 (背離) go against 3 (缺少) dispens...
- 子 : 子Ⅰ名詞1 (兒子) son 2 (人的通稱) person 3 (古代特指有學問的男人) ancient title of respect f...
- 配 : Ⅰ動詞1 (兩性結合) join in marriage 2 (使動物交配) mate (animals) 3 (按適當的標準或比例加以...
- 合 : 合量詞(容量單位) ge, a unit of dry measure for grain (=1 decilitre)
- 物 : 名詞1 (東西) thing; matter; object 2 (指自己以外的人或與己相對的環境) other people; the outsi...
- 離子 : [物理學] ion
- 配合 : suitable; fit; matching; rhythm; go together
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In all those complexes, no matter which conformation ida assumes ( mer - or fac - style ), the two 0 atoms of 1n2o are both from carboxylic hydroxyl. however, by comparing the bond length, we can find that o ( 4 ) and o ( 2 ) atom is from different group in this complex, 0 ( 4 ) atom from carboxylic hydroxyl, whereas, 0 ( 2 ) from carboxylic carboxide
值得注意的是:在這個雙核配合物中,我們首次發現一種新穎的配位方式: ida上與金屬離子配位的三齒螯合原子是亞氨n原子、一個羧基上的羥基o原子和另外一個羧基上的羰基o原子。Synthesis and characterization of mixed ligands complexes of coper ions with amino acid
銅離子與氨基酸混配合物的合成We have prepared a series of neodymium binary / ternary complexes, such as nd ( acac ) 3 ' 2h2o, nd ( tfa ) 3 ' 2h2o, nd ( hfa ) 3 ' 2h2o, nd ( dbm ) 3 ' h2o, nd ( acac ) 3phen, nd ( tfa ) 3phen, nd ( hfa ) 3phen, nd ( dbm ) 3phen, nd ( tta ) 3 ( tppo ) 2, nd ( hfa ) 3 ( tppo ) 2, nd ( acac ) 4hpy, nd ( tta ) 4hpy and ndq3. the effects of organic ligands, synergistic coordination agents and different substitution groups for - diketones on effective line width and photoluminescence intensity of neodymium complexes were investigated. the photoluminescence spectra indicate that synergistic coordination agents can shield neodymium ion and impede water molecules penetrating into inner coordination shell to satisfy large coordination number of nd3 + during hydrous synthesis process, so the luminescence intensity of neodymium ternary complexes is stronger than that of neodymium binary complexes
發光光譜研究表明,由於協同試劑的參與,屏蔽了水分子參與配位,降低了羥基( oh )對釹離子激發態能級~ 4f _ ( 3 2 )的猝滅,三元配合物的熒光強度均比二元配合物強,其中配合物nd ( tta ) _ 3 ( tppo ) _ 2在1340nm處的熒光強度最強,適合作為摻雜的光學活性物質,來制備有源光波導材料;在有水工藝條件下,單純地氟化配體未必能提高釹配合物的近紅外發光性能。Recently, study on solvent polymeric membrane ( spm ) anion selective electrodes based on metal complexes as neutral carrier and exhibiting anti - hofmeister selectivity pattern is an important project in the fields of electrochemistry and electroanalytical chemistry
近年來,以金屬配合物作為中性載體且呈現anti - hofmeister行為的陰離子選擇性電極是電化學和電分析領域中公認的活躍研究課題。On fluorescence emission strength of the complex was studied. the reaction of dtpaa with pas - na can give dtpa - pas and dtpa - 2pas. their tb
離子等對三元配合物熒光性質的影響,並且探索了用三元配合物作為熒光免疫標記示蹤物的可能性。Layered and pillared material are a kind of multifunctional material which were developed in recent years, much attention has been paid to this kind of material for its application in ion - exchange catalysts solid state proton conductivity, nonlinear optics and physic. a lot of literature have reported the intercalation behavior of a - zirconium phosphate ( abbreviated as a - zrp ), different guest molecules inserted into a - zrp have been studied in detail, those guest molecules include amine, alcohok amino acid protein, enzyme coornadiate compound and coronal compound. the intercalation guest is restricted by their size and basicity
層柱材料是近年來發展起來的一類多功能材料,由於其在離子交換、催化、固態質子導體、非線性光學以及醫學等方面的廣泛應用而受到國內外研究者的重視,大量文獻報道了-磷酸氫鋯zr ( hpo _ 4 ) _ 2 ? h _ 2o ( - zirconiumphosphate ,縮寫為- zrp )的超分子插層化合物及插層性能,其中對不同的客體分子對磷酸鋯的嵌入做了詳細的報道,客體分子的種類包括氨、醇、氨基酸、蛋白質、酶、配合物、冠狀化合物等。Experimental result shows that cavitation can destroy metal cyanogen preparation and chemical property of bearing cyanide wastewater is changed ; it intensify the fiber ' s adsorption progress and reduce the time of adsorption equilibrium, the general cyanide adsorption rate is increased 5 % or so, but it strength the different effect on different metal - cyanide negative ions ; strengthen effect of copper cyanide complex is stronger than zinc and iron cyanide complex, so ultrasonic wave may strength the fiber ' s adsorption processes
實驗結果表明,功率超聲的空化作用能破壞金屬氰配合物鍵,從而改變含氰廢水的化學性質,另外也可縮短吸附平衡時間,強化纖維的吸附過程,使總氰的吸附率可提高5 %左右;功率超聲對不同金屬氰配合物離子的強化效果是不同的,對銅氰絡離子的強化效果要強于鐵氰、鋅氰絡離子,所以功率超聲可以強化纖維的吸附過程。The main methods to prepare polyphosphazene were first introduced, then the living cation polymerization at room temperature and the reaction halogenphosphazene and pentacoordinate silicon complexes developed in our laboratory were discussed
在回顧聚磷腈的主要合成方法的基礎上,介紹了出現的室溫活性正離子聚合及本實驗室利用鹵化磷腈與五配位硅絡合物反應所取得的一些結果。And tg - dsc. 3. n, n ' - disalicylidenedianilines and its transition metal complexes of nicl2 6h2o are synthesized by liquid and solid state reaction at room temperature, and their thermochromism are investigated by ir, far i. r
文中的配合物就是其中之一,中心離子是與c = n雙鍵的n原子以及苯環上鄰位的羥基的氧原子同時進行配位的。In order to prepare composites with the least dimerization, it is important to design and assemble the target mpc molecule with desired structure, such as peripheral or axial substitutional groups. the optical limiting effect of the composites is measured at 532nm with 8ns pulses. the influence of different mpc doped concentrations, central metal ions, substitutional groups, dimerization ratios, and matrix on the composites " optical limiting effect is studied
在此基礎上,應用光限幅測試技術,系統地研究了無機基金屬酞菁復合固態材料的光限幅性能和金屬酞菁配合物在復合體系中的光限幅機理,揭示了復合體系光限幅性能的酞菁濃度效應、中心離子效應、取代基效應和基質效應,為金屬酞菁分子設計和復合制備工藝優化提供了可靠參考依據和可能。New solvent polymeric membrane electrodes based on schiff base complexes of [ mn ( hi ) - bsapc ] and [ mn ( iii ) - bsapdca ] are first described, which demonstrate excellent selectivity toward iodide ion
詳細研究了高靈敏度高選擇性碘離子電極中性載體? ?過渡金屬配合物分子的設計、合成及其作為電極載體對碘離子的選擇性電位響應特性。Synthesis and characterization of n - salicylidene glutamic acid with transition metals complexes
過渡金屬離子大二環籠狀配合物的研究進展Simple organic molecules tend to be colorless with electronic transitions in the uv, whereas visible absorption, or color is usually associated with electronic in extended and conjugated structures. color is influenced considerably by the extent of conjugation, as well as by the molecular environment imparted by substituents. the reports on organic hydrate thermochronlic material are relatively fewer
本文利用液相和室溫/低熱固相反應合成出變色溫度較高的具有良好熱色性的雙席夫堿及其配合物;過渡金屬離子具有d軌道,其配合物容易引起d - d躍遷或荷移躍遷,因而它們具有豐富的顏色。This article gives a review on the progress of the recognition and complexation between cucurbiturils as a noval macrocyclic host compound and metal ion, including the synthesis methods of supermolecular adducts, crystal structures, thermodynamics of binding and potential applications
摘要概述了新一代大環主體化合物南瓜尼與金屬離子的識別及配合作用的研究進展,包括其超分子配合物的合成方法,晶體結構,鍵合的熱力學性質及其應用前景。In this paper, according to organic ligands including polyaminocarboxylates, hydroxycarbolates, alcohols and so on, coordinative environments, patterns of synthesis and structures of complexes as well as other properties about bismuth complexes in solid state are summarized
本文主要根據有機配體的不同,對三價鉍離子配合物的合成及相應的結構進行分類概述,並針對固態鉍配合物,對鉍( )離子在各配合物中所處的配位環境以及與配體的配位方式等進行了綜述。The third part studied ecological effect of combined pollution for hms in plearotus ostreatus, measured the lingth and anti - weed - moulds ability of hyphae, biomass of plearotus ostreatus, biovailability of hms, hms enrichment, the variety of hms toxicity and the transformation amd redistribution ability of hms. the ecological dffect of hms on plearotus ostreatus is reviewed. hms mentioned above were harmful to the growth and yield of pleurotus, ostreatus, but cd could enhance billogical efficiency
第三部分:研究重金屬復合污染物對平菇生態效應的影響,分析了菌絲生長速度和抗雜性,平菇的生物量,重金屬離子的生物有效性,平菇對重金屬的吸收與富集,重金屬毒性的差異和重金屬離子的分配和遷移,綜合分析了重金屬的交互作用對平菇的生態效應。It is thought that the exciplex ' s emission is eliminated completely by modulating the transient excited state of exciplex thought varying the ratio of two molecules and by action from the excited state level of rare - earth ions
對于稀土配合物,可以通過控制混合層中的分子比率調制激基復合物的瞬間激發態能級位置,使其與稀土離子的激發態能級匹配,將激基復合物完全消除。Nir luminescence due to nd3 + ions from the vtes - derived films was observed, with peak shape similar to that of pure complexes. this indicates the ligands indeed effectively shield nd3 + ions from the chemical microenvironment and giving evidence of the lack of strong chemical interactions with the host matrix when the complex was embedded in the vtes - derived matrix
488nm光激發下,觀察到薄膜中釹的發光,與純配合物粉末熒光相比,峰形變化不大,表明配體對釹起著有效的包裹和保護作一浙江大學碩士學位論文用, nd3 +離子的配位環境受基質的影響很小。The factors of influencing coordinate polymer structure, such as metal ions and ligand, were discussed. the reaction conditions of coordinate polymer were studied
摘要討論了影響配合物結構的一些因素;金屬離子和配體等。也研究了配位聚合物的反應條件。Using above method with theories, we have computed the magnetic exchange coupling constants j values about ( vivo ) cr [ 1 ( cn ) 6 ] 2 / 3. 10 / 3h2o compound and [ mo2 ( cn ) 11 ] 5 compound, respectively. the j values are equal to - 42. 36cm - 1 and - 111. 46cm - 1, respectively
然後,分別對這兩種配合物自旋密度分佈加以分析,兩種配合物中金屬離子上的成單電子幾乎是定域的,其自旋極化佔主導作用。分享友人